Article
Engineering, Environmental
Xing Xia, Jin Liu, Lin Jin, Jian Wang, Aminu Inuwa Darma, Chao He, Mohsen Shakouri, Yongfeng Hu, Jianjun Yang
Summary: This study investigated the impact of organic matter on the behavior of chromium during the iron(II)-catalyzed transformation of ferrihydrite. The results showed that organic matter inhibited the release and extraction of chromium during the transformation process, as well as the nanoscale conversion and re-immobilization of chromium. Therefore, organic matter plays an important role in the geochemical cycling of chromium in soils.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Agronomy
Yanan Huang, Li Huang, Jun Nie, Mingjian Geng, Yanhong Lu, Yulin Liao, Bin Xue
Summary: The substitution of chemical fertilizer by Chinese milk vetch can increase soil organic carbon content and improve the stability of organic carbon in paddy soils, contributing to its sequestration.
Article
Chemistry, Physical
Apinya Saentho, Carin Sjostedt, Nattaporn Prakongkep, Wantana Klysubun, Jon-Petter Gustafsson, Worachart Wisawapipat
Summary: This study investigated the speciation of silicon in the clay-sized fraction of tropical soils. The results showed that silicon mainly existed in a beidellite structure and was adsorbed to montmorillonite and kaolinite. Si reference spectra had unique features that could differentiate different silicon forms. The extracted silicon amount was relatively low and correlated positively with pH, organic matter, and clay content in the soil.
APPLIED CLAY SCIENCE
(2023)
Article
Geochemistry & Geophysics
Yao Zhao, Oliver W. Moore, Ke-Qing Xiao, Lisa Curti, Alba Otero Farina, Steven A. Banwart, Caroline L. Peacock
Summary: This study investigates the impact of organic carbon (OC) binding strength on the aging of ferrihydrite and the fate of associated OC. It is found that OC substantially retards the aging process and that OC with higher binding strength becomes more stable with the solid phase during aging. The results provide insights into the mechanisms behind OC persistence with minerals and its long-term preservation in natural environments.
GEOCHIMICA ET COSMOCHIMICA ACTA
(2022)
Article
Environmental Sciences
Peidong Xu, Ji Wu, Hui Wang, Shan Tang, Wenlong Cheng, Min Li, Rongyan Bu, Shang Han, Mingjian Geng
Summary: The combined application of chemical fertilizer with Chinese milk vetch (CMV) improves the stabilization of organic carbon (C) in paddy soil by facilitating the association of difficultly decomposed carbon and Fe/Al oxides.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Engineering, Environmental
Anna L. Hermes, Merritt N. Logan, Brett A. Poulin, Amy M. McKenna, Todd E. Dawson, Thomas Borch, Eve-Lyn S. Hinckley
Summary: This study investigates the impact of increasing agricultural sulfur (S) applications on dissolved organic S content and composition. The results highlight the potential consequences of excess S in the environment and provide insights into the dominant microbial processes associated with different land use/land cover. The findings contribute to our understanding of the modern S cycle and highlight the importance of upland agricultural areas as sources of S.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Review
Environmental Sciences
Erika Di Iorio, Luana Circelli, Ruggero Angelico, Jose Torrent, Wenfeng Tan, Claudio Colombo
Summary: This review focuses on the surface colloidal properties of iron oxides and their reactivity with humic substances, as well as the effects of humic substance adsorption/precipitation on the binding of metalloid and trace elements. Future research directions include investigating the ability of Fe nano-particles to increase Fe bioavailability, improve carbon sequestration, reduce greenhouse gas emissions, and decrease the impact of persistent organic and inorganic pollutants.
Article
Soil Science
Emma J. Schmidt, Giovanni Zanoni, Amee Bumguardner, Branimir Segvic, Katie Lewis, Dalton Abdala, Matthew G. Siebecker
Summary: This study investigates the changes in the coordination environment of potassium (K) in soil profiles using X-ray absorption spectroscopy (XAS) combined with wet chemical extractions. The results show that the Mehlich extraction can remove the bonding between K and the siloxane surfaces in the interlayer space of illite and illite-smectite, resulting in increased hydration of K. This phenomenon is more significant in coarser-textured soils.
