期刊
ORGANIC LETTERS
卷 21, 期 20, 页码 8488-8491出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03323
关键词
-
资金
- National Natural Science Foundation of China [21572024]
- Jiangsu Key Laboratory of Advanced Catalytic Materials Technology [BM2012110]
A catalyst-controlled selective functionalization of indoles with vinyl diazoacetates has been developed. The use of gold catalysts exclusively leads to C3-alkylation products, whereas the highly diastereoselective cyclopropanation reaction is dominant for silver catalysis. Importantly, the gold and silver vinylcarbenes exhibit highly carbenic rather than vinylogous reactivity in these transformations.
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