期刊
CEMENT AND CONCRETE RESEARCH
卷 125, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.cemconres.2019.105891
关键词
Calcium-silicate-hydrate; Interaction; Mechanical properties; High-pressure X-ray diffraction; Composite
资金
- National Natural Science Foundation of China [51908119, U1706222, 51711530039]
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
Poly (vinyl alcohol) (PVA) emulsion is commonly used in cement-based materials to obtain higher performance. The present work investigates the interaction mechanisms between PVA and calcium silicate hydrates (C-S-H) using ambient and high pressure X-ray diffraction (XRD), Si-29 magic angle spinning nuclear magnetic resonance (MAS NMR), nano-indentation, and molecular dynamics simulation. In a C-S-H nano-particle, small-size PVA molecules can be intercalated into the interlayer region of the calcium silicate sheets, lowering the interlayer incompressibility and the overall bulk modulus of C-S-H at the crystal length scale. At a larger length scale, the large-size PVA chains can be in the midst among the C-S-H nano-particles, decreasing the porosity, thus the indentation modulus of the meso-composite is improved.
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