Article
Soil Science
Gergely Jakab, Balazs Madarasz, Malihe Masoudi, Mate Karlik, Csilla Kiraly, Dora Zachary, Tibor Filep, Igor Dekemati, Csaba Centeri, Thulfiqar Al-Graiti, Zoltan Szalai
Summary: This study analyzed the increased conditions of soil organic matter (SOM) among different systems (conventional moldboard plowing, deep cultivation, and no tillage) in a base-saturated Endocalcic Chernozem. The results showed that the concentration of soil organic carbon (SOC) in the topsoil increased in the order of conventional moldboard plowing > deep cultivation > no tillage.
SOIL & TILLAGE RESEARCH
(2023)
Review
Environmental Sciences
Qi Li, Weifang Hu, Linfeng Li, Yichun Li
Summary: This paper reviews the research on Fe-OC content in different environments and describes the mechanisms and processes of OM transformation dynamics at mineral-organic interfaces. Recent studies emphasize the diverse interactions between Fe oxides and OC, with organic compounds adhering to Fe oxides.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Environmental Sciences
Ting Gao, Jiawen Zhou, Peiyu Zhang, Wenyong Wang, Tong Zhou, Zhu Li, Peter Christie, Longhua Wu
Summary: This study investigated the distribution patterns and underlying mechanisms of cadmium (Cd) isotope fractionation within soil profiles around a lead-zinc mine in southwest China. The results revealed that mining activity was the main source of Cd, which led to vertical migration of Cd isotopes within the soil profiles. The Cd isotope fractionation was correlated with the content of free iron and manganese oxides in the soil, indicating their role in the migration of Cd isotopes. This study highlights the importance of considering Cd mobilization and transport in soil profiles when using isotope techniques to trace metal sources.
ENVIRONMENTAL POLLUTION
(2022)
Article
Soil Science
Arthur Monhonval, Catherine Hirst, Jens Strauss, Edward A. G. Schuur, Sophie Opfergelt
Summary: Interactions between mineral and organic carbon (OC) play a crucial role in stabilizing OC and reducing greenhouse gas emissions after permafrost thaw. However, changes in soil water pathways can affect the stability of these interactions by inducing dissolution and precipitation. This study used the radiogenic Sr isotope method to assess how dissolution and precipitation impact mineral OC interactions in thawed and unthawed layers. The results demonstrate the potential of this method to trace dissolution-precipitation processes in thawing permafrost.
Article
Engineering, Environmental
Qihuang Wang, Jiajia Wang, Xingxing Wang, Naresh Kumar, Zezhen Pan, Stefan Peiffer, Zimeng Wang
Summary: This study investigated the influence of the association of poorly crystalline iron (hydr)-oxides with organic matter (OM) on iron and carbon cycles in soils and sediments, as well as their behaviors under sulfate-reducing conditions. The results showed that the effect of added OM on sulfidation of ferrihydrite-organic matter (Fh-OM) coprecipitates is dependent on the amount of loaded sulfide. The presence of OM inhibited mineral transformation, with microbiogenic EPS having a stronger inhibitory effect compared to synthetic EPS proxies.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Engineering, Environmental
Fengmin Li, Yue Zhang, Boyang Tian, Zheng Zhou, Li Ye, Jesse C. Carozza, Wensheng Yan, Haixiang Han, Chunhua Xu
Summary: Passivation layers on zero valent iron (ZVI) surface can be transformed into iron sulfides through an anion exchange pathway; samples from different origins show varied activities in Cr(VI) sequestration after sulfidation; Fe remains unchanged after sulfidation, indicating a non-redox, anion exchange reaction pathway for the production of iron sulfides.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Soil Science
Carlo Angeletti, Elga Monaci, Beatrice Giannetta, Serena Polverigiani, Costantino Vischetti
Summary: The crop rotation system plays a crucial role in accumulating and preserving soil organic matter, with tillage intensity being a key factor in maintaining soil aggregates and protecting organic matter from degradation. Including legumes in crop rotation has been shown to have a positive impact on the accumulation of SOM.
