4.6 Article

Translucent and adsorptive PVA thin film containing microfibrillated cellulose intercalated with TiO2 nanoparticles for dye removal

出版社

ELSEVIER
DOI: 10.1016/j.colsurfa.2019.123590

关键词

Microfibrillated cellulose; TiO2 nanoparticles; Polyvinyl alcohol; Photodegradation; Thin film

资金

  1. Universiti Sains Malaysia [MRUN Rakan-RU-2019-004/2]

向作者/读者索取更多资源

Photocatalyst, TiO2 nanoparticles were blended into polyvinyl alcohol (PVA) dope solution containing microfibrillated cellulose (MFC) before polymerization and curing to create photocatalytic composite. Transmittance electronic microscopy (TEM) image showed that MFC reduced the agglomeration and improved the dispersion of TiO2 nanoparticles. Although exhibiting the similar Fourier transform infrared spectroscopy spectra and thermogravimetric analysis thermogram, the light transmittance and electrical conductivity of PVA-TiO2-microfibrillated cellulose (PVA-TC) thin film achieved slight improvement of light transmittance and electrical conductivity compared to PVA-TiO2 (PVA-T) thin film due to the reduction of particle agglomeration. Although MFC limited the water uptake or film swelling by restricting the mobility of molecular chains, MFC formed hydrogen bonding with PVA to strengthen the thin films, up to 237% improvement of tensile strength was observed by comparing PVA-TC and PVA-T thin films. All these thin films showed dense and non-porous structure as shown in scanning electronic microscopy images and TiO2 nanoparticles were dispersed on the surface as proven in the Energy dispersive X-ray analysis results. TiO2 nanoparticles only adsorbed 12% of methylene blue (MB) in aqueous solution, but PVA-TC thin film adsorbed up more than 90% of MB in 15 min. The fast adsorption kinetics of this composite film resulted in photocatalytic enhancement. Under UV irradiation, PVA-TC thin film could remove 91.45% of MB within 10 min. Besides maintaining the dye removal efficiency up to 10 cycles, this composite film could be also decolorized near to 50% based on light transmittance.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Correction Chemistry, Physical

N-modified carbon quantum dot in 3D-network of microfibrillated cellulose for building photoluminescent thin film as tartrazine sensor (vol 389, 112286, 2020)

H. K. Melvin Ng, G. K. Lim, C. P. Leo

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2020)

Article Environmental Sciences

Sustainable cultivation of Navicula incerta using cellulose-based scaffold incorporated with nanoparticles in air-liquid interface cultivation system

Jia Xin Yap, C. P. Leo, Nazlina Haiza Mohd Yasin, C. J. C. Derek

Summary: This study synthesized cellulose-based scaffolds with nanoparticles added to support the growth of microalgae, with the cellulose membrane scaffold with TiO2 showing the highest growth rate for Navicula incerta. The results demonstrate the potential of cellulose-based scaffolds with TiO2 for effective plant cell culture.

CHEMOSPHERE (2021)

Article Chemistry, Multidisciplinary

Surface Modification of Polytetrafluoroethylene Hollow Fiber Membrane for Direct Contact Membrane Distillation through Low-Density Polyethylene Solution Coating

Mohamad Razif Mohd Ramli, Abdul Latif Ahmad, Choe Peng Leo

Summary: The hydrophobic coating of LDPE on the PTFE membrane creates a fine nanostructure, enhancing membrane hydrophobicity and permeability flux while resolving membrane wetting issues. Coated membranes with different LDPE concentrations exhibit higher water contact angles and liquid entry pressure values than uncoated membranes.

