Article
Geosciences, Multidisciplinary
Abbas Shahrabadi, Parham Babakhani Dehkordi, Fatemeh Razavirad, Reza Noorimotlagh, Masoud Nasiri Zarandi
Summary: The study found that low salinity water injection has a significant effect on releasing trapped oil, and smart water flooding achieves the maximum oil recovery. Low salinity water and smart water have a significant impact on relative permeability curves, indicating wettability alteration.
NATURAL RESOURCES RESEARCH
(2022)
Article
Energy & Fuels
Yang Zhou, Lijun You, Yili Kang, Changgui Jia, Bo Xiao
Summary: Lacustrine shale with high clay mineral content and heterogeneity is difficult to hydraulic fracture and stimulate effectively. This study focuses on the spontaneous imbibition properties of lacustrine shale and suggests technical countermeasures to improve the complexity of fracture networks. The main influencing factor is the imbibition and diffusion ability of fluid, and clay stabilizer should be added to avoid formation damage caused by clay minerals.
Article
Chemistry, Multidisciplinary
Xueping Zhang, Youquan Liu, Yuzhou Liu, Chuanrong Zhong
Summary: This study quantitatively investigates the imbibition characteristics of fracturing fluids in tight sandstone reservoirs through high-precision fluid spontaneous imbibition experiments. The results show that the tight sandstone samples have strong imbibition capacity and fast imbibition rate, with surface tension being the main controlling factor. This research is important for understanding the absorption mechanism of fracturing fluids in tight sandstone reservoirs and predicting flowback rates.
Article
Energy & Fuels
Tufan Ghosh, Yashwanth Kumar Gujjala, Debasis Deb, G. P. Raja Sekhar
Summary: This study investigates the co-current spontaneous imbibition in two-dimensional reservoir formations. The anisotropic ratio between the vertical and horizontal intrinsic permeability significantly affects the recovery dynamics. Cross-flow behavior leads to early water breakthrough and bypassing of oil/non-wetting phase. The onset of forced imbibition is regulated by the mean pressure distribution of the underground formation.
GEOMECHANICS AND GEOPHYSICS FOR GEO-ENERGY AND GEO-RESOURCES
(2022)
Review
Energy & Fuels
Marzhan Karimova, Razieh Kashiri, Peyman Pourafshary, Randy Hazlett
Summary: Fluid flow in naturally fractured reservoirs is complex and heterogeneous, and understanding fracture-matrix interactions is crucial. Fluid movement between fractures and matrix occurs through spontaneous imbibition, which can be affected by wettability. Low-salinity water injection is considered as an effective enhanced oil recovery approach for fractured and non-water-wet carbonate rocks. This review summarizes experimental and numerical studies on the imbibition process and highlights the need for further research on wettability alteration and simulation models for co/countercurrent flows in naturally fractured reservoirs.
Article
Mathematics, Interdisciplinary Applications
Jianhong Zhu, Junbin Chen, Xiaoliang Duanmu, Xiaoming Wang, Diguang Gong, Xiangrong Nie
Summary: Based on HPMI experiments and NMR analyses, this study quantitatively evaluated the pore-size distribution of a shale oil reservoir in Ordos Basin. The results showed strong heterogeneity and micro-nano characteristics, with micropores and mesopores accounting for over 90% of the volume. The imbibition water content was highest in micropores, followed by mesopores, while macropores had the lowest content.
FRACTAL AND FRACTIONAL
(2023)
Article
Energy & Fuels
Ahmed Kasha, Bastian Sauerer, Hasan Al-Hashim, Wael Abdallah
Summary: The study reveals that modifying the ionic composition of injection water significantly impacts oil recovery from carbonate reservoirs, with SO42- ions having a profound influence on surface charges of limestone.
Article
Energy & Fuels
Zhen Liu, Dawei Zhao, He Yang, Guangming Li, Wenyu Wang
Summary: By simulating the migration and wetting process of water and coal grains through inverse spontaneous imbibition experiments, the study reveals the impact of grain size and metamorphic grade on imbibition effect. It suggests improvements to traditional mathematical models and provides theoretical guidance for enhancing hydraulic techniques.