Article
Geochemistry & Geophysics
Brandy D. Stewart, Jeffry Sorensen, Kathleen Wendt, Jason B. Sylvan, Christopher R. German, Karthik Anantharaman, Gregory J. Dick, John A. Breier, Brandy M. Toner
Summary: This study investigates the speciation of particulate iron in buoyant hydrothermal plumes through observations and modeling, revealing a high diversity in solid-state chemistry and the need for a multi-modal analytical approach. Equilibrium modeling was found to work well for certain phases but poorly for others, leading to recommendations for future field expeditions to explore a variety of site conditions and for the development of kinetic models and expansion of thermodynamic databases to better reflect the composition of plumes.
Article
Microbiology
Cody S. Sheik, Jonathan P. Badalamenti, Jon Telling, David Hsu, Scott C. Alexander, Daniel R. Bond, Jeffrey A. Gralnick, Barbara Sherwood Lollar, Brandy M. Toner
Summary: Deep subsurface environments host diverse microbial communities facing unique challenges, with nutrient limitations likely facilitating diverse microbe-microbe interactions that drive biogeochemical cycling of major elements. Microbial communities in low temperature, chemically reduced brines at the Soudan Underground Mine State Park are dominated by Firmicute and Proteobacteria phyla, with metabolic reconstruction showing dominant carbon-fixation pathways and potential for cryptic sulfur cycling. Overall, metabolic flexibility is an important trait for microorganisms in deep isolated systems.
FRONTIERS IN MICROBIOLOGY
(2021)
Article
Engineering, Environmental
Caroline E. Pierce, Olha S. Furman, Sarah L. Nicholas, Jill Coleman Wasik, Caitlin M. Gionfriddo, Ann M. Wymore, Stephen D. Sebestyen, Randall K. Kolka, Carl P. J. Mitchell, Natalie A. Griffiths, Dwayne A. Elias, Edward A. Nater, Brandy M. Toner
Summary: We investigated the composition and spatial correlation of sulfur and mercury pools in peatland soil profiles. Our findings suggest that organic sulfur species play an important role in mercury methylation processes.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Soil Science
Xiang Wang, Adrian A. Wackett, Brandy M. Toner, Kyungsoo Yoo
Summary: In steep mountainous landscapes constrained by erosion, the longevity of soil organic carbon is largely independent of organic matter chemistry.
Article
Archaeology
Seth Quintus, Dolly Autufuga, Stephanie Day, Jennifer Huebert, Noa Kekuewa Lincoln, Nolita Motu, Kyungsoo Yoo
Summary: Successful settlement on Polynesian islands required altering the environment, which led to extensive cultural landscapes. This study in American Samoa's Ta'u Island suggests that variability in slope and soil fertility drove archaeological patterns. Early settlements were dispersed in optimal locations, while later settlements showed signs of community integration and a shift towards a despotic distribution.
JOURNAL OF FIELD ARCHAEOLOGY
(2022)
Article
Environmental Sciences
Sara C. Keen, Adrian A. Wackett, Jane K. Willenbring, Kyungsoo Yoo, Hanna Jonsson, Travis Clow, Jonatan Klaminder
Summary: Studies have shown that analyzing soil soundscapes can indirectly monitor soil ecosystem health and track earthworm activities. Earthworms alter the soil soundscape by indirectly changing the soil matrix, with different vegetation types having varying acoustic impacts on earthworms.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Anthropology
Seth Quintus, Peter Mills, Jasper Konter, Stephanie Day, Darr Gilreath, Noa Kekuewa Lincoln, Steven Lundblad, Denys Vonderhaar, Kyungsoo Yoo
Summary: This study examines trends in intra-archipelago exchange in the Samoan archipelago, specifically the Manu'a group, using geochemical and limited technological analysis of a lithic assemblage. The results indicate the presence of material from multiple basalt sources, including sources outside the Manu'a group. The nonlocal material was used differently than local material, but there is no evidence to suggest differential distribution or control. This suggests decentralized exchange and the use of imported materials as common pool resources to support community resiliency and sustainability.