ACS OMEGA (2021)

Article Energy & Fuels

Hydrogen separation using polybenzimidazole membrane with palladium nanoparticles stabilized by polyvinylpyrrolidone

Hani Shazwani Mohd Suhaimi, Choe Peng Leo, Abdul Latif Ahmad

Summary: This study breaks through the limitations of the selectivity-permeability trade-off boundary in hydrogen separation by incorporating Pd nanoparticles into PBI membranes. The Pd nanoparticles blended into PBI membrane show improved ideal H-2/CO2 selectivity and surpass the upper bound Robeson plot at high temperatures.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2021)

Article Engineering, Chemical

Superhydrophobic PVDF/micro fibrillated cellulose membrane for membrane distillation crystallization of struvite

Hoi-Fang Tan, Why-Ling Tan, B. S. Ooi, C. P. Leo

Summary: This study successfully enhanced phosphate recovery in MDC by modifying PVDF/MFC membrane, achieving a high water contact angle, relatively large pore size, and satisfactory porosity, ensuring stable permeate flux in MDC.

CHEMICAL ENGINEERING RESEARCH & DESIGN (2021)

Article Environmental Sciences

Stability evaluation and formula optimization of cellulose-based scaffold for the air-liquid interface cultivation of Navicula incerta

Jia Xin Yap, C. P. Leo, Nazlina Haiza Mohd Yasin, Pau Loke Show, C. J. C. Derek

Summary: By adjusting TiO2 loading and casting gap, the stability of regenerated cellulose culture scaffolds was enhanced in this study, leading to improved surface hydrophilicity and porosity of the membrane scaffolds. The optimal cellulose membrane scaffold with TiO2 loading of 0.5 wt% and thickness of 100 μm achieved the highest N. incerta growth rate and exhibited good membrane stability.

ENVIRONMENTAL RESEARCH (2021)

Article Chemistry, Multidisciplinary

Carbon dioxide conversion into calcium carbonate nanoparticles using membrane gas absorption

Why-Ling Tan, Hoi-Fang Tan, A. L. Ahmad, C. P. Leo

Summary: Mineral carbonation in an aqueous solution is a practical strategy in CCUS, and wet carbonation can be used to produce calcium carbonate nanoparticles with vast applications. The use of porous membranes in MGA enhances the mass transfer of CO2 gas into liquid absorbent for the carbonation of calcium-rich solution.

JOURNAL OF CO2 UTILIZATION (2021)

Review Energy & Fuels

Ionic liquid-modified materials as polymer electrolyte membrane and electrocatalyst in fuel cell application: An update

Norazuwana Shaari, Nor Naimah Rosyadah Ahmad, Raihana Bahru, Choe Peng Leo

Summary: Ionic liquids show promise as solvents for various applications due to their high conductivity and stability, with this review focusing on incorporating ILs into fuel cell systems. Improving polymer electrolyte membranes and electrocatalysts with IL additives is crucial for enhancing fuel cell performance.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2022)

Article Chemistry, Multidisciplinary

Non-solvent Flux Augmentation of an LDPE-Coated Polytetrafluoroethylene Hollow Fiber Membrane for Direct Contact Membrane Distillation

Mohamad Razif Mohd Ramli, Abdul Latif Ahmad, Ebenezer Idowu Oluwasola, Choe Peng Leo

Summary: This study successfully enhanced the water permeation flux of the PTFE HF membrane by modifying its surface and achieved high rejection for NaCl. The modified membrane exhibited high stability and wetting resistance during the MD process, with lower energy consumption compared to traditional distillation, making it more economically feasible.

ACS OMEGA (2021)

Review Environmental Sciences

An assessment of technological development and applications of decentralized water reuse: A critical review and conceptual framework

Geetha Maniam, Nur Ain Zakaria, Choe Peng Leo, Vasilena Vassilev, Karen Banahene Blay, Kourosh Behzadian, Phaik Eong Poh

Summary: This article reviews various products for rainwater harvesting and greywater treatment and reuse on laboratory, pre-commercialization scale, and commercialized products. A conceptual framework is proposed to facilitate decision making for suitable decentralized water reclamation solutions. Decentralized systems are crucial in reducing dependence on centralized water supply.

