Carbene-Catalyzed Desymmetrization and Direct Construction of Arenes with All-Carbon Quaternary Chiral Center

Switching the statistical C1:C3-ratio in threefold aromatic substitution of tribenzotriquinacenes towards the C3-isomer

(2018) Michael Mastalerz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective arene formation

(2018) Achim Link et al.   CHEMICAL SOCIETY REVIEWS

Combining Stereoselective Enzyme Catalysis with Chirality-Assisted Synthesis in Tribenzotriquinacene Chemistry

(2018) Philipp Rommelmann et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions

(2018) Guoting Zhang et al.   Nature Communications

Catalyst-Controlled Stereodivergent Synthesis of Atropisomeric Multiaxis Systems

(2018) Dominik Lotter et al.   ACS Central Science

Trefoil-Shaped Porous Nanographenes Bearing a Tribenzotriquinacene Core by Three-fold Scholl Macrocyclization

(2018) Lisi He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to All-Carbon Spirocycles through a Carbene and Thiourea Cocatalytic Desymmetrization Cascade Reaction

(2018) Shitian Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Electrophilic Aromatic Nitration: A Chiral Auxiliary Approach

(2018) Joseph P. Campbell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Terpenoids Employing a “Benzannulation of Carvone” Strategy: Synthesis of (−)-Crotogoudin

(2017) Peter Finkbeiner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective N-Heterocyclic Carbene Catalysis by the Umpolung of α,β-Unsaturated Ketones

(2016) Yuji Nakano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Free Conditions for Rhodium-Catalyzed Asymmetric Arylation To Produce Stereochemically Labile α-Aryl Ketones

(2016) Xiaowei Dou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dysprosium(III)-Catalyzed Ring-Opening ofmeso-Epoxides: Desymmetrization by Remote Stereocontrol in a Thiolysis/Elimination Sequence

(2016) Lu Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Ileabethoxazole, Pseudopteroxazole, and seco -Pseudopteroxazole

(2016) Ming Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chirality-Assisted Synthesis of a Very Large Octameric Hydrogen-Bonded Capsule

(2016) Daniel Beaudoin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective syntheses of indanes: from organocatalysis to C–H functionalization

(2016) Cyril Borie et al.   CHEMICAL SOCIETY REVIEWS

Three-Fold Scholl-Type Cycloheptatriene Ring Formation around a Tribenzotriquinacene Core: Toward Warped Graphenes

(2016) Ho-Wang Ip et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The pentadehydro-Diels–Alder reaction

(2016) Teng Wang et al.   NATURE

N-Heterocyclic Carbene-Catalyzed Convenient Benzonitrile Assembly

(2016) Qianfa Jia et al.   ORGANIC LETTERS

Enantiomerically Pure Tribenzotriquinacenes through Stereoselective Synthesis

(2015) Wilko Greschner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring Opening of Bicyclo[3.1.0]hexan-2-ones: A Versatile Synthetic Platform for the Construction of Substituted Benzoates

(2015) Johannes Feierfeil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Shape-Controlled Synthesis and Self-Sorting of Covalent Organic Cage Compounds

(2015) Stefanie Klotzbach et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Aerobic Oxidative Dehydrogenation of Cyclohexenes to Substituted Arene Derivatives

(2015) Andrei V. Iosub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed δ-Carbon LUMO Activation of Unsaturated Aldehydes

(2015) Tingshun Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Formal C(sp2)–H Alkylation

(2015) Madhu Sudan Manna et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition

(2014) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Atroposelective Aldol Condensation: Synthesis of Axially Chiral Biaryls by Arene Formation

(2014) Achim Link et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiocontrolled Synthesis and Optical Resolution of Mono-, Di-, and Trisubstituted Tribenzotriquinacene Derivatives: Key Building Blocks for Further Assembly into Molecular Squares and Cubes

(2014) Wen-Rong Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium/Copper-Catalyzed Aerobic Intermolecular Cyclization of Enediyne Compounds and Alkynes: Interrupting Cycloaromatization for (4 + 2) Cross-Benzannulation

(2014) Fei Ling et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzannulation via Ruthenium-Catalyzed Diol–Diene [4+2] Cycloaddition: One- and Two-Directional Syntheses of Fluoranthenes and Acenes

(2014) Laina M. Geary et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzene construction via organocatalytic formal [3+3] cycloaddition reaction

(2014) Tingshun Zhu et al.   Nature Communications

Total synthesis of the Daphniphyllum alkaloid daphenylline

(2013) Zhaoyong Lu et al.   Nature Chemistry

Copper(I)-Catalyzed Asymmetric Desymmetrization: Synthesis of Five-Membered-Ring Compounds Containing All-Carbon Quaternary Stereocenters

(2012) Kohsuke Aikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The hexadehydro-Diels–Alder reaction

(2012) Thomas R. Hoye et al.   NATURE

N-Heterocyclic Carbene-Catalyzed Cyclization of Unsaturated Acyl Chlorides and Ketones

(2011) Li-Tao Shen et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent advances in [2+2+2] cycloaddition reactions

(2011) Gema Domínguez et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols

(2011) Y. Izawa et al.   SCIENCE

NHC-Catalyzed Michael Addition to α,β-Unsaturated Aldehydes by Redox Activation

(2010) Suman De Sarkar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Sporolide B and 9-epi-Sporolide B

(2010) K. C. Nicolaou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NHC Catalyzed Oxidations of Aldehydes to Esters: Chemoselective Acylation of Alcohols in Presence of Amines

(2010) Suman De Sarkar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discovery of MK-3207: A Highly Potent, Orally Bioavailable CGRP Receptor Antagonist

(2010) Ian M. Bell et al.   ACS Medicinal Chemistry Letters

Reactions of 4-unsubstituted 4,5-dihydro-1H-indeno[1,2-b]pyridines

(2009) D. Tanaev et al.   Chemistry of Heterocyclic Compounds

Antineoplastic Agents. 556. Isolation and Structure of Coprinastatin 1 fromCoprinus cinereus†,(1)

(2009) George R. Pettit et al.   JOURNAL OF NATURAL PRODUCTS

α′-Hydroxyenones as Mechanistic Probes and Scope-Expanding Surrogates for α,β-Unsaturated Aldehydes in N-Heterocyclic Carbene-Catalyzed Reactions

(2009) Pei-Chen Chiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The discovery of highly potent CGRP receptor antagonists

(2008) Craig A. Stump et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS