期刊
ORGANIC LETTERS
卷 21, 期 22, 页码 8874-8878出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02702
关键词
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A bulky three-hindered quadrant bisphosphine ligand, di-1-adamantylphosphino(tert-butylmethylphosphino)methane, named BulkyP*, has been synthesized via a convergent short pathway with chromatography-free procedures. The ligand is a crystalline solid and can be readily handled in air. Its rhodium(I) complex exhibits very high enantioselectivities and catalytic activities in the asymmetric hydrogenation of functionalized alkenes.
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