WILEY INTERDISCIPLINARY REVIEWS-WATER (2022)

Article Environmental Sciences

Air-liquid interface cultivation of Navicula incerta using hollow fiber membranes

Jia Xin Yap, C. P. Leo, Derek Juinn Chieh Chan, Nazlina Haiza Mohd Yasin, Pau Loke Show

Summary: This study investigates the improvement of air-liquid interface cultivation of Navicula incerta using rearranged polyethersulfone (PES) and poly (vinylidene fluoride) (PVDF) hollow fiber membranes. The results show that PVDF hollow fiber membranes have a greater improvement in N. incerta cell growth rate compared to PES hollow fiber membranes. Furthermore, PVDF membranes significantly promote the growth of microalgae N. incerta through the air-liquid interface system, leading to potential applications in wastewater treatment.

CHEMOSPHERE (2022)

Article Engineering, Chemical

Electrochemical cleaning of superhydrophobic polyvinylidene fluoride/polymethyl methacrylate/carbon black membrane after membrane distillation

N. A. Zakaria, S. Q. Zaliman, C. P. Leo, A. L. Ahmad, B. S. Ooi, Phaik Eong Poh

Summary: In this study, the addition of PMMA, carbon black, and/or conductive ink improved the morphology and electrochemical properties of PVDF membranes, resulting in high permeate flux and stable salt rejection in membrane distillation.

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS (2022)

Review Engineering, Civil

Recent development, utilization, treatment and performance of solid wastes additives in asphaltic concrete worldwide: A review

Tracy Leh Xin Wong, Mohd Rosli Mohd Hasan, Leo Choe Peng

Summary: This article reviews the application of waste material recycling in improving the performance of asphalt pavements and emphasizes the improvement of material properties through chemical treatments. This research is important for cost-saving, efficient waste management, and achieving higher commercial feasibility.

JOURNAL OF TRAFFIC AND TRANSPORTATION ENGINEERING-ENGLISH EDITION (2022)

Article Chemistry, Applied

Polysaccharide Hydrogels for Controlling the Nutrient Release

Jialin Fu, Jia Xin Yap, C. P. Leo, Chun Kiat Chang, Pau-Loke Show

Summary: This review compares the loading and release of different nutrients from polysaccharide hydrogels for fertilizing purposes. Various methods were studied to control the release of urea, nitrogen sources, phosphate, and potassium from the hydrogels. However, most of the polysaccharide hydrogels did not meet the nutrient release standards. Additionally, utilizing polysaccharide-rich waste and nutrients in wastewater can further reduce the cost.

SEPARATION AND PURIFICATION REVIEWS (2023)

Article Energy & Fuels

Fabrication of hybrid tin oxide-cellulose nanocomposite as the flexible and thin supercapacitor

Iswary Letchumanan, Choe Peng Leo, Swee-Yong Pung, Chee Meng Koe, Norazuwana Shaari, Yusra Nadzirah Yusoff

Summary: A hybrid tin oxide-cellulose nanocomposite was produced and coated on microfibrillated cellulose (MFC) thin films to form a supercapacitor. The hybrid tin oxide-cellulose thin films were structurally analyzed using various techniques. The cellulose thin film with the highest loading of the hybrid nanocomposite exhibited high specific capacitance and excellent cyclic stability, indicating its potential in energy storage.

ENERGY STORAGE (2023)

Article Chemistry, Physical

BiOCl as the role of cleaner for the fabrication of self-cleaning PES membranes based on the RTIPS method

Wenjing Tan, Chunmei Gao, Shifeng Ji, Yunqing Xing, Yi Guo, Baogui Liang

Summary: Membrane separation technology is widely used in wastewater treatment due to its cost-effectiveness and productivity. However, organic membrane fouling caused by humic acid is a major barrier to its further development. This study successfully addressed this issue through the production of composite materials and self-cleaning membranes, providing beneficial strategies and solutions for membrane contamination problems.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Low-temperature plasma-induced porous Sb2WO6 microspheres with rich oxygen vacancies to promote high-performance photocatalytic activity

Qichang Peng, Qingdong Ruan, Bin Wang, Jinyuan Liu, Chao Huang, Xingwang Zhu, Dan Li, Liangliang Liu, Yinchuan Wang, Xiaolin Zhang, Jia Yan, Paul K. Chu, Hui Xu

