Article
Chemistry, Inorganic & Nuclear
Ignacio Chamorro-Mena, Noemi Linares, Javier Garcia-Martinez
Summary: This study describes the optimization of Cu2O/CuO heterostructures for enhanced (photo)catalytic performance. The evaluation of catalysts with different Cu2O/CuO molar ratios revealed that a ratio of 0.15 resulted in significantly higher rate constants under blue-LED light. Furthermore, this photocatalyst exhibited good stability and excellent chemoselectivity in the presence of other functionalities.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Ignacio Chamorro-Mena, Noemi Linares, Javier Garcia-Martinez
Summary: This study explores the optimization of Cu2O/CuO heterostructures for enhancing their (photo)catalytic performance. By evaluating catalysts with different Cu2O/CuO molar ratios, the researchers found that a ratio of 0.15 resulted in significantly higher reaction rate constants under blue LED light compared to lower (0.01) or higher (0.42) ratios. The photocatalyst also demonstrated good stability (>70% after 5 cycles) and excellent chemoselectivity in the selective reduction of the nitro group in the presence of other functionalities, such as -COOH, -CONH2, and -OH.
DALTON TRANSACTIONS
(2023)
Review
Chemistry, Multidisciplinary
Xiaorui Yan, Lele Chen, Huaxing Song, Zhaohua Gao, Haisheng Wei, Wanzhong Ren, Wenhua Wang
Summary: Selective hydrogenation of nitroarenes to anilines is a vital reaction in fine chemistry, but it remains challenging when reducible groups are present. MOF-derived catalysts have gained attention for their potential in catalysis, and this review discusses the progress in using them for selective hydrogenation of nitroarenes, analyzing key factors affecting catalytic performance.
NEW JOURNAL OF CHEMISTRY
(2021)
Review
Chemistry, Physical
Wenfeng Zhao, Hu Li, Heng Zhang, Song Yang, Anders Riisager
Summary: Ammonia borane (AB) is a promising material for hydrogen storage and has attracted much attention in reductive organic transformations. This review summarizes the recent progress of AB-mediated transfer hydrogenation reactions of various substrates and discusses the synthesis protocols, reaction parameters, product distribution, and reactivity. The mechanism involving the action mode of AB and structure-activity relationships are also discussed, and the challenges and opportunities for AB-enabled transfer hydrogenation reactions are highlighted.
GREEN ENERGY & ENVIRONMENT
(2023)
Article
Chemistry, Physical
Vincent Vermaak, Hermanus C. M. Vosloo, Andrew J. Swarts
Summary: The study reports the selective transfer hydrogenation of nitriles to secondary amines using nickel (II) catalysts and ammonia borane as a hydrogen source. The experiments demonstrate that under ambient temperature, specific catalysts can efficiently convert nitriles to secondary amines with high yields.
MOLECULAR CATALYSIS
(2021)
Article
Chemistry, Applied
Jing Tian, Daqian Xu, Wei Sun
Summary: Several cobalt(II) complexes supported by tetradentate and tridentate ligands have been prepared and characterized. X-ray crystallographic analysis shows that the cobalt complex of the BPMB ligand has a distorted octahedral configuration. These complexes can catalyze the transfer hydrogenation reaction of simple olefins with good to excellent yields, and the Co-N4 complexes are more effective than the Co-N3 complex.
ADVANCED SYNTHESIS & CATALYSIS
(2022)
Article
Chemistry, Inorganic & Nuclear
Adam W. Augustyniak, Anna M. Trzeciak
Summary: The [Pd(2-pymo)(2)](n) framework catalyzes the conversion of NH3BH3 to H-2 in water. Hydrophobic windows in the MOF structure may contribute to the formation of two equivalents of H-2 independently of the amount of NH3BH3. The presence of styrene or phenylacetylene in the system inhibits H(2) production and instead leads to hydrogen transfer hydrogenation. Mechanistic studies reveal that water, as a solvent, acts as a hydrogen donor and contributes to the hydrogenation of styrene and phenylacetylene.
