期刊
JOURNAL OF ENERGY CHEMISTRY
卷 38, 期 -, 页码 26-33出版社
ELSEVIER
DOI: 10.1016/j.jechem.2019.01.003
关键词
Slow-release strategy; Layered double hydroxides (LDHs); Nanosheets; Oxygen evolution reaction; Supercapacitor
资金
- National Natural Science Foundation of China [21476145]
An OH--slow-release strategy was established to controllably tune the (alpha- and beta-) phase of nickel cobalt binary hydroxide in the presence of ammonium chloride. Ammonium chloride is added to the ionic solution to regulate the pH of the solution and slow down the release of OH-, effectively regulating the phase, nanostructure, interlayer spacing, surface area, thickness, and the performance of binary Ni-Co hydroxide. The ion-slow-release mechanism is conducive to the formation of alpha-phase with larger interlayer spacing and thinner flakes rather than beta-phase. Attributed to the enlarged interlayer spacing, thinner nanosheets, and more exposed active sites, the resultant alpha-phase hydroxides (NCNS-5.2), displayed much lower over potential of 285 mV with respect to the dense-stacked beta-phase hydroxides (362 mV) for OER at 10 mA/cm(2). It also exhibited high specific capacitance of 1474.2 F/g, when tested at 0.5 A/g within a voltage range of 0-0.45 V vs. Hg/HgO. This composite was also stable for water oxidation reaction and supercapacitor. The proof-of-concept of using controlled-release agent may provide suggestive insights for the material innovation and a variety of applications. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
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