期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 6, 页码 2375-2379出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201911012
关键词
dicarbofunctionalization; heterocycles; palladium catalysis; quaternary centers; radicals
资金
- Deutsche Forschungsgemeinschaft [SFB 858]
The redox-neutral dicarbofunctionalization of tri- and tetrasubstituted olefins to form a variety of (hetero)cyclic compounds under photoinduced palladium catalysis is described. This cascade reaction process was used to couple styrenes or acryl amides with a broad range of highly decorated olefins tethered to aryl or alkyl bromides (>50 examples). This procedure enables one or two contiguous all-carbon quaternary centers to be formed in a single step. The products could be readily diversified and applied in the synthesis of a bioactive oxindole analogue.
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