Article
Chemistry, Physical
Pinyun Ren, Xianpei Ren, Jinyou Xu, Honglai Li, Yi Zheng, Yilun Hong, Yi Lin, Yating Zhou, Yuanfu Chen, Wanli Zhang
Summary: Metastable hexagonal MoO3 nanosheets with rich oxygen vacancies and high specific surface area were fabricated through a simple hydrothermal method, leading to excellent adsorption performance and superior stability in a wide pH range. The adsorption capacity of the nanosheets is influenced by the surface oxygen vacancies, and the adsorption mechanism is predominantly chemical adsorption caused by electrostatic induction.
APPLIED SURFACE SCIENCE
(2022)
Article
Engineering, Chemical
Naiwen Cao, Xinyu Zhao, Mingming Gao, Zhiyong Li, Xuejiao Ding, Chang Li, Kening Liu, Xindong Du, Weixia Li, Jing Feng, Yueming Ren, Tong Wei
Summary: The study found that F+-MgO exhibits selective adsorption, separation, and recovery performance for reactive dyes, while having low adsorption capacity for non-reactive dyes; Recycling of F+-MgO can be achieved through high-temperature calcination, with high adsorption efficiency maintained; The adsorbed dyes can also be reused by reintroducing MgO into the solution.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Chemistry, Physical
Songcan Wang, Boyan Liu, Xin Wang, Yingjuan Zhang, Wei Huang
Summary: By designing a nanoporous MoO3-x/BiVO4 heterojunction photoanode, we have improved the efficiency of charge separation in bismuth vanadate, resulting in significantly enhanced photoelectrochemical performance. Stable photoelectrochemical water splitting with high photocurrent density and applied bias photon-to-current efficiency is achieved by depositing dual oxygen evolution cocatalysts.
Article
Energy & Fuels
Amarja P. Naik, G. Bharath, Fawzi Banat, Pranay P. Morajkar, Akshay V. Salkar, Gerardo D. J. Guerrero Pena, Mohammad Haija
Summary: In this study, two-dimensional truncated microplates and microdisks of molybdenum oxide are synthesized using an innovative chemistry method. These microstructures show superior performance in charge storage devices, with high specific capacitance and excellent capacitance retention and Coulombic efficiency.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Multidisciplinary
Lijun Zhang, Zhiliang Jin, Noritatsu Tsubaki
Summary: The study involved the construction of a Step-scheme (S-scheme) core-shell heterojunction photocatalyst using in situ phosphating method, introducing a new design concept and providing insights for the construction of other mixed anion photocatalysts.
Article
Energy & Fuels
Yanqi Feng, Hui Liu, Yi Liu, Junqi Li
Summary: This study presents a strategy to enhance the energy storage performance of lithium-ion batteries by controlling the concentration of oxygen vacancies and generating MoO3-x/MoO2 heterojunction. The heterojunction exhibits high specific capacity and capacity retention, showing promising potential as an electrode material in Li-ion batteries.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Engineering, Environmental
Zihan Wei, Manvel Gasparyan, Liren Liu, Francis Verpoort, Jie Hu, Zhong Jin, Serge Zhuiykov
Summary: Large specific surface area and oxygen defects of metal oxides have a significant impact on surface adsorption processes, and are important considerations in material synthesis. This study fabricated oxygen-deficient two-dimensional (2D) oligo-layer molybdenum trioxide (MoO3-x) nanosheets with high aspect ratio through a convenient microwave-assisted exfoliation method, and comprehensively investigated the effect of oxygen vacancies on surface adsorption using experiments and DFT calculations. The results showed that the enlarged interlayer spacings and oxygen vacancies made the 2D oligo-layer MoO3-x nanosheets promising for the adsorption of various organic molecules and exhibited superior gas sensing performance as p-type gas sensors at room temperature.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Qijia Ding, Dongbo Xu, Jinrui Ding, Weiqiang Fan, Xiaowu Zhang, Yihuan Li, Weidong Shi
Summary: By using ZIF-8 as the precursor, ZnO/TiO2 photoelectrodes were prepared through electrostatic interaction, leading to the formation of abundant oxygen vacancies in the heterojunction. The optimal photocurrent density of the photoelectrode reached 1.76 mA/cm(2) at 1.23 V vs. RHE, which is 2.75 times that of pure TiO2. The IPCE of the best photoelectrode increased to 58.2% at 390 nm, with charge injection and separation efficiencies reaching 93.53% and 51.62%, respectively.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Physical
Endre-Zsolt Kedves, Eniko Bardos, Tamas Gyulavari, Zsolt Pap, Klara Hernadi, Lucian Baia
