4.7 Article

Multifunctional molybdenum oxide for solar-driven water evaporation and charged dyes adsorption

期刊

APPLIED SURFACE SCIENCE
卷 491, 期 -, 页码 328-334

出版社

ELSEVIER
DOI: 10.1016/j.apsusc.2019.06.155

关键词

MoO3-x; Oxygen vacancies; Superstructure; Water evaporation; Dyes adsorption

资金

  1. National Natural Science Foundation of China [11874270]
  2. Shenzhen Peacock Technological Innovation Project [KQJSCX20170727101208249]
  3. Shenzhen Science and Technology Project [JCYJ20170412105400428, JCYJ20180507182246321]

向作者/读者索取更多资源

Significant efforts have been made to seek technologies to resolve water shortages. Among these efforts, seawater desalination and wastewater purification are considered mainstream strategies. Photothermal materials and adsorbents are the main components of solar-driven seawater desalination and wastewater purification, respectively. Herein, we propose MoO3-x (0 < x < 1) as a multifunctional material applied simultaneously to solar-driven seawater desalination and wastewater purification. Thanks to the oxygen vacancies (OVs)-induced localized surface plasmon resonance (LSPR) and 3D nanoflower-like superstructures, the resultant MoO3-x possesses a high total absorption of 97% over the whole solar spectrum and a high water evaporation rate of 1.51 kgm(-2) h(-1) as well as an calculated energy conversion efficiency of 95% under one-sun irradiation. At the same time, MoO3-x exhibits a remarkably high removal ratio of 96.1% and a high adsorption capacity of 295.0 mg g(-1) for positively charged organic dyes with a fast speed (similar to 5 min), which is ascribed to the surface functional groups generated by OVs. Finally, the photocatalytic properties of MoO3-x can be further utilized to recycle with green solar energy. The high photothermal conversion efficiency of the material combined with its excellent adsorption properties and good photocatalytic activity opens up exciting possibilities in energy and environmental applications.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Review Chemistry, Multidisciplinary

Recent Advances in Ferroelectric-Enhanced Low-Dimensional Optoelectronic Devices

Muhammad Ahsan Iqbal, Haowei Xie, Lu Qi, Wei-Chao Jiang, Yu-Jia Zeng

Summary: Ferroelectric materials, such as BiFeO3, P(VDF-TrFE), and CuInP2S6, exhibit unique spontaneous electric polarization that can be reversed by external electric fields. The combination of ferroelectric and low-dimensional materials has sparked significant interest in solar cells, photodetectors, and nonvolatile memory. This article discusses the fundamental aspects of ferroelectric materials, their impact on optoelectronic devices, and future directions in this rapidly growing field.
Article Chemistry, Physical

Enhanced ion conductivity of water-in-salt electrolytes by nanochannel membranes

Yuqi Wang, Xishun Hao, Yuan Kang, Mengyang Dong, Zhou Fang, Yue Hu, Huanting Wang, Xiulin Fan, Youguo Yan, Zhizhen Ye, Xinsheng Peng

Summary: Understanding the ion transport in concentrated electrolytes is important. This study demonstrates an enhanced ion transport of water-in-salt (WIS) electrolytes in 2D nanochannel membranes. The mechanism involves a stratification process induced by functional groups, where a free anion layer moves between two continuous water-cation layers. Lithium-ion batteries with this confined electrolyte showed improved capacity and coulombic efficiency. This work provides new insights into the ion transport mechanism in nanoconfined concentrated electrolytes and offers strategies for designing high-performance and safe electrolytes for energy and environmental devices.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Optics

Metasurfaces Excited by an Evanescent Wave for Terahertz Beam Splitters with a Tunable Splitting Ratio

Wenqi Zhu, Jinhui Lu, Min Zhang, Hong Su, Ling Li, Qi Qin, Huawei Liang

Summary: In this research, a tunable splitting ratio terahertz (THz) beam splitter is demonstrated using a metasurface integrated onto a prism. The metasurface converts part of the incident wave into a cross-polarized wave and manipulates its phase, allowing it to pass through the interface even at large incident angles. The splitting ratio of the device can be adjusted by tuning the resonant response of the metasurface and varying the distance between the metasurface and the prism.

PHOTONICS (2023)

Article Chemistry, Inorganic & Nuclear

Strong Magnetocaloric Coupling in Oxyorthosilicate with Dense Gd3+ Spins

Ziyu W. Yang, Jie Zhang, Dabiao Lu, Xiaoxiao Zhang, Haoting Zhao, Hongzhi Cui, Yu-Jia Zeng, Youwen Long

Summary: In this study, the thermodynamic and magnetocaloric parameters of an X1 phase oxyorthosilicate, Gd2SiO5, were investigated. The results showed that it has a strong correlation strength and impressive magnetic entropy change, making it a potential candidate for cryocoolers in the temperature range of 2-20 K.

