4.8 Editorial Material

Comment on exposure to microplastics (<10 μm) associated to plastic bottles mineral water consumption: The first quantitative study by Zuccarello et al. [Water Research 157 (2019) 365-371]

期刊

WATER RESEARCH
卷 162, 期 -, 页码 516-517

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.watres.2019.06.032

关键词

Microplastics; Bottled mineral water; PET bottles

向作者/读者索取更多资源

Microplastics in food is a relatively new research field with only few studies available so far. Scientists have been pointing out that some of these studies apply questionable analytical methods. Nevertheless, media often use such results to gain attention of the readers. It is therefore of particular significance, that only those scientific studies are published, clearly presenting valid data on the content of microplastics in food. Unfortunately, the study by Zuccarello et al. shows very critical aspects regarding analytical methods used and conclusions made. The applied procedure is not described and, therefore, does not allow any assessment by other groups, which is indispensable prerequisite of any scientific publication. Moreover, the analytical method used for the identification and quantification of microplastic particles SEM-EDX is not sound and not validated. Therefore, in our opinion the results on the contamination of bottled mineral water with microplastics published by Zuccarello et al. are more than questionable. (C) 2019 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Biochemistry & Molecular Biology

Migration Testing of GPPS and HIPS Polymers: Swelling Effect Caused by Food Simulants Compared to Real Foods

Valeria Guazzotti, Anita Gruner, Mladen Juric, Veronika Hendrich, Angela Stoermer, Frank Welle

Summary: This study investigates the migration kinetics of polystyrene under different temperatures using food simulants and real foods. The findings suggest that the recommendations provided by EU regulations may not always align with the physicochemical properties of the polymer.

MOLECULES (2022)

Review Chemistry, Analytical

The identification of microplastics based on vibrational spectroscopy data- A critical review of data analysis routines

Jana Weisser, Teresa Pohl, Michael Heinzinger, Natalia P. Ivleva, Thomas Hofmann, Karl Glas

Summary: This article discusses data analysis methods for identifying microplastics using vibrational spectra, introduces relevant programs provided by the scientific community, and aims to provide guidance for those who want to establish or enhance data analysis routines for vibrational spectra of microplastics.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2022)

Article Engineering, Environmental

Microplastic sampling from wastewater treatment plant effluents: Best-practices and synergies between thermoanalytical and spectroscopic analysis

Mohammed S. M. Al-Azzawi, Matin Funck, Marco Kunaschk, Elisabeth Von der Esch, Oliver Jacob, Korbinian P. Freier, Torsten C. Schmidt, Martin Elsner, Natalia P. Ivleva, Jochen Tuerk, Oliver Knoop, Joerg E. Drewes

Summary: This study discusses the best practices for microplastic sampling campaigns in wastewater treatment plants (WWTPs) and explores the potential synergies between thermoanalytical and spectroscopic analysis. The results show that polyethylene (PE) is consistently the most prominent polymer in WWTP effluents and can serve as a surrogate polymer to assess the total polymer removal efficiency of tertiary sand filters.

WATER RESEARCH (2022)

Article Microbiology

Fructobacillus cardui sp. nov., isolated from a thistle (Carduus nutans) flower

Marion K. Gallus, Irina Beer, Natalia P. Ivleva, Matthias A. Ehrmann

Summary: In this study, a new strain of Fructobacillus was isolated and identified from the flower of a nodding thistle in Germany. The strain is a Gram-positive, rod-shaped, non-motile bacterium with facultative anaerobic growth. Through various analyses, it was classified as a new species named Fructobacillus cardui.

INTERNATIONAL JOURNAL OF SYSTEMATIC AND EVOLUTIONARY MICROBIOLOGY (2022)

Article Chemistry, Analytical

Multi-element stable isotope Raman microspectroscopy of bacterial carotenoids unravels rare signal shift patterns and single-cell phenotypic heterogeneity

Julian Weng, Kara Mueller, Oleksii Morgaienko, Martin Elsner, Natalia P. Ivleva

Summary: The combination of single-cell Raman microspectroscopy and stable isotope probing allows for tracking carbon and hydrogen fluxes at the single-cell level, with high potential for analyzing metabolic processes and biogeochemical cycles. This study investigates the use of resonance Raman enhanced microspectroscopy for tracking bacterial carotenoids and reveals high phenotypic heterogeneity and evidence for de novo synthesis. It also explores the uptake of hydrogen into carotenoids and a novel approach for simultaneous monitoring of carbon and hydrogen uptake.