Summary: The presence of alpha-MoO3 significantly influences TiO2 photocatalytic performance and dye adsorption, with the (0 4 0) facet growth enhancing photocatalytic activity while decreasing adsorption affinity for cationic dyes. The solubility of alpha-MoO3 depends on the proportion of the (0 4 0) facet, affecting both adsorption and photocatalytic behaviors of the oxide. Evaluating photocatalytic activity of alpha-MoO3 with cationic dyes requires careful consideration due to the interaction between adsorption and photocatalytic processes.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Xunxun Li, Yaru Wang, Jiaqin He, Jun Xiao, Wanjun Xu, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: The synergistic effect of adsorption and photothermal can be utilized for efficient pollutant treatment technologies. A porous covalent triazine frameworks modified CuO@CoMn2O4 catalyst (PCTF-CCM) was developed for the full spectrum driven photothermal degradation of toluene, achieving 100% toluene conversion and 98% CO2 yield within 40 minutes under simulated solar irradiation (optical power density = 350 mW/cm2). Oxygen vacancies play a crucial role in thermal and photothermal catalysis by improving the adsorption of pollutant gases and oxygen mobility. The designed system extends the catalyst's range and service life, and provides a new approach for adsorption-photothermal catalyst design.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Materials Science, Multidisciplinary
Juhi Kumari, Pratima Agarwal
Summary: The influence of deposition conditions on the optoelectronic properties of MoO3-x films is investigated in this article. It is found that increasing the substrate temperature leads to the formation of oxygen-deficient MoO3-x films with lower transmission (-30%) and higher conductivity (15-200 Ω-1cm-1). Films prepared at a substrate temperature of 400 degrees C and an RF power of 80 W exhibit crystallinity and the formation of MoO2 as well as MoO3-x, making them suitable for catalytic applications. Additionally, introducing oxygen gas during deposition results in highly transparent (-80%) and resistive (10-6 Ω-1cm-1) thin films suitable for hole transport layer applications. The stoichiometry of molybdenum oxide can be controlled by varying the film preparation conditions, thus allowing for the tuning of optoelectronic properties.
Article
Chemistry, Physical
Lei Yang, Ruyi Wang, Ningning Zhou, Dewei Liang, Delin Chu, Chonghai Deng, Hai Yu, Jianguo Lv
Summary: The introduction of oxygen vacancies (Ov) has been proven efficient in enhancing the photoelectrochemical (PEC) water splitting performance. In this study, BiVO4 (BVO) photoanodes with both bulk and surface Ov were fabricated and their roles in PEC performance were investigated. The bulk Ov increased carrier density and improved electron-hole separation efficiency, while the surface Ov provided abundant active sites for charge injection. The synergistic effect between the bulk and surface Ov resulted in highly promoted PEC water splitting activity, offering a promising strategy for efficient solar water splitting systems.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Multidisciplinary Sciences
Andreas Velte-Schafer, Eric Laurenz, Gerrit Fueldner
Summary: In this research article, a simplified calculation method is proposed to predict the efficiency and heat flow rates of adsorption heat pumps and chillers. Experimental data validation shows that the method has good prediction accuracy.
Article
Environmental Sciences
Yichao Deng, Mengying Xu, Xiangyang Jiang, Junting Wang, Pier-Luc Tremblay, Tian Zhang
Summary: Crystal plane regulation, defect engineering, and element doping were utilized to enhance the performance of BiOCl for pollutant degradation. Iodine-doped BiOCl nanowafers with (110) crystal planes and oxygen vacancies were prepared and showed excellent photodegradation properties. The iodine-doped photocatalyst achieved high degradation efficiencies for toxic dye and antibiotic, outperforming unmodified BiOCl. The enhanced properties were attributed to the presence of (110) crystal planes, oxygen vacancies, and a modified electronic band structure.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Juguo Dai, Xueqiang Qi, Long Xia, Qian Xue, Lili Luo, Xiaohong Wang, Chunying Yang, Dongxu Li, Hongmei Xie, Andreu Cabot, Lizong Dai, Yiting Xu
Summary: The use of non-metal charge carriers such as ammonium offers advantages in energy storage devices, but the development of suitable electrodes lags behind. This study presents a high-performance anode material based on a MoO3/carbon composite for ammonium-ion supercapacitors. The optimized material exhibits unprecedented specific capacitance and good capacitance retention.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Muhammad Ahsan Iqbal, Haowei Xie, Lu Qi, Wei-Chao Jiang, Yu-Jia Zeng
Summary: Ferroelectric materials, such as BiFeO3, P(VDF-TrFE), and CuInP2S6, exhibit unique spontaneous electric polarization that can be reversed by external electric fields. The combination of ferroelectric and low-dimensional materials has sparked significant interest in solar cells, photodetectors, and nonvolatile memory. This article discusses the fundamental aspects of ferroelectric materials, their impact on optoelectronic devices, and future directions in this rapidly growing field.