Article
Energy & Fuels
Agihtias Salam, Xiuyu Wang
Summary: In this study, a new analytical model of spontaneous imbibition height in low-permeability reservoirs was derived, considering various factors such as effective viscosity, surface roughness, slip, and gravity effects in a single tortuous capillary tube. The analytical model showed good agreement with experimental results from literatures in typical low-permeability core samples. Sensitivity studies indicated that parameters like surface fractal dimension, effective viscosity, and contact angle have an inverse relationship with imbibition height on rough surfaces, while pore radius, interfacial tension, and slip length have a proportional relationship with imbibition height. Neglecting slip effects may lead to underestimation of imbibition height in nanopore sizes. The presented models provide clear physical interpretations for each parameter affecting imbibition height performance.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Physics, Multidisciplinary
Dazhong Ren, Litao Ma, Dengke Liu, Jing Tao, Xueqing Liu, Rongjun Zhang
Summary: This research systematically analyzed the physical properties and thin-section images of tight sandstone reservoirs and examined the efficiency of spontaneous imbibition through core tests. The results showed that quartz and feldspar predominantly contributed to mineralogy, and low brine salinity, high oil viscosity, and high interfacial tension were associated with strong spontaneous imbibition ability and fast process. High interfacial tension was identified as the dominant controlling factor in this field. Furthermore, the parameter simulation model established using the dimension reduction method provided a reliable prediction of spontaneous imbibition efficiency.
FRONTIERS IN PHYSICS
(2022)
Article
Chemistry, Physical
Ehsan Shahbazi, Ali Moradzadeh, Sabber Khandoozi, Masoud Riazi
Summary: This study investigates the synergistic effect of a modified brine solution and a cationic surfactant on the wettability of carbonate rock formations. The results demonstrate that these chemicals can alter the wettability from oil-wet to water-wet, leading to a significant increase in oil recovery. Additionally, different scenarios for low oil recovery during surfactant imbibition are considered, including variations in surfactant concentration, oil snap-off phenomenon, and asphaltene deposition and pore plugging.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Multidisciplinary
Dawei Liu, Chong Lin, Boyun Guo, Quanwen Liu, Fubo Ma, Qi Wang, Chengxing Wei, Lin Wang, Dongmin Jia
Summary: Formation damage caused by the injected working fluid reduces the production of coalbed methane (CBM) wells. The traditional method to evaluate the severity of formation damage focuses on permeability, but neglects the damage caused by the pure liquid phase of the working fluid on the gas transport process of CBM. Therefore, a multiscale working fluid filtrate damage evaluation method was proposed in this study, which demonstrated significant damage to the desorption-diffusion and seepage ability of CBM by pure liquids with different pH values and salinities.
Article
Chemistry, Multidisciplinary
Dawei Liu, Boyun Guo, Quanwen Liu, Fubo Ma, Qi Wang, Chengxing Wei, Lin Wang, Dongmin Jia, Chong Lin
Summary: Formation damage caused by the injected working fluid affects the production of coalbed methane wells. The severity of damage to coal has been evaluated using permeability as a parameter, but less attention has been given to the formation damage from the liquid phase of the working fluid. In this study, a multiscale working fluid filtrate damage evaluation method is proposed to evaluate high-rank coal in China. The results show that different liquids significantly damage the desorption-diffusion and seepage ability of coal, and the damage severity in the seepage process is higher. Effective channel reduction and resistance increase in gas transport are the mechanisms of working fluid filtrate-induced formation damage.
Article
Mathematics, Interdisciplinary Applications
Guanqun LI, Yuliang Su, Wendong Wang
Summary: Large-scale hydraulic fracturing is crucial for efficient shale oil production, but the mechanisms of fracturing fluid flow in shale micropores and the impact of shale microstructure and physical properties are not well understood. This lack of understanding hinders the optimization of fracturing flowback and limits shale oil recovery enhancement. This study analyzes the characteristics of shale pores using SEM and XRD experiments, finding multiple pore types including organic pores, brittle mineral pores, and clay pores. The study investigates the influence of cross-section shapes on capillary force and analyzes the dynamics of imbibition in different pore types. A shale semi-analytical solution that considers imbibition time, fluid properties, pore cross-section shapes, tortuosity, and forced pressure is established using a shale multi-pores physical model and fractal theory.
