期刊
MATERIALS RESEARCH EXPRESS
卷 6, 期 11, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/2053-1591/ab4d24
关键词
Bi-functional electrocatalyst; cathode material; Li-CO2 batteries; Li-O-2 batteries
资金
- National Natural Science Foundation of China [51502082]
- Fund of Key Scientific and Technological Project of Henan Province [182102210079]
The problem of Li-O-2 batteries lies in the lack of high performance and low-cost catalyst that can promote the decomposition of discharge products. The trouble is even more serious when it cycles in CO2. Herein, we synthesize a nitrogen (N) and sulfur (S) co-doped 3D graphene@NiO (N, S-3DG@NiO) composite as a bi-functional electrode catalyst, which can concurrently support the stable cycling of Li-O-2 and Li-CO2 batteries. In this design, the N, S-3DG@NiO has three-dimensional porous structure, which can provide extra storage space for discharge products, and N and S co-doping provides more reaction active sites. The bi-functional electrode catalyst delivers a high discharge capacity of 17 300 mAh g(-1) and excellent cyclability (more than 50 cycles, limited capacity 500 mA g(-1)) when it is applied for Li-O-2 batteries. In addition, the N, S-3DG@NiO catalyst also exhibits a large discharge capacity of 13 400 mAh g(-1) when it is used as cathode for Li-CO2 batteries (more than 50 cycles, limited capacity 500 mA g(-1)). This study not only provides a high efficiency bi-functional cathode catalyst for Li-O-2 and Li-CO2 batteries, but also promotes the development of high specific energy batteries.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据