INORGANIC CHEMISTRY (2023)

Article Materials Science, Multidisciplinary

Reversal of spin-polarization near the Fermi level of the Rashba semiconductor BiTeCl

J. Qu, X. Han, S. Sakamoto, C. J. Jia, J. Liu, H. Li, D. Guan, Y. -J. Zeng, M. Schuler, P. S. Kirchmann, B. Moritz, Z. Hussain, T. P. Devereaux, Z. -X Shen, J. A. Sobota

Summary: Spin-orbit coupling is the foundation for quantum materials with non-trivial topology and potential spintronics applications. The Rashba interaction is a representative model of spin-orbit interactions, and BiTeX (X = Cl, Br, I) semiconductors have been identified as exemplary Rashba materials. However, a detailed investigation of their spin textures and their relationship to local crystal symmetry is currently lacking. In this study, we directly image the spin texture of surface states of BiTeCl and find deviations from ideal behavior, including spin-polarization reversal near the Fermi level. These effects are described by higher-order contributions to the canonical Rashba model.

NPJ QUANTUM MATERIALS (2023)

Article Chemistry, Physical

A two-dimensional nanochannel facilitates ionic conductivity of a deep eutectic solvent for an efficient supercapacitor

Xiaoyu Wang, Yuqi Wang, Mengyang Dong, Zhou Fang, Yue Hu, Kainan Xue, Zhizhen Ye, Xinsheng Peng

Summary: This paper presents a method of confining deep eutectic solvents (DESs) onto graphene oxide (GO) membranes to improve their ionic conductivity and apply them to supercapacitors.

MATERIALS TODAY ENERGY (2023)

Article Chemistry, Physical

Ultrathin PtNiGaSnMoRe Senary Nanowires with Partial Amorphous Structure Enable Remarkable Methanol Oxidation Electrocatalysis

Furong Yang, Jinyu Ye, Lei Gao, Jingwei Yu, Zhilong Yang, Yangfan Lu, Chao Ma, Yu-Jia Zeng, Hongwen Huang

Summary: In this study, ultrathin PtNiGaSnMoRe senary nanowires (SNWs) with partial amorphous structure, multimetallic ensembles, and ultrathin diameter are synthesized for direct methanol fuel cells. The SNWs exhibit excellent mass activity (6.2 A mg(Pt)(-1)) and specific activity (12.3 mA cm(-2)) for alkaline methanol oxidation reaction (MOR). The SNWs also demonstrate remarkable CO tolerance and improved MOR performance through faster CO* removal and advanced nanostructure.

ADVANCED ENERGY MATERIALS (2023)

Review Electrochemistry

Three-Dimensional Printing, an Emerging Advanced Technique in Electrochemical Energy Storage and Conversion

Shu Zhang, Shuyue Xue, Yaohui Wang, Gufei Zhang, Nayab Arif, Peng Li, Yu-Jia Zeng

Summary: Three-dimensional printing, as an advanced additive manufacturing technique, shows great potential in the field of electrical energy storage and conversion. It enables precise control of printed structures and porosity, leading to improved performance in electrocatalysis, battery components, and supercapacitors. Although progress has been made, challenges still exist.

BATTERIES-BASEL (2023)

Article Chemistry, Physical

An ultrahigh mass-loading integrated high coulombic efficiency Si-graphite electrode for high-energy-density lithium ion batteries

Shu Zhang, Yi Zhu, Xiandi Zhang, Fanglin Hu, Wengao Zhao, Jianxuan Du, Shuyue Xue, Peng Li, Yu-Jia Zeng

Summary: Currently, silicon-based anode active materials for lithium-ion batteries have gained increasing attention due to their potential high energy density. However, the replacement of graphite with silicon still faces challenges such as low coulombic efficiency, low electrode loading, and insufficient areal capacity. In this study, a silicon-graphite electrode was developed to overcome these limitations, demonstrating promising results including high coulombic efficiency, ultrahigh areal capacity, and impressive loading level. Special characterization tests further confirmed the stability of the electrode design, which was attributed to enhanced conductivity, reliable volume buffer effect, and improved ion transport and side reaction prevention.

SUSTAINABLE ENERGY & FUELS (2023)

Article Materials Science, Multidisciplinary

Magnetic and optoelectronic modulation of Cu-MOF-74 films by quantum dots

Zhimin Mao, Su-Yun Zhang, Duo Zhao, Xiaoliang Weng, Chenxu Kang, Hui Fang, Yu-Jia Zeng

Summary: In this study, in situ synthesis of Cu-MOF-74 is investigated, revealing its ferromagnetic and antiferromagnetic behaviors. The introduction of SnS:Co quantum dots enhances the antiferromagnetic coupling and improves the phase transition temperature of the MOF material. Moreover, Cu-MOF-74 exhibits both magnetic and optoelectronic properties, with the responsivity and detectivity of the photodetector significantly improved by SnS:Co quantum dots.

JOURNAL OF MATERIALS CHEMISTRY C (2023)

Article Materials Science, Multidisciplinary

Broadband photoresponse in plasmon-enhanced Ga-doped ZnO

Manli Yang, Xiaoliang Weng, Muhammad Ahsan Iqbal, Chenxu Kang, Su-Yun Zhang, Yu-Jia Zeng

Summary: In this study, Ga-doped ZnO (GZO) photodetectors with localized surface plasmon resonance (LSPR) properties were developed, extending the optical response range to the near-infrared region. The photothermoelectric (PTE) effect resulted in an intriguing current polarity reversal phenomenon. Finally, the coupling of black phosphorus nanocrystals further improved the performance of the photodetector. This study provides a promising noble-metal free plasmon-enhanced photodetector with great potential for use in broadband photodetection and bipolar signal communication.