ANALYST (2022)

Article Biochemistry & Molecular Biology

Migration Modeling as a Valuable Tool for Exposure Assessment and Risk Characterization of Polyethylene Terephthalate Oligomers

Verena N. Schreier, Alex Odermatt, Frank Welle

Summary: Polyethylene terephthalate (PET) is widely used as a food contact material due to its good mechanical properties and recyclability. This study utilized migration modeling to evaluate the migration potential of 52 PET oligomers in various application scenarios. Results were compared with safety thresholds to identify potential risks associated with certain oligomers or applications.

MOLECULES (2023)

Editorial Material Biochemical Research Methods

Advances in chemical analysis of micro- and nanoplastics

Natalia P. Ivleva, Sebastian Primpke, Jennifer M. Lynch

ANALYTICAL AND BIOANALYTICAL CHEMISTRY (2023)

Article Biochemical Research Methods

Physicochemical characterization and quantification of nanoplastics: applicability, limitations and complementarity of batch and fractionation methods

Maximilian J. Huber, Natalia P. Ivleva, Andy M. Booth, Irina Beer, Ivana Bianchi, Roland Drexel, Otmar Geiss, Dora Mehn, Florian Meier, Alicja Molska, Jeremie Parot, Lisbet Sorensen, Gabriele Vella, Adriele Prina-Mello, Robert Vogel, Fanny Caputo

Summary: A comprehensive physicochemical characterization of heterogeneous nanoplastic (NPL) samples remains challenging due to the need for a combination of measurement techniques to improve accuracy and robustness. Various methods including DLS, NTA, TRPS, TEM, SEM, CLS, FFF-MALS, pyGC-MS, and RM were evaluated for NPL size, shape, chemical composition, and quantification. The applicability and limitations of these methods were assessed using representative particles of different chemical natures. The results showed that orthogonal batch methods provided comparable results for monodisperse spherical samples, while deviations were observed in polydisperse and non-spherical particles. Specific techniques such as TRPS and electron microscopy provided increased resolution and morphological information.

ANALYTICAL AND BIOANALYTICAL CHEMISTRY (2023)

Article Biochemical Research Methods

TUM-ParticleTyper 2: automated quantitative analysis of (microplastic) particles and fibers down to 1 μm by Raman microspectroscopy

Oliver Jacob, Alejandro Ramirez-Pinero, Martin Elsner, Natalia P. Ivleva

Summary: Accurate quantification of small microplastics in environmental and food samples is essential for studying their potential hazard. Raman microspectroscopy can identify particles as small as 1 μm in diameter. This study presents a new software, TUM-ParticleTyper 2, which allows for automated quantification of microplastics across the defined size range, using random window sampling and on-the-fly confidence interval estimation.

ANALYTICAL AND BIOANALYTICAL CHEMISTRY (2023)

Article Green & Sustainable Science & Technology

Recycling of Post-Consumer Polystyrene Packaging Waste into New Food Packaging Applications-Part 2: Co-Extruded Functional Barriers

Frank Welle

Summary: Using new polystyrene polymer as a functional barrier to introduce post-consumer polystyrene recyclates in packaging materials. However, there is no official guidance on how to test the performance of a functional barrier, and no threshold limits for the evaluation of post-consumer recyclates have been published. In this study, co-extruded yogurt cups with artificially spiked core layer were investigated for migration of applied surrogates. The migration kinetic testing method was shown to be sensitive and suitable for evaluating the functional barrier performance. Based on the conditions, data, and evaluation presented, the use of post-consumer recycled PS behind a functional barrier can be considered safe.

RECYCLING (2023)

Article Green & Sustainable Science & Technology

Recycling of Post-Consumer Polystyrene Packaging Waste into New Food Packaging Applications-Part 1: Direct Food Contact

Frank Welle

Summary: The increase in plastic recycling is crucial for a circular economy, and recycling polystyrene (PS) back into food contact materials holds promise. However, commercial-scale PS cup recycling has not been established yet. The health and safety of consumers must be ensured, and therefore, recycling processes need to undergo a rigorous assessment. However, evaluation criteria for PS recycling are currently not available, which is a disadvantage for process developers.

RECYCLING (2023)

Article Green & Sustainable Science & Technology

Identification and Evaluation of (Non-)Intentionally Added Substances in Post-Consumer Recyclates and Their Toxicological Classification

Christian Rung, Frank Welle, Anita Gruner, Arielle Springer, Zacharias Steinmetz, Katherine Munoz

Summary: According to the European circular economy strategy, all plastic packaging placed on the market by 2030 has to be recyclable. The European Food Safety Authority (EFSA) has derived very low migration limits for recycled polymers in direct contact with food. PET is currently the only polymer that complies with EFSA's requirements for a circular economy. However, better-structured collection systems and cleaning processes, as well as more analytical methods, might offer the possibility of implementing other polymers into recycling processes in the future.

