4.6 Article

Effect of natural and anthropogenic acidification on aluminium distribution in forest soils of two regions in the Czech Republic

期刊

JOURNAL OF FORESTRY RESEARCH
卷 32, 期 1, 页码 363-370

出版社

NORTHEAST FORESTRY UNIV
DOI: 10.1007/s11676-019-01061-1

关键词

Soil acidification; Spruce forest; Soil properties; Aluminium forms; Aluminium species

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资金

  1. European Regional Development Fund, project Centre for the Investigation of Synthesis and Transformation of Nutritional Substances in the Food Chain in Interaction with Potentially Harmful Substances of Anthropogenic Origin: Comprehensive Assessment of Soi [CZ.02.1.01/0.0/0.0/16_019/0000845]

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The research elucidates the dynamics of aluminium in soils, with higher levels found in anthropogenically acidified areas. The concentrations of univalent aluminium in organic soil horizons were similar for both regions. The relationships of aluminium concentrations in different forms with calcium concentrations and pH were observed.
To elucidate the dynamics of aluminium (Al), an element potentially toxic and strongly affected by acidification processes, in soils, we selected two regions that were similar in relief, soil types, and vegetation cover but differed markedly in their history of acid precipitation: the Jizerske Mountains (anthropogenically acidified) and the Novohradske Mountains (naturally acidified) in the Czech Republic. The levels of Al forms (exchangeable and organically bound) associated with different environmental impacts were measured and univalent, divalent and trivalent Al species were quantified using HPLC/IC. Exchangeable and organically bound Al concentrations were higher in the anthropogenically acidified area. Only the concentrations of the least-dangerous species, the univalent, in organic soil horizons were similar for both mountains. The concentrations of exchangeable Al forms were correlated with Ca concentrations and with pH in the organic horizon. The known relationship of Al with soil pH was stronger in the mineral horizons. Relationships of exchangeable Al forms concentrations with sulphur concentrations or even more with the sulphur calcium molar ratio were found only in the Jizerske Mountains, not in the Novohradske. Generally, the obtained results support the hypothesis that mechanisms differed between natural and anthropogenic acidification.

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