4.7 Article

Ratiometric optical thermometer with high sensitivity based on dual far-red emission of Cr3+ in Sr2MgAl22O36

期刊

CERAMICS INTERNATIONAL
卷 46, 期 4, 页码 5008-5014

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.10.241

关键词

Ratiometric thermometer; High relative sensitivity; Dual far-red emission; Sr2MgAl22O36

资金

  1. 2019 Special Funds for the Development of Local Colleges and Universities by Central Finance
  2. Science and Technology Program of Guangzhou, China [201707010324]
  3. Key Platforms and Research Projects of Department of Education of Guangdong Province [2016KTSCX031, 2017KTSCX054]
  4. National Natural Science Foundation of China [11804057, 11604056]

向作者/读者索取更多资源

A series of Cr3+ ions activated Sr2MgAl22O36 inorganic luminescence materials were successfully synthesized. The structure provides suitable crystal field for Cr3+ ions to achieve both broadband and narrowband emission simultaneously in far-red region. Cr3+ ions doped Sr2MgAl22O36 reach the maximum of luminescence intensity when the concentration is increased to 0.02. When the concentration exceeds the value, the luminescence intensity of Cr3+ ions is quenched by the dipole-dipole interaction. The fluorescence intensity ratio I-2/I-1 (I(1)and I-2 represent the intensity at 677 and 693 nm, respectively) originating from Cr3+ ions in Sr2MgAl22O36 shows good linearity in the Arrhenius plot. The relative sensitivity of Sr2MgAl22O36: Cr3+ material at 310 K (physiological temperature) reaches 1.7% which has good application potential on ratiometric thermometers. Present researches indicate that Sr2MgAl22O36: Cr3+ has great potential application value on ratiometric thermometers.

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