RECYCLING (2023)

Article Spectroscopy

Development of laser-induced breakdown spectroscopy-methods for rapid element quantification in alloy particles in technical cleanliness analysis

Maria Lanzinger, Dominik Huber, Virginia Merk, Stephanie Kaufmann, Michael Schuster, Natalia Ivleva

Summary: In today's industrial production, it is crucial to eliminate particle contamination in order to ensure the safety and quality of products. This study focuses on the representativeness of in-house generated aluminum reference particles to their source bulk material through quantitative element analysis. The results validate the functionality and applicability of using laser-induced breakdown spectroscopy (LIBS) for particle analysis and provide a new method for the easy generation of internal reference particles.

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY (2023)

Review Environmental Sciences

Plastics can be used more sustainably in agriculture

Thilo Hofmann, Subhasis Ghoshal, Nathalie Tufenkji, Jan Franklin Adamowski, Stephane Bayen, Qiqing Chen, Philip Demokritou, Markus Flury, Thorsten Hueffer, Natalia P. Ivleva, Rong Ji, Richard L. Leask, Milan Maric, Denise M. Mitrano, Michael Sander, Sabine Pahl, Matthias C. Rillig, Tony R. Walker, Jason C. White, Kevin J. Wilkinson

Summary: Plastics have been widely used in agriculture, but their accumulation in soils has become a major issue. Controlling plastic pollution in agriculture requires rational use, reduction, collection, and innovative recycling. Sustainable alternatives with smaller environmental impacts should be promoted, along with better monitoring, technical innovation, education, and economic incentives.

COMMUNICATIONS EARTH & ENVIRONMENT (2023)

Article Biochemistry & Molecular Biology

Impact of Partitioning in Short-Term Food Contact Applications Focused on Polymers in Support of Migration Modelling and Exposure Risk Assessment

Rainer Brandsch, Mark Pemberton, Dieter Schuster, Frank Welle

Summary: Food contact materials (FCMs) can transfer chemicals to food before consumption. The migration testing conditions for FCMs are conservative and often assume worst-case scenarios. In repeated-use FCMs, the steady-state is rarely reached, and migration is diffusion-controlled. Modeling based on diffusion parameters can be used to assess migration in certain domains. These findings are significant for regulatory guidance and compliance practices.

MOLECULES (2022)

Article Engineering, Environmental

Parabens and their metabolite in a marine benthic-dominated food web from the Beibu gulf, South China Sea: Occurrence, trophic transfer and health risk assessment

Rong-Gui Zhu, Chang-Gui Pan, Feng-Jiao Peng, Chao-Yang Zhou, Jun-Jie Hu, Kefu Yu

Summary: This comprehensive survey investigated the occurrence, bioaccumulation, and trophic magnification of parabens and their metabolite 4-HB in a marine food web. Results showed that parabens were the predominant pollutants in marine organisms, with significant bioaccumulation from sediments. The estimated trophic magnification factor indicated biomagnification for MeP and trophic dilution for 4-HB. Overall, the risks for humans consuming marine organisms were found to be low.

WATER RESEARCH (2024)

Article Engineering, Environmental

Partitioning and inactivation of enveloped and nonenveloped viruses in activated sludge, anaerobic and microalgae-based wastewater treatment systems

Andres F. Torres-Franco, Deborah Leroy-Freitas, Cristina Martinez-Fraile, Elisa Rodriguez, Pedro A. Garcia-Encina, Raul Munoz

Summary: Anaerobic and microalgae-based technologies have emerged as sustainable alternatives for municipal wastewater treatment. However, the presence of viruses in the treated wastewater is a major concern for reuse applications. This study assessed the ability of these technologies to reduce viruses during secondary wastewater treatment. The results showed that all technologies were effective in reducing the concentration of viruses, with microalgae-based treatment exhibiting the highest potential for reducing the disinfection requirements of treated wastewater.

WATER RESEARCH (2024)

Article Engineering, Environmental

Reconsidering mercury sources and exposure pathways to bivalves: Insights from mercury stable isotopes

Young Gwang Kim, Sae Yun Kwon, Spencer J. Washburn, Scott C. Brooks, Ji Won Yoon, Lucien Besnard

Summary: The study uses Hg isotope ratios to identify the sources and exposure pathways of mercury in bivalves, finding that dissolved Hg phases in the water column are the primary source and exposure pathway to bivalves. This provides new insights into using bivalves as bioindicators for sediment quality monitoring.