Summary: The escalating issue of water pollution has led to significant attention in the field of photocatalysis. In this study, OV-Sb2WO6-X photocatalyst with oxygen vacancies was synthesized, which exhibited enhanced charge separation efficiency and improved photocatalytic activity. The introduction of oxygen vacancies was successfully controlled and characterized, and the modified photocatalyst showed superior degradation efficiency for dye wastewater treatment.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Preparation and application of self-emulsifying curing agent for CO2 high-pressure corrosion-resistant resin cement

Wangcheng Zhang, Cunchuan Zheng, Hu Xie, Weichao Du

Summary: By using a specific curing agent ETB, the problem of dispersion and stability for oily epoxy resin in cement slurry system has been successfully solved. The application of the emulsified curing agent ETB in oilfield cement slurry system shows good rheological performance, resistance to high temperature and high pressure water loss, and corrosion resistance.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

New approaches for regulation of structure and adsorption properties of biochar based on freshwater sediments (sapropels)

O. I. Krivonos, A. Babenko, O. B. Belskaya

Summary: This study synthesized biochar based on sapropel and investigated the effects of chemical modification on its textural characteristics, acid-base properties, and adsorption properties. The results showed that the chemical modification increased the fraction of micropores, specific surface area, and changed the surface properties of biochar. The experiment also revealed that biochar pretreated with alkali exhibited the maximum adsorption capacity for copper ions. A conceptual model identifying the mechanisms of copper adsorption on sapropel-based biosorbent was proposed.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Detailed experimental performance of two new pyrimidine-pyrazole derivatives as corrosion inhibitors for mild steel in HCl media combined with DFT/MDs simulations of bond breaking upon adsorption

H. Lachhab, N. Benzbiria, A. Titi, S. Echihi, M. E. Belghiti, Y. Karzazi, A. Zarrouk, R. Touzani, C. Jama, F. Bentiss

Summary: The corrosion inhibitory potency of two new pyrimidine-pyrazole derivatives, PPA and PPC, was evaluated for mild steel in 1 M HCl. The results showed enhanced inhibition activities with increased concentration, reaching maximal values of 91.15% and 92.39% for PPA and PPC, respectively. However, the mitigation potency decreased with increasing temperature. SEM and XPS analysis revealed that PPA and PPC adsorbed on the mild steel surface, forming a shielding layer that prevented the dissolution of the steel in the acidic solution.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Encapsulation of essential oil to prepare environment friendly nanobio-fungicide against Fusarium oxysporum f.sp. lycopersici: An experimental and molecular dynamics approach

Shanmugapriya Sivalingam, D. Jeya Sundara Sharmila, Goutham Golla, Lakshmanan Arunachalam, Tarunendu Singh, G. Karthikeyan, A. Shanthi, Kannan Malaichamy

Summary: This study aims to develop a nano-biofungicide comprising of volatile essential oil molecules to enhance its efficacy in the field of agriculture through easily scalable green synthesis technique. The nano biofungicide was prepared through one pot hot melt ultrasonication technique with easy water dispersibility and long term stability. The physico-chemical analysis revealed that, nano bio-fungicides were amorphous sphere-shaped nanoparticles with low melting point. The encapsulation efficiency of major components of essential oil was determined, and it was found that they followed Higuchi model of release kinetics. The essential oil loaded nanostructured lipid carrier showed significantly higher mycelial growth inhibition compared to pure essential oil, indicating enhanced bio-efficacy.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Waterborne epoxy composite coating with long-term corrosion resistance through synergy of MXene nanosheets and ZnO quantum dots

Yinlong Li, Yingqing Zhan, Yiwen Chen, Hongshan Jia, Ximin Chen, Fei Zhu, Xulin Yang

Summary: In this study, ZnO quantum dots decorated MXene nanosheets were used as a functional filler for waterborne epoxy coating. The improved dispersion and synergy of ZnO QDs and MXene nanosheets enhanced the anticorrosion performance of the coating.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Alginate-based aerogel fibers with a sheath-core structure for highly efficient methylene blue adsorption via directed freezing wet-spinning

Fucheng Guan, Jing Tao, Qiang Yao, Zheng Li, Yihang Zhang, Shi Feng, Jianbin Sun, Qiang Yang, Xuecui Song, Jing Guo, Yuanfa Liu