INORGANICA CHIMICA ACTA
(2022)
Article
Chemistry, Multidisciplinary
Huanqin Guan, Mengqi Shen, Cooro Harris, Honghong Lin, Kecheng Wei, Michael Morales, Noah Bronowich, Shouheng Sun
Summary: This study reports the synthesis of Cu2O nanoparticles by controlling the oxidation of Cu nanoparticles, and investigates their application as catalysts in ammonia borane dehydrogenation, nitroarene hydrogenation, and amine/aldehyde condensation reactions. The 13 nm Cu2O nanoparticles show high catalytic activity in converting nitro groups to amines, and facilitate the synthesis of highly stable PBO materials.
Article
Chemistry, Inorganic & Nuclear
David Decker, Zhihong Wei, Jabor Rabeah, Hans-Joachim Drexler, Angelika Brueckner, Haijun Jiao, Torsten Beweries
Summary: In this study, a Co(ii) PNNH pincer catalyst system was applied for the highly E-selective transfer semihydrogenation of internal diaryl alkynes. The catalyst system showed high activity, short reaction times, and operated under mild conditions.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Physical
Yong Cheng, Dan Wang, Xiuxiu Wang, Ying-Hua Zhou
Summary: In this study, a high-efficiency tandem catalyst CuO-Ru-0.3@Co3O4 was synthesized for the hydrolytic dehydrogenation of ammonia borane (AB) and the hydrogenation of nitrobenzenes (NBs). The catalyst showed high activity and good cyclic stability.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Multidisciplinary
Shunbin Yang, Dengju Zhang, Weiguo Zuo, Guanqun Wang, Chengtao Wang, Jiyang Guo, Duona Fan, Song You, Xian Jia
Summary: In this study, a simple and efficient method was developed for the (Z)-selective transfer semihydrogenation of alkynes using in situ-generated cobalt nanoparticles and ammonia-borane. The method showed good to excellent yields and the recovered cobalt nanoparticles could be reused multiple times without significant loss of catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Cheng Peng, Wei Liu, Yong Wang
Summary: Density functional theory calculations were used to investigate the dehydrogenation mechanism of H3B center dot NMeH2 catalyzed by cobalt complexes and the formation of polyaminoborane. The computational results showed that Co-based complexes are efficient catalysts for selective synthesis of (H2BNMeH)(n) polymer from amine borane at low loadings. NMeH2 plays a crucial role in promoting hydride transfer processes and enabling the catalytic cycle of H3B center dot NMeH2 dehydrogenation. The formation of polyaminoborane involves a nucleophilic head-to-tail polymerization mechanism.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Organic
Huai-Yu Wang, Xiang-Long Chen, Chun-Yan Wu, Dong-Sheng Yang, Ting Chen, An-Xin Wu
Summary: Here, we present a straightforward method for the transition-metal-free reductive N-formylation of nitroarenes. This reaction utilizes the dual role of rongalite as a reductant and a C1 building block simultaneously. Our method provides an alternative approach for the synthesis of N-aryl formamides from nitroarenes, including the formation of a C-N bond. The utility of this protocol is demonstrated through scale-up synthesis and late-stage functionalizations of complex molecules.
Article
Chemistry, Inorganic & Nuclear
Valle Krishnaveni, Marilyn Esclance DMello, Keloth Basavaiah, Dasi Samsonu, Dheer A. Rambhia, Suresh Babu Kalidindi
Summary: Metal-organic frameworks (MOFs) with designable pores were loaded with Pd nanoparticles to create a pi-electron rich environment. The material exhibited superior activity for the transformation of 4-Nitro phenol (4-NP) to 4-Amino phenol (4-AP) using ammonia borane (AB) as a transfer hydrogenation agent.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Qin Zhu, Shuoqi Zhang, Jing Ma, Jun Zhu, Shuhua Li, Guixiang Zeng
Summary: The transfer hydrogenation of azobenzene with ammonia borane mediated by pincer bismuth complex 1 was studied using density functional theory calculations. The study revealed an unusual metal-ligand cooperation mechanism involving the saturation/regeneration of the C=N functional group on the pincer ligand. The reaction proceeds through the hydrogenation of the C=N bond, followed by the conversion of 3(CN) to a Bi-H intermediate, and eventually results in the production of N,N'-diphenylhydrazine and regeneration of the catalyst. The substitution of the phenyl group with a tert-butyl group on the pincer ligand improves the catalyst's performance.