WATER RESEARCH (2024)

Article Engineering, Environmental

Cation exchange resins enhance anaerobic digestion of sewage sludge: Roles in sequential recovery of hydrogen and methane

Hui Geng, Ying Xu, Rui Liu, Dianhai Yang, Xiaohu Dai

Summary: This study investigates the effect of cation exchange resin (CER) on the sequential recovery of hydrogen and methane from anaerobic digestion (AD) and the corresponding mechanisms. The results show that CER can simultaneously enhance the production of hydrogen and methane by promoting the solubilisation, hydrolysis, and acidification of organic matter. Additionally, CER facilitates effective contact between bacteria and organic particulates and reduces the energy barrier for mass transfer during methane production. The study also reveals changes in the microbial community structure and metagenomics during the AD process.

WATER RESEARCH (2024)

Article Engineering, Environmental

Fertilizer recovery from source-separated urine by evaporation with a combined process of dehumidification and the addition of absorbent resin supplement

Xiaojing Lin, Zhan Jin, Shunfeng Jiang, Zhiquan Wang, Suqing Wu, Ke Bei, Min Zhao, Xiangyong Zheng

Summary: Dehumidification combined with addition of absorbent resin supplement (ARS) was used to achieve rapid evaporation of non-pretreated urine, resulting in high water evaporation efficiency and nutrient recovery.

WATER RESEARCH (2024)

Article Engineering, Environmental

Influences of hydrodynamics on microbial community assembly and organic carbon composition of resuspended sediments in shallow marginal seas

Yangli Che, Chaoran Lin, Shen Li, Jiao Liu, Longhai Zhu, Shilei Yu, Nan Wang, Haoshuai Li, Mutai Bao, Yang Zhou, Tonghao Si, Rui Bao

Summary: Hydrodynamic processes play a crucial role in the transmission of sediments, microbial assembly, and organic carbon redistribution in the ocean. Through experiments and analysis, we found that hydrodynamics shape the assembly of microbial communities and control the redistribution of different sourced organic carbon, thereby influencing microbial-mediated biogeochemical transformation.

WATER RESEARCH (2024)

Article Engineering, Environmental

A comprehensive evaluation of the temporal and spatial fouling characteristics of RO membranes in a full-scale seawater desalination plant

Chao Chen, Yu Yang, Nigel J. D. Graham, Zhenyu Li, Xingtao Yang, Zhining Wang, Nadia Farhat, Johannes S. Vrouwenvelder, Li -an Hou

Summary: The fouling of seawater reverse osmosis membranes is a persistent challenge in desalination. This study monitored the operational performance of a desalination plant for 7 years and the fouling development in different areas of membrane modules. The findings showed that operational performance declined over time and fouling mainly occurred at the feed side of the modules, with the highest microbial diversity. Keystone species like Chloroflexi and Planctomycetes played an important role in maintaining community structure and biofilm maturation. Polysaccharides, soluble microbial products, marine humic acid-like substances, and inorganic substances contributed to fouling. Overall, biofouling had a significant impact on membrane fouling after 7 years of operation.

WATER RESEARCH (2024)

Article Engineering, Environmental

Fluctuating redox conditions accelerate the electron storage and transfer in magnetite and production of dark hydroxyl radicals

Dan Li, Jieyi Sun, Yibo Fu, Wentao Hong, Heli Wang, Qian Yang, Junhong Wu, Sen Yang, Jianhui Xu, Yunfei Zhang, Yirong Deng, Yin Zhong, Ping'an Peng

Summary: Sulfidation-oxidation treatment of magnetite (Fe3O4) enhances the production of dark center dot OH, which can efficiently degrade dissolved organic matter (DOM) and accelerate carbon cycling.

WATER RESEARCH (2024)

Article Engineering, Environmental

Full-scale upgrade activated sludge to continuous-flow aerobic granular sludge: Implementing microaerobic-aerobic configuration with internal separators

Cheng Yu, Kaijun Wang, Kaiyuan Zhang, Ruiyang Liu, Pingping Zheng

Summary: This study implemented a microaerobic-aerobic configuration in a full-scale municipal wastewater treatment facility and investigated the effects on sludge characteristics, pollutant removal, microbial community, and granulation mechanisms. The results showed successful transition from flocculent-activated sludge to well-defined AGS after two months of operation. The primary pathways for pollutant removal were simultaneous nitrification, denitrification, and phosphorus removal. Moreover, the incorporation of internal separators induced shifts in the flow pattern, which promoted granulation.