ARCHAEOLOGICAL AND ANTHROPOLOGICAL SCIENCES
(2022)
Article
Geosciences, Multidisciplinary
Cristopher J. Schuler, Lindsey J. Briscoe, Scott C. Alexander, E. Calvin Alexander, Jeffrey A. Gralnick, Cara M. Santelli, Brandy M. Toner
Summary: This study characterizes the hydrogeologic and geochemical systems of a 2.7 Ga banded iron formation in the Soudan Underground Mine State Park, highlighting the interplay between geochemistry and microbiology in deep environments. The presence of high magnesium concentrations and distinct water isotope values suggests a unique subsurface community, making Soudan a promising site for future research into deep crustal life.
FRONTIERS IN EARTH SCIENCE
(2022)
Article
Environmental Sciences
Brandy Stewart, Sarah Nicholas, Sharon Bone, Ryan Tappero, Paul Eger, Cody Sheik, Brandy M. Toner
Summary: Low-cost and low-input water treatment systems are crucial for industrial stormwater remediation. Researchers found that the primary mechanism for chromium attenuation in the reactors is precipitation as Cr-Fe hydroxides combined with trivalent Cr adsorption onto peat surfaces.
JOURNAL OF ENVIRONMENTAL QUALITY
(2022)
Article
Soil Science
Jeonghwan Jang, Xianyi Xiong, Chang Liu, Kyungsoo Yoo, Satoshi Ishii
Summary: This study found that invasive earthworms have an impact on soil microbiomes and ecosystem functioning, particularly in nitrogen cycling. The degree of earthworm invasion and soil depth influenced the structures of microbiomes and the abundance of functional genes. In soils with minimal invasion, genes related to nitrification were more abundant, while in heavily invaded soils, genes related to denitrification and nitrogen fixation were more abundant.
SOIL BIOLOGY & BIOCHEMISTRY
(2022)
Article
Geochemistry & Geophysics
William S. Dowd, Christopher J. Schuler, Cara M. Santelli, Brandy M. Toner, Cody S. Sheik, Kelden Pehr, Jill M. McDermott
Summary: In isolated fracture networks in the Precambrian Shield, saline anoxic fluids produced through water and rock interactions host microbial communities that rely on anaerobic reactions for energy. Methane and other short-chain alkanes serve as electron donors, while sulfate, nitrate, and ferric iron act as alternative electron acceptors.
EARTH AND PLANETARY SCIENCE LETTERS
(2022)
Article
Microbiology
A. Soares, A. Edwards, D. An, A. Bagnoud, J. Bradley, E. Barnhart, M. Bomberg, K. Budwill, S. M. Caffrey, M. Fields, J. Gralnick, V. Kadnikov, L. Momper, M. Osburn, A. Mu, J. W. Moreau, D. Moser, L. Purkamo, S. M. Rassner, C. S. Sheik, B. Sherwood Lollar, B. M. Toner, G. Voordouw, K. Wouters, A. C. Mitchell
Summary: Our meta-analysis reveals that the microbial diversity in the terrestrial deep subsurface is dominated by Betaproteobacteria, Gammaproteobacteria, and Firmicutes, suggesting their diverse metabolic strategies as the reasons. Furthermore, a common small consortium of prevalent Betaproteobacteria and Gammaproteobacteria operational taxonomic units was found across various locations, implying a core deep subsurface community that plays a significant role in colonizing and sustaining microbial habitats. In silico contamination-aware analysis of the deep subsurface-derived sequencing data emphasizes the importance of downstream methods to ensure the reliability of conclusions. Understanding microbial diversity and ecological dynamics in the deep terrestrial subsurface is crucial for comprehending the microbial contribution to global subsurface element and nutrient cycling.
Article
Soil Science
Dolly Autufuga, Seth Quintus, Kyungsoo Yoo, Stephanie Day, Jennifer Huebert, Jonathan Deenik, Noa Kekuewa Lincoln
Summary: Soils and agriculture are closely related, especially in the Pacific islands. This study analyzed soil chemistry and vegetation patterns in the Manu'a islands of American Samoa, and found that soil fertility indicators had some application to the distribution of traditional agriculture. Agroforestry and arboriculture were key components of past agricultural practices.