CHEMISTRY-AN ASIAN JOURNAL
(2023)
Article
Engineering, Environmental
Ningzhao Shang, Chun Wang, Xiaoyu Zhang, Shutao Gao, Shuaihua Zhang, Tao Meng, Junmin Wang, Haijun Wang, Congcong Du, Tongde Shen, Jianyu Huang, Yuqing Qiao, Qiuhua Wu, Yongjun Gao
Summary: The study fabricated atomically dispersed iron supported on nitrogen-doped carbon as a highly efficient electrocatalyst for oxygen reduction reaction, which showed superior performance and stable cycling performance in energy conversion applications, providing a facile and effective strategy for constructing high performance electrocatalysts.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Ningzhao Shang, Shangyang Li, Xin Zhou, Shutao Gao, Yongjun Gao, Chun Wang, Qiuhua Wu, Zhi Wang
Summary: The folic acid based metal-organic gels synthesized through coordination induced self-assemble strategy show good dispersion and larger accessible surface areas, providing potential to enhance the oxygen reduction reaction and oxygen evolution reaction activities in nonprecious metal based bifunctional electrocatalysts for metal-air batteries.
APPLIED SURFACE SCIENCE
(2021)
Article
Engineering, Chemical
Shuai Zhang, Ningzhao Shang, Shutao Gao, Tao Meng, Zhi Wang, Yongjun Gao, Chun Wang
Summary: In this study, ultra-dispersed Co loaded on nitrogen-doped carbon (Co-NC 900) was prepared via a sacrificial template pyrolysis method, showing superior electrocatalytic performance for oxygen reduction reaction and excellent stability and power performance in zinc-air batteries.
CHEMICAL ENGINEERING SCIENCE
(2021)
Article
Chemistry, Physical
Xiaokang Yue, Lihong Zhang, Lixia Sun, Shutao Gao, Wei Gao, Xiang Cheng, Ningzhao Shang, Yongjun Gao, Chun Wang
Summary: The study demonstrates that flower-like Ni catalysts supported on mixed metal oxides exhibit excellent activity, mainly due to the large specific surface area of the support and strong interaction between the metal and support. By tuning the properties and composition of the catalyst, efficient hydrodeoxygenation catalysts can be constructed.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Energy & Fuels
Xiaokang Yue, Ningzhao Shang, Wei Gao, Xiang Cheng, Shutao Gao, Chun Wang, Zhi Wang
Summary: The use of bipyridine ligand-based porous organic framework materials as a support for PdAg bimetallic nanoparticles shows high activity and stability in the hydrodeoxygenation of lignin-derived molecules. This catalyst also exhibits excellent performance in the hydrogenation of vanillin, indicating promising application prospects for catalytic hydrodeoxygenation of lignin-derived compounds.
Article
Chemistry, Inorganic & Nuclear
Lixia Sun, Shangyang Li, Zhuoyou Gao, Shutao Gao, Wei Gao, Xiang Cheng, Ningzhao Shang, Yongjun Gao, Chun Wang
Summary: The fabrication of biofuels and chemicals from renewable biomass is highly desirable. In this paper, a new CoSi-PS catalyst was prepared and its performance in the hydrogenolysis reaction of HMF was studied. The results showed that the catalyst exhibited excellent catalytic activity and selectivity, surpassing other reported catalysts.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Physical
Yu Han, Hongmei Liu, Miao Fan, Shutao Gao, Dehui Fan, Zhenguang Wang, Jin Chang, Jinchao Zhang, Kun Ge
Summary: Improving the deep penetration of drugs in tumor sites is crucial for enhancing the therapeutic effect of tumors due to the unique tumor microenvironment. This study developed ultra-small permeable carbon dots (PCD) that can penetrate deep into tumor tissue without modification using near-infrared-II (NIR-II) window photothermal irradiation and exhibited good biocompatibility. The PCD showed multi-color fluorescence under visible light and photoacoustic signals under excitation, allowing for fluorescence and photoacoustic imaging for localization and distribution both in vitro and in vivo.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Energy & Fuels
Lixia Sun, Ying Zhao, Zhuoyou Gao, Xiaokang Yue, Shutao Gao, Wei Gao, Xiang Cheng, Ningzhao Shang, Chun Wang
Summary: A highly dispersed non-noble CoFe catalyst prepared via a sacrificial template method shows high activity and selectivity for the selective hydrogenation of furfural to furfuryl alcohol, outperforming most reported non-precious catalysts. Additionally, this catalyst efficiently catalyzes the hydrogenation of nitro and carbonyl compounds.