Article
Chemistry, Physical
Yuqi Wang, Xishun Hao, Yuan Kang, Mengyang Dong, Zhou Fang, Yue Hu, Huanting Wang, Xiulin Fan, Youguo Yan, Zhizhen Ye, Xinsheng Peng
Summary: Understanding the ion transport in concentrated electrolytes is important. This study demonstrates an enhanced ion transport of water-in-salt (WIS) electrolytes in 2D nanochannel membranes. The mechanism involves a stratification process induced by functional groups, where a free anion layer moves between two continuous water-cation layers. Lithium-ion batteries with this confined electrolyte showed improved capacity and coulombic efficiency. This work provides new insights into the ion transport mechanism in nanoconfined concentrated electrolytes and offers strategies for designing high-performance and safe electrolytes for energy and environmental devices.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Optics
Wenqi Zhu, Jinhui Lu, Min Zhang, Hong Su, Ling Li, Qi Qin, Huawei Liang
Summary: In this research, a tunable splitting ratio terahertz (THz) beam splitter is demonstrated using a metasurface integrated onto a prism. The metasurface converts part of the incident wave into a cross-polarized wave and manipulates its phase, allowing it to pass through the interface even at large incident angles. The splitting ratio of the device can be adjusted by tuning the resonant response of the metasurface and varying the distance between the metasurface and the prism.
Article
Chemistry, Inorganic & Nuclear
Ziyu W. Yang, Jie Zhang, Dabiao Lu, Xiaoxiao Zhang, Haoting Zhao, Hongzhi Cui, Yu-Jia Zeng, Youwen Long
Summary: In this study, the thermodynamic and magnetocaloric parameters of an X1 phase oxyorthosilicate, Gd2SiO5, were investigated. The results showed that it has a strong correlation strength and impressive magnetic entropy change, making it a potential candidate for cryocoolers in the temperature range of 2-20 K.
INORGANIC CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
J. Qu, X. Han, S. Sakamoto, C. J. Jia, J. Liu, H. Li, D. Guan, Y. -J. Zeng, M. Schuler, P. S. Kirchmann, B. Moritz, Z. Hussain, T. P. Devereaux, Z. -X Shen, J. A. Sobota
Summary: Spin-orbit coupling is the foundation for quantum materials with non-trivial topology and potential spintronics applications. The Rashba interaction is a representative model of spin-orbit interactions, and BiTeX (X = Cl, Br, I) semiconductors have been identified as exemplary Rashba materials. However, a detailed investigation of their spin textures and their relationship to local crystal symmetry is currently lacking. In this study, we directly image the spin texture of surface states of BiTeCl and find deviations from ideal behavior, including spin-polarization reversal near the Fermi level. These effects are described by higher-order contributions to the canonical Rashba model.
NPJ QUANTUM MATERIALS
(2023)
Article
Chemistry, Physical
Xiaoyu Wang, Yuqi Wang, Mengyang Dong, Zhou Fang, Yue Hu, Kainan Xue, Zhizhen Ye, Xinsheng Peng
Summary: This paper presents a method of confining deep eutectic solvents (DESs) onto graphene oxide (GO) membranes to improve their ionic conductivity and apply them to supercapacitors.
MATERIALS TODAY ENERGY
(2023)
Article
Chemistry, Physical
Furong Yang, Jinyu Ye, Lei Gao, Jingwei Yu, Zhilong Yang, Yangfan Lu, Chao Ma, Yu-Jia Zeng, Hongwen Huang
Summary: In this study, ultrathin PtNiGaSnMoRe senary nanowires (SNWs) with partial amorphous structure, multimetallic ensembles, and ultrathin diameter are synthesized for direct methanol fuel cells. The SNWs exhibit excellent mass activity (6.2 A mg(Pt)(-1)) and specific activity (12.3 mA cm(-2)) for alkaline methanol oxidation reaction (MOR). The SNWs also demonstrate remarkable CO tolerance and improved MOR performance through faster CO* removal and advanced nanostructure.
ADVANCED ENERGY MATERIALS
(2023)
Review
Electrochemistry
Shu Zhang, Shuyue Xue, Yaohui Wang, Gufei Zhang, Nayab Arif, Peng Li, Yu-Jia Zeng
Summary: Three-dimensional printing, as an advanced additive manufacturing technique, shows great potential in the field of electrical energy storage and conversion. It enables precise control of printed structures and porosity, leading to improved performance in electrocatalysis, battery components, and supercapacitors. Although progress has been made, challenges still exist.