FRACTALS-COMPLEX GEOMETRY PATTERNS AND SCALING IN NATURE AND SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Yuejie Wang, Huiqing Liu, Yu Li, Qing Wang
Summary: The research established a spontaneous imbibition model for tight reservoirs, verified its reliability through experiments, and found variations in imbibition area and recovery under different boundary conditions. The superimposed effect can not only enhance oil washing efficiency but also inhibit the spread of the imbibition area.
Article
Engineering, Chemical
Aliasghar Parsaie, Mohammad Mohammadi-Khanaposhtani, Masoud Riazi, Yousef Tamsilian
SEPARATION AND PURIFICATION TECHNOLOGY
(2020)
Article
Chemistry, Multidisciplinary
Hossein Salmanvandi, Parizad Rezaei, Yousef Tamsilian
Article
Chemistry, Physical
A. Maghsoudian, A. Esfandiarian, S. Kord, Y. Tamsilian, B. Soltani Soulgani
JOURNAL OF MOLECULAR LIQUIDS
(2020)
Article
Energy & Fuels
Tahoura Ahsani, Yousef Tamsilian, Alireza Rezaei
Summary: The adsorption of hydrolyzed polyacrylamide on carbonate surface was investigated by molecular dynamic simulation and experimental procedure, showing that polymer adsorption decreased the water contact angle, resulting in a moderately oilwet state and good agreement with experimental results. This opens up opportunities for further molecular dynamic investigations of different polymers as wettability modifiers during EOR processes.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2021)
Article
Chemistry, Physical
Aliasghar Parsaie, Yousef Tamsilian, Majid Rahimi Pordanjani, Abdolreza Kazemi Abadshapoori, Gordon McKay
Summary: A novel superhydrophobic/superoleophilic spongy absorbent has been developed using polyurethane sponge coated with zinc stearate and phenol-formaldehyde resin, providing excellent oil absorption capacity and superhydrophobicity. Characterization analysis confirmed the rough surface and chemical hydrophobicity of the coated sponge. The product demonstrated efficient absorption rates and capacities for a wide range of oils and solvents, depending on the different sponge densities.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Energy & Fuels
Ali Esfandiarian, Ali Maghsoudian, Mahsa Shirazi, Yousef Tamsilian, Shahin Kord, James J. Sheng
Summary: This study analyzed the performance of three imidazolium-based ionic liquids in reducing the interfacial tension between crude oil and IL solutions under a wide range of salinities. It was found that longer alkyl chain ILs accumulated more at the solution interface under high ionic strength conditions, leading to a greater reduction in IFT. Additionally, under low salinity conditions, longer alkyl chain IL exhibited a lower IFT value in diluted seawater compared to diluted formation water.