Summary: This paper presents a method for preparing adsorbent materials based on biomass that can efficiently adsorb methylene blue. The experimental results show that the material has a hierarchical structure, high adsorption capacity, and reusability.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

In-situ study on the heterocoagulation between fine coal particles and coarse glass beads by the particle vision and measurement (PVM) techniques

Pengfei Hu, Zuli Mo, Weiliang Wang, Chengzhe Li, Zhaojia Guo, Guanqing Lin, Zhimin Guo

Summary: This study developed a novel in-situ particle vision and measurement (PVM) system to investigate heterocoagulation between coarse and fine particles in mineral processing. The experimental results showed that the degree of heterocoagulation decreased with increasing pH and stirring speed. Furthermore, under certain hydrodynamic conditions, coal particles were more distributed at the rear of the glass bead.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Label-free immunosensor for detection of hepatitis C (HCV) core antigen using ternary polypyrrole-Ag doped ZnO-exfoliated graphene nanocomposite

Tanveer ul Haq Zia, Anwar ul Haq Ali Shah, Behisht Ara, Kashif Gul

Summary: A label-free immunosensor for detection of hepatitis C core antigen was fabricated using a ternary nanocomposite based on polypyrrole, silver doped zinc oxide, and exfoliated graphene. The immunosensor demonstrated low detection limit, high selectivity, and stability.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Zwitterionic polymers as high-performance coatings for hemoperfusion adsorbents and their chemisorption of protein-bound toxins through computational simulations

Xiaoyan Feng, Jiachen Li, Lijun Liang, Linli Zhu, Sa Liu, Li Ren

Summary: In this study, polystyrene divinylbenzene microspheres were surface-modified by poly(carboxybetaine methacrylate) to develop an efficient hemoperfusion adsorbent for the removal of protein-bound toxins. The modified microspheres showed increased adsorption capacity and better biocompatibility, making them promising for clinical hemoperfusion therapy.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

A flexible high-efficiency approach to preparing a durable flame-retardant cellulosic fabric as well as the research of the property

Xiaoye Bi, Dong Xue, Yunpeng Wang, Chencheng Lv, Zexiong Li, Tao Zhao

Summary: This research aimed to develop a durable and formaldehyde-free flame retardant treatment for cotton fabrics. The results demonstrated successful grafting of phosphorous acid (PA) onto cotton fabrics, leading to enhanced flame resistance while maintaining the desired fabric characteristics.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Inhibiting mechanisms and applications of novel Al-starch for ultrafine gangue minerals based on experimental and computational study

Ruolin Wang, Wenjuan Sun, Haisheng Han, Dongping Tao

Summary: This study finds that Al-starch colloidal depressants can effectively inhibit the flotation of ultrafine calcite and chlorite, and increase the grade of valuable minerals. The chemisorption of Al-starch on mineral surface changes the functional group peaks and generates new O-Al functional groups.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Tuneable functionalized biochar for simultaneous removal of pharmaceuticals from binary mixture

Wondimu K. Wakejo, Ali Maged, Beteley T. Meshesha, Joon W. Kang, Abayneh G. Demesa, Sandip Chakrabarti, Thallada Bhaskar, Ashok Kumar Gupta, Amit Bhatnagar

Summary: Simultaneously removing different pharmaceutical pollutants from wastewater is an important environmental issue, and the use of a system that can remove multiple contaminants at once is necessary. Functionalized biochar (FBC) has been found to be effective in simultaneously removing acetaminophen and ciprofloxacin and other pharmaceutical pollutants.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Full utilization of Cu single atoms on carbon nitride nanofibers for enhanced Fenton-like degradation of methylene blue

Yu Wang, Fengwen Yan, Jie Wu, Zhijun Huang, Liuting Song, Shunda Yuan

Summary: In this study, Cu single atoms are anchored on the external surface of g-C3N4 nanofibers to maximize atom utilization. This catalyst exhibits excellent Fenton-like catalytic activity and good stability due to the full utilization of Cu active sites.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)