期刊
FUEL
卷 253, 期 -, 页码 1130-1139出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2019.05.095
关键词
CCS; Pressure swing adsorption; Pre-combustion; Activated carbon; Monoethanolamine
资金
- Brazilian National Council for Scientific and Technological Development (CNPq) from the program Science Without Borders (SwB) [206095/2014-7]
- EPSRC
- Centre for Doctoral Training of Carbon Capture and Storage and Cleaner Fossil Energy [EP/L016362/1]
Pressure swing adsorption (PSA) demonstrates high potential for capturing pre-combustion carbon dioxide in Integrated Gasification Combined Cycle (IGCC) power plants, due to a binary mixture of hydrogen and carbon dioxide entering the separation process. In this work, a seven-step PSA model was developed and compared to adsorption experiments under PSA conditions (25 bar and ambient temperatures) performed with tetraethylenepentamine (TEPA) and a novel blend of monoethanolamine-monodiethanolamine (MEA-MDEA) modified activated carbons, using nitrogen and carbon dioxide mixtures. The MEA-MDEA modified activated carbon showed promising results for pre-combustion PSA processes, due to their high carbon dioxide adsorption capacity and delayed break-point of about 200 s compared to the unmodified activated carbons. A sensitivity analysis carried out for the adsorbent parameters in a seven-step PSA process showed that high mass transfer coefficient values yielded to highly purified products, specifically for the light product stream (99.4%). A sensitivity analysis of the process variables showed that purity values of the heavy stream (carbon dioxide) were over 90% when the purge pressure was reduced to 0.5 bar and the carbon dioxide feed fraction increased to 60%.
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