Article
Chemistry, Physical
A. Maghsoudian, Y. Tamsilian, S. Kord, B. Soltani Soulgani, A. Esfandiarian, M. Shajirat
Summary: This study focused on the application of a hydrophobically modified copolymer (HSPAM) in enhanced oil recovery under harsh reservoir conditions. Through analysis and experiments, it was found that HSPAM showed better stability and wettability compared to HPAM, which resulted in improved oil recovery mechanisms and ultimately led to a higher ultimate recovery rate.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Engineering, Chemical
Yousef Tamsilian, Zeinab Ansari-Asl, Ali Maghsoudian, Abdolreza Kazemi Abadshapoori, Amaia Agirre, Radmila Tomovska
Summary: This study developed superhydrophobic nanocomposite sponges based on PU sponges coated with ZIF8 and PDMS to enhance hydrophobicity while maintaining mechanical strength and porous structure, achieving excellent oil/water separation performance.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2021)
Article
Chemistry, Physical
Amirhossein Fadavi Firooz, Abdolnabi Hashemi, Ghasem Zargar, Yousef Tamsilian
Summary: In this study, molecular dynamics simulations were used to investigate the wettability effects of different types of silicon dioxide nanoparticles in the Nano-EOR process at a microscopic scale. The results showed that Type II nanoparticles exhibited a suitable dispersion on the surface and reduced the oil contact angle in less time compared to other types of nanoparticles, demonstrating different modification mechanisms of calcite surface wettability.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Khadijeh Khederlou, Reza Bagheri, Akbar Shojaei, Nathalie Gontard, Yousef Tamsilian
Summary: This study reports the production of a hybrid nanostructure based on iron nanoparticles on montmorillonite nanoclays as an oxygen scavenger and barrier additive in polymeric packaging materials. The interactions between iron nanoparticles and montmorillonite nanoclays were demonstrated to effectively limit particle growth and agglomeration, resulting in smaller nanoparticles with higher specific surface area. Different solvent and primary cation types showed different preferences in interacting with the nanoclays, leading to different site selection. The results suggest the possibility of tailoring the properties of the hybrid nanoparticles for specific applications.
Article
Energy & Fuels
Ali Esfandiarian, Ali Maghsoudian, Afshin Davarpanah, Yousef Tamsilian, Shahin Kord
Summary: A new method was introduced in this study to measure ultra-low interfacial tension, using needles with different outer diameters to provide a wide range of surface and interfacial tension values from ultra-low to high. Furthermore, a comprehensive table was created based on the results to assist researchers in selecting the best needle for their experiments.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Energy & Fuels
Mahsa Shirazi, Mohsen Masihi, Hassan Mahani, Yousef Tamsilian
Summary: This study artificially created surfaces that simulate natural porous structures on flat glass substrates using various methods. The impact of high temperature on surface roughness and topography was also investigated. Laser ablation resulted in a homogenous distribution of roughness, while HF etching led to a wide range of roughness values that varied with exposure time. Applying etching cream reduced roughness. No significant changes in chemical composition were observed for the etched surfaces.
Article
Polymer Science
Aliasghar Parsaie, Masoud Riazi, Abdolreza Kazemi Abadshapoori, Mohammad Mohammadi-Khanaposhtani, Yousef Tamsilian
Summary: This study focused on the effects of sponge density and magnesium stearate loadings on the separation performance of superhydrophobic magnesium stearate coated-polyurethane. The results showed that the surface of the sponge became rougher after being coated with magnesium stearate, while the sponge density had no significant impact on the water contact angle and oil absorption rate. The absorption capacity of the modified sponges for various oils and solvents was also tested and showed promising results.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Applied
Khadijeh Khederlou, Mohammadjavad Eslamian, Akbar Shojaei, Reza Bagheri, Yousef Tamsilian
Summary: Polyolefin-blend/clay nanocomposites based on LDPE, LLDPE, and OC were prepared by melt extrusion. PE-g-MA was used as a compatibilizer and its effects on LDPE/LLDPE crystallization behavior and morphology were investigated. Results showed that OC and compatibilizer are localized at the interface of LDPE and LLDPE phases, and their presence improves the tensile properties of the nanocomposites by influencing the crystalline structure development.