WATER RESEARCH (2024)

Article Engineering, Environmental

Target analysis, occurrence and cytotoxicity of halogenated polyhydroxyphenols as emerging disinfection byproducts in drinking water

Zhe Zhang, Shaoyang Hu, Guangrong Sun, Wei Wang

Summary: Halogenated aromatic disinfection byproducts (DBPs), such as halogenated phenols, have garnered widespread attention due to their high toxicity and prevalence. This study reports on the analysis, occurrence, and cytotoxicity of a group of emerging halogenated aromatic DBPs, known as halogenated polyhydroxyphenols (HPPs), in drinking water.

WATER RESEARCH (2024)

Article Engineering, Environmental

A coupled model to improve river water quality prediction towards addressing non-stationarity and data limitation

Shengyue Chen, Jinliang Huang, Peng Wang, Xi Tang, Zhenyu Zhang

Summary: Accurate prediction of river water quality is crucial for sustainable water management. This study introduces wavelet analysis and transfer learning techniques to assist LSTM modeling, proposing a newly coupled modeling approach that improves short-term prediction of river water quality.

WATER RESEARCH (2024)

Article Engineering, Environmental

Deciphering anaerobic ethanol metabolic pathways shaped by operational modes

Bang Du, Xinmin Zhan, Piet N. L. Lens, Yifeng Zhang, Guangxue Wu

Summary: Efficient anaerobic digestion relies on the cooperation of different microorganisms with different metabolic pathways. This study investigated the effects of different operational modes and the addition of powdered activated carbon (PAC) on ethanol metabolic pathways. The results showed that the SBR mode and the presence of CO2 facilitated ethanol metabolism towards propionate production, while the CFR mode with extended solids retention time enriched Geobacter. Adjusting operational modes and PAC addition can modulate anaerobic ethanol metabolism and enrich Geobacter.

WATER RESEARCH (2024)

Article Engineering, Environmental

Unraveling the factors influencing CO2 emissions from hydroelectric reservoirs in karst and non-karst regions: A comparative analysis

Wanfa Wang, Si-Liang Li, Jun Zhong, Yuanbi Yi, Fujun Yue, Zenglei Han, Qixin Wu, Ding He, Cong-Qiang Liu

Summary: This study compares the carbon biogeochemical processes in karst and non-karst regions within large thermal stratified river-reservoir systems. The results demonstrate that karst reservoirs have a reduced potential for carbon emissions and highlight the importance of considering geologic settings to improve accuracy in regional and global CO2 emission estimates.

WATER RESEARCH (2024)

Article Engineering, Environmental

Rare resistome rather than core resistome exhibited higher diversity and risk along the Yangtze River

Chunxia Jiang, Zelong Zhao, Dong Zhu, Xiong Pan, Yuyi Yang

Summary: This study analyzed the occurrence and distribution of antibiotic resistance genes (ARGs) in different environmental media of the Yangtze River using metagenomics. Core resistome dominated by multidrug resistance genes was found in all samples, while rare resistome dominated by various resistance genes was more prevalent in plasmids. Specific bacteria were identified as hosts for both core and rare resistomes, with high clinical concern ARGs found in the rare resistome. Particle-associated environment provided the most ideal conditions for resistome hosts. This study provided insights into the genetic locations of ARGs and the community assembly mechanisms of ARG hosts in freshwater environments.

WATER RESEARCH (2024)

Article Engineering, Environmental

Uncovering interactions among ternary electron donors of organic carbon source, thiosulfate and Fe0 in mixotrophic advanced denitrification: Proof of concept from simulated to authentic secondary effluent

Yu Zhang, Yongtao He, Linchun Jia, Lei Xu, Zheng Wang, Yueling He, Ling Xiong, Xumeng Lin, Hong Chen, Gang Xue

Summary: By synergizing organic carbon source, thiosulfate, and zero-valent iron, efficient mixotrophic denitrification of oligotrophic secondary effluent can be achieved. Thiosulfate plays a vital role in promoting TN removal efficiency, while corrosion of Fe0 releases OH- to neutralize H+ from thiosulfate-driven denitrification, creating a suitable environment for denitrification. The coordination of thiosulfate and Fe0 maintains the dominance of Thiobacillus for denitrification.

WATER RESEARCH (2024)