Article
Oceanography
Rose Jones, Sarah Nicholas, Paul Northrup, Benjamin C. Bostick, Colleen Hoffman, Wen Hu, Phoebe J. Lam, Alessandra Leri, Brandy M. Toner, Benjamin S. Twining
Summary: Synchrotron instruments are valuable tools for marine studies, allowing nondestructive measurements of chemical composition and speciation on small sample volumes and at low concentrations. This article provides guidance for new users on accessing these instruments, designing appropriate experiments, and avoiding common pitfalls. Successful marine studies using synchrotron techniques are also presented.
Article
Environmental Sciences
Toshimi Nakajima, Mao Kuragano, Makoto Yamada, Ryo Sugimoto
Summary: This study compared the contribution of submarine groundwater discharge (SGD) to river nutrient budgets at nearshore and embayment scales, and found that SGD-derived nutrients become more important at larger spatial scales.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Fan Liu, Lei Zhang, Chongyang Zhang, Ziguang Chen, Jingguang Li
Summary: NO2 emissions from wall-mounted gas stoves used for household heating have become a significant source of indoor pollution in Chinese urban areas. The high indoor concentration of NO2 poses potential health risks to residents. It is urgently necessary to establish relevant regulations and implement emission reduction technologies to reduce NO2 emissions from wall-mounted gas stoves.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Letter
Environmental Sciences
Hans Peter H. Arp, Raoul Wolf, Sarah E. Hale, Sivani Baskaran, Juliane Gluege, Martin Scheringer, Xenia Trier, Ian T. Cousins, Harrie Timmer, Roberta Hofman-Caris, Anna Lennquist, Andre D. Bannink, Gerard J. Stroomberg, Rosa M. A. Sjerps, Rosa Montes, Rosario Rodil, Jose Benito Quintana, Daniel Zahn, Herve Gallard, Tobias Mohr, Ivo Schliebner, Michael Neumann
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Philomina Onyedikachi Peter, Binessi Edouard Ifon, Francois Nkinahamira, Kayode Hassan Lasisi, Jiangwei Li, Anyi Hu, Chang-Ping Yu
Summary: This study investigates the relationship between dissolved organic matter (DOM) and Rare Earth Elements (REEs) in sediments from Yundang Lagoon, China. The results show four distinct fluorescent components, with protein-like substances being the most prevalent. Additionally, the total fluorescence intensity and LREE concentrations exhibit a synchronized increase from Outer to Inner to Songbai Lake core sediments. The findings demonstrate a strong correlation between DOM content and pollution levels.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Surya Gupta, Pasquale Borrelli, Panos Panagos, Christine Alewell
Summary: The objective of this study is to incorporate soil hydraulic properties into the erodibility factor (K) of USLE-type models. By modifying and improving the existing equations for soil texture and permeability, the study successfully included information on saturated hydraulic conductivity (Ksat) into the calculation of K factor. Using the Random Forest machine learning algorithm, two independent K factor maps with different spatial resolutions were generated. The results show that the decrease in K factor values has a positive impact on the modeling of soil erosion rates.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Jesmin Akter, Wendy J. M. Smith, Yawen Liu, Ilho Kim, Stuart L. Simpson, Phong Thai, Asja Korajkic, Warish Ahmed
Summary: The choice of workflow in wastewater surveillance has a significant impact on SARS-CoV-2 concentrations, while having minimal effects on HF183 and no effect on HAdV 40/41 concentrations. Certain components in the workflow can be interchangeable, but factors such as buffer type, chloroform, and homogenization speed can affect the recovery of viruses and bacteria.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Yu Luo, Xueting Yang, Diwei Wang, Hongmei Xu, Hongai Zhang, Shasha Huang, Qiyuan Wang, Ningning Zhang, Junji Cao, Zhenxing Shen
Summary: Atmospheric PM2.5, which can generate reactive oxygen species (ROS), is associated with cardiorespiratory morbidity and mortality. The study found that both the mass concentration of PM2.5 and the DTT activity were higher during the heating season than during the nonheating season. Combustion sources were the primary contributors to DTT activity during the heating season, while secondary formation dominated during the nonheating season. The study also revealed that biomass burning had the highest inherent oxidation potential among all sources investigated.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Erin L. Murphy, Leah R. Gerber, Chelsea M. Rochman, Beth Polidoro