Article
Chemistry, Physical
Zhen Wang, Ningzhao Shang, Wenhui Wang, Shutao Gao, Shuaihua Zhang, Wei Gao, Xiang Cheng, Chun Wang
Summary: In this study, atomically distributed Co/S,N-C catalyst was prepared using a sacrificial template strategy. The catalyst exhibited abundant active sites for ORR and showed comparable electrocatalytic performance to commercial Pt/C in alkaline condition. The S, N co-doping modified the charges around the Co active center, resulting in excellent performance in zinc-air battery with high specific power and superior long-term stability.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Wenhui Wang, Wei Gao, Xinhao Nie, Weihua Liu, Xiang Cheng, Ningzhao Shang, Shutao Gao, Chun Wang
Summary: A series of hyper-cross-linked polymers (HCPs) photocatalysts were synthesized through Friedel-Crafts alkylation reaction. Different crosslinkers could change the energy level of HCPs, affecting their photocatalytic performance. Among them, DCM-HCPs showed the highest conversion and selectivity, as well as high production of H2O2 under blue LED lamp and sunlight irradiation.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Materials Science, Biomaterials
Gaoqian Zhao, Yan Jin, Shutao Gao, Tingshan Xiao, Miao Fan, Dandan Liu, Jinchao Zhang, Zhenhua Li, Xiaohan Zhou, Huifang Liu
Summary: In this study, a nanodrug-loading system was designed to combine hypoxic-activated prodrug TPZ with glucose oxidase (GOx) for starvation, oxidation, and chemotherapy in hypoxic regions, enhancing the anticancer effects.
ACS BIOMATERIALS SCIENCE & ENGINEERING
(2022)
Review
Chemistry, Physical
Ningzhao Shang, Zhen Wang, Siwei Liu, Sicheng Ma, Yalin Xing, Xiang Cheng, Wei Gao, Shutao Gao, Chun Wang
Summary: In this paper, a Mo-doped CoNi metal-organic framework-layered double hydroxide nanosheet supported on Ni foam was constructed as an electrocatalyst for replacing oxygen evolution reaction (OER) with benzylamine oxidation reaction (BOR) to enhance cathodic hydrogen production. The MOF@LDH-Mo heterostructure array exhibited large tangible surface area, rich active species, and open electron transport channels, showing excellent activity towards BOR.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Multidisciplinary
Xinhao Nie, Ying Zhao, Wei Gao, Weihua Liu, Xiang Cheng, Yongjun Gao, Ningzhao Shang, Shutao Gao, Chun Wang
Summary: A series of hyper-cross-linked polymers (HCPs) photocatalysts with different arenes monomers were synthesized, and QP-HCPs showed the highest photocatalytic activity for benzylamine oxidation under 455 nm Blue LED lamp irradiation. The conversion of benzylamine to N-benzylidenebenzylamine reached over 99% within 60 min, and a high production rate of nearly stoichiometric H2O2 was obtained. Rating: 9.5
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Shuai Zhang, Jie Li, Ning-Zhao Shang, Shu-Tao Gao, Chun Wang, Zhi Wang
NEW JOURNAL OF CHEMISTRY
(2020)
Review
Medicine, Research & Experimental
Miao Fan, Yu Han, Shutao Gao, Hongyu Yan, Lingzhi Cao, Zhenhua Li, Xing-Jie Liang, Jinchao Zhang
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)