JOURNAL OF VINYL & ADDITIVE TECHNOLOGY
(2023)
Article
Chemistry, Analytical
Fatemeh Kardani, Roya Mirzajani, Yousef Tamsilian, Alireza Kiasat, Farnoosh Bakhshandeh Farajpour
Summary: In this study, immunoaffinity columns based on metal-organic framework (MOF) and molecular imprinted polymers (MIPs) were synthesized for the extraction and preconcentration of aflatoxins AFB1, AFB2, AFG1, and AFG2 using deep eutectic solvents (DES). The parameters affecting the extraction efficiency were optimized using the one factor at a time (OFAT) method. The method showed low limits of detection, good linearity, and acceptable relative standard deviations (RSDs). It was successfully applied to quantify aflatoxin in cereal samples.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Physical
Rajalaxmi Sahoo, C. Reshma, D. S. Shankar Rao, C. V. Yelamaggad, S. Krishna Prasad
Summary: This study investigates the influence of the flexible spacer parity of a guest photoactive liquid crystalline dimer on the photonic bandgap features of the cholesteric and twist grain boundary smectic C phases of the host molecule. The results show that the parity of the photoactive dimer affects the width of the photonic bandgap and the blue-shift of the cholesteric phase. Additionally, the parity of the dimer also affects the layer spacing and two-dimensional periodicity of the liquid crystalline phases.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Sara Rozas, Alberto Gutierrez, Mert Atilhan, Alfredo Bol, Santiago Aparicio
Summary: This study presents a multiscale theoretical investigation on the use of bifunctional hydrophobic Deep Eutectic Solvent for carbon capture using tetrapropylammonium chloride, acetic acid, and ethanolamine. The characterization includes nanoscale analysis of CO2 absorption mechanisms and changes in liquid phase properties during gas capture.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Tabouli Eric Da-yang, Alhadji Malloum, Jean Jules Fifen, Mama Nsangou, Jeanet Conradie
Summary: In this study, the potential energy of different glycine tautomers and their interaction with Cu2+ cations was investigated. The results showed that the solvation medium and the presence of Cu2+ cations influenced the stability of glycine tautomers.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Xiaoliang Gou, Nan Ye, Qingqing Han, Junjie Cui, Long Yi Jin
Summary: In this study, amphiphilic rod-coil molecules with rigid DSA parts and flexible oligoether chains were designed and their assembly capacities were investigated. The morphology of the molecular aggregates was influenced by the pH of the solution and UV light, and the aggregates showed adsorption capacity for nitroaromatic compounds.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Shuang Liu, Liyan Shan, Cong Qi, Wenhui Zhang, Guannan Li, Bei Wang, Wei Wei
Summary: Optimizing the design of styrene-butadiene-styrene copolymer (SBS) is crucial for producing cost-effective SBS modifiers and improving road quality. This study examined the influence of SBS content and molecular structure on viscosity and compatibility. The results showed that the viscosity contribution of SBS is determined by its molecular structure and phase morphology.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Artem A. Petrov, Ekaterina A. Titova, Aydar A. Akhmadiyarov, Ilnaz T. Rakipov, Boris N. Solomonov
Summary: This work focuses on the thermochemistry of solvation of azeotropes. The enthalpies of dissolution of azeotropes in different mediums were determined, and the impact of the structure of the azeotropes on their properties in solution was discussed. A correlation between enthalpies of solvation and molar refraction was used to determine the vaporization enthalpies of azeotropes for the first time. The results were found to be consistent with literature data, obtained using direct and calculated methods. These findings contribute to the analysis of the structure-property relationships of azeotropes.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
L. V. Kamaeva, E. N. Tsiok, N. M. Chtchelkatchev
Summary: Understanding the correlations between liquids and solids allows us to predict the thermodynamic parameter range favorable for the formation of intriguing solid phases by studying liquids. In this study, we experimentally and theoretically investigated an Al-Cu-Co system within different composition ranges, and identified high-temperature solid phases. Our findings demonstrated the correlation between the boundaries of different solid phases and undercooling and viscosity in the concentration area.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
R. Aneesh Kumar, S. Jamelah Al-Otaibi, Y. Sheena Mary, Y. Shyma Mary, Nivedita Acharjee, Renjith Thomas, Renjith Raveendran Pillai, T. L. Leena