Summary: Plastic pollution has devastating consequences for marine organisms. This study uses a trait-based framework to develop a vulnerability index for marine mammals, seabirds, and sea turtles in Hawai'i. The index ranks 63 study species based on their vulnerability to macroplastic pollution, providing valuable information for species monitoring and management priorities.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Kenji Maurice, Amelia Bourceret, Sami Youssef, Stephane Boivin, Liam Laurent-Webb, Coraline Damasio, Hassan Boukcim, Marc-Andre Selosse, Marc Ducousso
Summary: Growing pressure from climate change and agricultural land use is destabilizing soil microbial community interactions. Little is known about microbial community resistance and adaptation to disturbances, hindering our understanding of recovery latency and implications for ecosystem functioning. This study found that anthropic disturbance and natural disturbance have different effects on the topology and stability of soil microbial networks.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Yunhao Li, Yali Feng, Haoran Li, Yisong Yao, Chenglong Xu, Jinrong Ju, Ruiyu Ma, Haoyu Wang, Shiwei Jiang
Summary: Deep-sea mining poses a serious threat to marine ecosystems and human health by disturbing sediment and transmitting metal ions through the food chain. This study developed a new regenerative adsorption material, OMN@SA, which effectively removes metal ions. The adsorption mechanism and performance of the material for metal ion fixation were investigated.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Antonio Medici, Margherita Lavorgna, Marina Isidori, Chiara Russo, Elena Orlo, Giovanni Luongo, Giovanni Di Fabio, Armando Zarrelli
Summary: Valsartan, a widely used antihypertensive drug, has been detected in high concentrations in surface waters due to its unchanged excretion and incomplete degradation in wastewater treatment plants. This study investigated the degradation of valsartan and identified 14 degradation byproducts. The acute and chronic toxicity of these byproducts were evaluated in key organisms in the freshwater trophic chain.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Jiang Lin, Lianbao Chi, Qing Yuan, Busu Li, Mingbao Feng
Summary: This study investigated the photodegradation behavior and product formation of two representative pharmaceuticals in simulated estuary water. The study found that the formed transformation products of these pharmaceuticals have potential toxicity on marine organisms, including oxidative stress and damage to cellular components.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Hua Fang, Dongdong Jiang, Ye He, Siyi Wu, Yuehong Li, Ziqi Zhang, Haoting Chen, Zixin Zheng, Yan Sun, Wenxiang Wang
Summary: This study revealed that exposure to lower levels of air pollutants led to decreased pregnancy rates, with PM10, NO2, SO2, and CO emerging as the four most prominent pollutants. Individuals aged 35 and above exhibited heightened susceptibility to pollutants.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Ali Shaan Manzoor Ghumman, Rashid Shamsuddin, Amin Abbasi, Mohaira Ahmad, Yoshiaki Yoshida, Abdul Sami, Hamad Almohamadi
Summary: In this study, inverse vulcanized polysulfides (IVP) were synthesized by reacting molten sulfur with 4-vinyl benzyl chloride, and then functionalized using N-methyl D-glucamine (NMDG). The functionalized IVP showed a high mercury adsorption capacity and a machine learning model was developed to predict the amount of mercury removed. Furthermore, the functionalized IVP can be regenerated and reused, providing a sustainable and cost-effective adsorbent.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Rita Bonfiglio, Renata Sisto, Stefano Casciardi, Valeria Palumbo, Maria Paola Scioli, Erica Giacobbi, Francesca Servadei, Gerry Melino, Alessandro Mauriello, Manuel Scimeca
Summary: This study investigated the presence of aluminum in human colon cancer samples and its potential association with biological processes involved in cancer progression. Aluminum was found in tumor areas of 24% of patients and was associated with epithelial to mesenchymal transition (EMT) and cell death. Additional analyses revealed higher tumor mutational burden and mutations in genes related to EMT and apoptosis in aluminum-positive colon cancers. Understanding the molecular mechanisms of aluminum toxicity may improve strategies for the management of colon cancer patients.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)