MATERIALS ADVANCES (2023)

Article Chemistry, Inorganic & Nuclear

Strong Magnetocaloric Coupling in Oxyorthosilicate with Dense Gd3+ Spins

Ziyu W. Yang, Jie Zhang, Dabiao Lu, Xiaoxiao Zhang, Haoting Zhao, Hongzhi Cui, Yu-Jia Zeng, Youwen Long

Summary: Searching for working refrigerant materials is crucial in designing magnetic cooling devices. This study investigates the thermodynamic and magnetocaloric parameters of a phase oxyorthosilicate, Gd2SiO5, and finds impressive magnetic entropy change and adiabatic temperature change at low temperatures. The material shows potential in cryocoolers with both the Stirling and Carnot cycles, and the layered spin arrangement enhances magnetocaloric coupling for designing efficient magnetic refrigerants.

INORGANIC CHEMISTRY (2023)

Article Chemistry, Multidisciplinary

Design and Fabrication of Biomass Derived Black Carbon Modified g-C3N4/FeIn2S4 Heterojunction as Highly Efficient Photocatalyst for Wastewater Treatment

Nayab Arif, Yunfei Ma, Muhammad Nadeem Zafar, Muhammad Humayun, Mohamed Bououdina, Su-Yun Zhang, Qitao Zhang, Xiaopeng Yang, Huawei Liang, Yu-Jia Zeng

Summary: In this study, a novel low-cost pi-pi biomass-derived black carbon modified g-C3N4 coupled FeIn2S4 composite photocatalyst was developed, showing significantly improved photocatalytic performance for the degradation of Eosin Yellow dye. The optimized composite displayed 99% removal performance for the dye, almost three times higher than that of the pristine counterparts. The degradation process was proven to involve hydroxyl radicals and superoxide radicals, and a systematic photocatalytic degradation route was proposed based on the analysis of degradation intermediates.
Article Optics

Thermally Activated Delayed Fluorescence Triplet State Excitons for High-Performance Organic Photodetectors: A Novel Strategy

Muhammad Ahsan Iqbal, Xiaoliang Weng, Chenxu Kang, Nayab Arif, Kewen Wu, Wei Tang, Sichao Dai, Xueqian Fang, Houzhi Cai, Yu-Jia Zeng

Summary: Photoinduced charge-trapping is a strategy to enhance the photosensitivity of organic photodetectors, but it comes at the expense of response time. The extraction and population of triplet state excitons in TADFs is an underexplored aspect in photodetectors. By blending PBTTT-C-14 polymer with 4CzIPN TADF, it is possible to increase carrier extraction efficiency and retain electrons in the TADF triplet states.

LASER & PHOTONICS REVIEWS (2023)

Article Chemistry, Physical

Multifunctional continuous solid solution Na0.9Mg0.45Ti3.55O8-Na2Fe2Ti6O16: Preparation, characterization, magnetism, dual absorption, adsorption, and photocatalysis

Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou

Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.

APPLIED SURFACE SCIENCE (2024)

Review Chemistry, Physical

Critical advances in the field of magnetron sputtered bioactive glass thin-films: An analytical review

George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira

Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Corrosion mode evaluation of Fe-based glassy alloys with metalloid elements by electrochemical noise (EN)

Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang

Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Impacts of Zr content of HfZrOx-Based FeFET memory on resilience towards proton radiation

Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu

Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Excellent crystalline silicon surface passivation by transparent conductive Al-doped ZnO/ITO stack

Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong

Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Hydrogen sensing capabilities of highly nanoporous black gold films

Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata

Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Abnormal stability of hydrogenic defects and magnetism near the HSrCoO2.5(001) surface

Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu

Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Space variant fiber nanogratings induced by femtosecond laser direct writing

Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng

Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Wetting mechanisms in the mass transfer process of CuSi3 droplets on the TC4 and 304SS multi-metal system controlled by the hybrid shielding gas atmosphere

Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun

Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Size-regulated Co-doped hetero-interfaced 3D honeycomb MXene as high performance electromagnetic absorber with anti-corrosion performance

Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu

Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Ultrafine Ru nanoparticles on nitrogen-doped CNT arrays for HER: A CVD-based protocol achieving microstructure design and strong catalyst-support interaction

Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng

Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Novel biphenylene as cisplatin anticancer drug delivery carrier; insight from theoretical perspective

Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty

Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Platform for surface-enhanced Raman scattering in layered quantum materials

Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong

Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Cyclotriphosphazene (P3N3) derived FeOx@SPNO-C core-shell nanospheres as peroxymonosulfate activator for degradation via non-radical pathway

Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun

Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Hierarchical confinement of Prussian blue nanoparticles via NH2-MIL-88B (Fe): Rational design and electrocatalytic application

Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan

Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.

APPLIED SURFACE SCIENCE (2024)