Summary: In this study, the interactions between doped and pristine coronenes and adenine nucleobases were investigated using Density Functional Theory. The optimal configurations, adsorption energies, charge transfer, and electrical properties of each complex were calculated. It was found that doped coronene had stronger adsorption strength and charge transfer compared to pristine coronene. The stability of the complexes was attributed to non-covalent interactions in the interactive region. The change in electrical conductivity of coronenes after adsorption suggested their sensitivity towards DNA bases. The predicted energy gap and prolonged recovery time for adenine-coronene configurations indicated the potential application of pristine/doped coronene in DNA detection.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Gang Zhou, Yongwei Liu, Biao Sun, Zengxin Liu, Cuicui Xu, Rulin Liu, Qi Zhang, Yongmei Wang
Summary: The CFD-DEM method was used to simulate the dust deposition pattern in the bronchus of anchor digging drivers, revealing the highest dust concentration in the vortex region of the working face. The study also found a positive correlation between dust particle diameter and bronchial deposition rate, and a negative correlation with alveolar deposition rate.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Yan Zhang, Yafei Luo, Lingkai Tang, Mingyan E, Jianping Hu
Summary: This study investigates the effects of different transition metal decorations on B12N12 nanocages on the adsorption properties of nitrosourea drugs using computational methods. The results reveal the presence of weak non-covalent interactions between metals and nanocages, and the interaction between drugs and nanocages plays a significant role in drug adsorption. Compared to free drugs, the adsorption of drugs on nanocages can facilitate electron transfer, reduce energy gaps and chemical hardness, indicating activity at the target site.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
C. I. Alcolado, J. Poblete, L. Garcia-Rio, E. Jimenez, F. J. Poblete
Summary: In this study, the selective oxidation of aromatic aldehydes was investigated using Ru(VI) as a catalyst and hexacyanoferrate (III) as a cooxidant in an alkaline medium. The reaction mechanism involves complex reaction orders for the oxidant and the aromatic aldehyde, while the reaction order for Ru(VI) is one. The proposed mechanism includes two catalytic cycles and the formation and decomposition of complexes. Quantitative structure-activity relationship analysis showed that deactivating groups in the para-position enhance the process.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Inez A. Barbieri, Marcos L. S. Oliveira, Franciele S. Bruckmann, Theodoro R. Salles, Leonardo Zancanaro, Luis F. O. Silva, Guilherme L. Dotto, Eder C. Lima, Mu. Naushad, Cristiano R. Bohn Rhoden
Summary: This study evaluated the adsorption of zolpidem on magnetic graphene oxide and synthesized magnetic graphene oxide adsorbents for zolpidem removal. The best magnetic nanoadsorbent was found to have a removal percentage of 87.07% at specific pH and temperature conditions. The results suggest that the removal of zolpidem is related to the surface chemistry of the adsorbent rather than the surface area of graphene oxide. The adsorbent showed excellent adsorption efficiency and magnetic behavior, making it a promising material for removing zolpidem from aqueous solutions.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Hongyan Huang, Chunquan Li, Siyuan Huang, Yuling Shang
Summary: This study examines the sensitivity of the thermal conductivity of water-based alumina nanofluids to changes in concentration, sphericity, and temperature. The results show that volume fraction and temperature have a significant impact on the thermal conductivity, while sphericity also needs to be considered. A support vector machine regression model was created to analyze the sensitivity of the thermal conductivity to different parameters. The findings indicate that temperature, sphericity, and volume fraction are the most sensitive variables.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Correction
Chemistry, Physical
V. M. Pergamenshchik, T. Bryk, A. Trokhymchuk
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Valentyn Rudenko, Anatolii Tolochko, Svitlana Bugaychuk, Dmytro Zhulai, Gertruda Klimusheva, Galina Yaremchuk, Tatyana Mirnaya, Yuriy Garbovskiy
Summary: This paper reports on the synthesis, structural characterization, spectral and nonlinear-optical properties of glass nanocomposites made of glass forming ionic liquid crystals and nanoparticles. The study reveals that by exciting the nanocomposites within their absorption band, a control over effective optical nonlinearities can be achieved, allowing the modification of the magnitude and sign of the effective nonlinear absorption coefficient. The proposed strategy using metal-alkanoates based glass-forming ionic liquid crystals and nanoparticles shows great potential for the development of nanophotonics and plasmonics technologies.
JOURNAL OF MOLECULAR LIQUIDS
(2024)