期刊
CHEMSUSCHEM
卷 12, 期 23, 页码 5192-5198出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201902093
关键词
bilayer; cathode material; K-0; 5V(2)O(5); layered potassium vanadate; Na-ion battery
资金
- Agence Universitaire de la Francophonie (AUF)
- Vietnam National University, Ho Chi Minh City [HS2013-76-01, B2011-08-01TD]
- Ministry of Education and Science of Kazakhstan [AP05136016-ZRABS]
- Campus France
A bilayered potassium vanadate K0.5V2O5 (KVO) is synthesized by a fast and facile synthesis route and evaluated as a positive electrode material for Na-ion batteries. Half the potassium ions can be topotactically extracted from KVO through the first charge, allowing 1.14 Na+ ions to be reversibly inserted. A good rate capability is also highlighted, with 160 mAh g(-1) at C/10, 94 mAh g(-1) at C/2, 73 mAh g(-1) at 2C and excellent cycling stability with 152 mAh g(-1) still available after 50 cycles at C/10. Ex situ X-ray diffraction reveals weak and reversible structural changes resulting in soft breathing of the KVO host lattice upon Na extraction-insertion cycles (Delta V/V approximate to 3 %). A high structure stability upon cycling is also achieved, at both the long-range order and atomic scale probed by Raman spectroscopy. This remarkable behavior is ascribed to the large interlayer spacing of KVO (approximate to 9.5 angstrom) stabilized by pillar K ions, which is able to accommodate Na ions without any critical change to the structure. Kinetics measurements reveal a good Na diffusivity that is hardly affected upon discharge. This study opens an avenue for further exploration of potassium vanadates and other bronzes in the field of Na-ion batteries.
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