期刊
INORGANIC CHEMISTRY
卷 58, 期 22, 页码 15637-15643出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b02717
关键词
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资金
- National Natural Science Foundation of China [21801187, 21805109, 21871105]
- Science & Technology Development Fund of Tianjin Education Commission for Higher Education [2017KJ127]
- Doctoral Program Foundation of Tianjin Normal University [043135202-XB1702]
A double-walled MOF [Zn-5(mu(3)-OH)(2) (DBTA)(2)(H2O)(4)]center dot solvents [1, H(4)DBTA = 2,2'-dihydroxy-1,1'-binaphthyl-3,3',6,6'-tetrakis-(4-benzoic acid)] has been designed and constructed based on a rare Zn-5 cluster. The resultant sample has enrichment of porous structure with high BET and Langmuir surface area. By virtue of multiaperture structure and plentiful catalytic sites of Bronsted (-OH) and Lewis acidic (Zn-II), MOF 1 is a unique catalyst to synthesize cyclic carbonates from CO2 and epoxides with preferable repeatability.
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