Article
Chemistry, Physical
Shu Zhang, Yi Zhu, Xiandi Zhang, Fanglin Hu, Wengao Zhao, Jianxuan Du, Shuyue Xue, Peng Li, Yu-Jia Zeng
Summary: Currently, silicon-based anode active materials for lithium-ion batteries have gained increasing attention due to their potential high energy density. However, the replacement of graphite with silicon still faces challenges such as low coulombic efficiency, low electrode loading, and insufficient areal capacity. In this study, a silicon-graphite electrode was developed to overcome these limitations, demonstrating promising results including high coulombic efficiency, ultrahigh areal capacity, and impressive loading level. Special characterization tests further confirmed the stability of the electrode design, which was attributed to enhanced conductivity, reliable volume buffer effect, and improved ion transport and side reaction prevention.
SUSTAINABLE ENERGY & FUELS
(2023)
Article
Materials Science, Multidisciplinary
Zhimin Mao, Su-Yun Zhang, Duo Zhao, Xiaoliang Weng, Chenxu Kang, Hui Fang, Yu-Jia Zeng
Summary: In this study, in situ synthesis of Cu-MOF-74 is investigated, revealing its ferromagnetic and antiferromagnetic behaviors. The introduction of SnS:Co quantum dots enhances the antiferromagnetic coupling and improves the phase transition temperature of the MOF material. Moreover, Cu-MOF-74 exhibits both magnetic and optoelectronic properties, with the responsivity and detectivity of the photodetector significantly improved by SnS:Co quantum dots.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Materials Science, Multidisciplinary
Manli Yang, Xiaoliang Weng, Muhammad Ahsan Iqbal, Chenxu Kang, Su-Yun Zhang, Yu-Jia Zeng
Summary: In this study, Ga-doped ZnO (GZO) photodetectors with localized surface plasmon resonance (LSPR) properties were developed, extending the optical response range to the near-infrared region. The photothermoelectric (PTE) effect resulted in an intriguing current polarity reversal phenomenon. Finally, the coupling of black phosphorus nanocrystals further improved the performance of the photodetector. This study provides a promising noble-metal free plasmon-enhanced photodetector with great potential for use in broadband photodetection and bipolar signal communication.
MATERIALS ADVANCES
(2023)
Article
Chemistry, Inorganic & Nuclear
Ziyu W. Yang, Jie Zhang, Dabiao Lu, Xiaoxiao Zhang, Haoting Zhao, Hongzhi Cui, Yu-Jia Zeng, Youwen Long
Summary: Searching for working refrigerant materials is crucial in designing magnetic cooling devices. This study investigates the thermodynamic and magnetocaloric parameters of a phase oxyorthosilicate, Gd2SiO5, and finds impressive magnetic entropy change and adiabatic temperature change at low temperatures. The material shows potential in cryocoolers with both the Stirling and Carnot cycles, and the layered spin arrangement enhances magnetocaloric coupling for designing efficient magnetic refrigerants.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Nayab Arif, Yunfei Ma, Muhammad Nadeem Zafar, Muhammad Humayun, Mohamed Bououdina, Su-Yun Zhang, Qitao Zhang, Xiaopeng Yang, Huawei Liang, Yu-Jia Zeng
Summary: In this study, a novel low-cost pi-pi biomass-derived black carbon modified g-C3N4 coupled FeIn2S4 composite photocatalyst was developed, showing significantly improved photocatalytic performance for the degradation of Eosin Yellow dye. The optimized composite displayed 99% removal performance for the dye, almost three times higher than that of the pristine counterparts. The degradation process was proven to involve hydroxyl radicals and superoxide radicals, and a systematic photocatalytic degradation route was proposed based on the analysis of degradation intermediates.
Article
Optics
Muhammad Ahsan Iqbal, Xiaoliang Weng, Chenxu Kang, Nayab Arif, Kewen Wu, Wei Tang, Sichao Dai, Xueqian Fang, Houzhi Cai, Yu-Jia Zeng
Summary: Photoinduced charge-trapping is a strategy to enhance the photosensitivity of organic photodetectors, but it comes at the expense of response time. The extraction and population of triplet state excitons in TADFs is an underexplored aspect in photodetectors. By blending PBTTT-C-14 polymer with 4CzIPN TADF, it is possible to increase carrier extraction efficiency and retain electrons in the TADF triplet states.
LASER & PHOTONICS REVIEWS
(2023)
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)