期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 44, 页码 15671-15674出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201907609
关键词
Au24Cu6; bimetallic nanomaterials; heterogeneous catalysis; pi-bonding; ring-opening reactions
资金
- National Natural Science Foundation of China [21631001, 21871001, 21672001, U1532141]
- Ministry of Education
- Education Department of Anhui Province
- 211 Project of Anhui University
Bimetallic nanomaterials are of major importance in catalysis. A Au-Cu bimetallic nanocluster was synthesized that is effective in catalyzing the epoxide ring-opening reaction. The catalyst was analyzed by SCXRD and ESI-MS and found to be Au24Cu6(SPhtBu)(22) (Au24Cu6 for short). Six copper atoms exclusively occupy the surface positions in two groups with three atoms for each, and each group was bonded with three thiolate ligands to give a planar motif reminiscent of a benzene ring. In the epoxide-ring opening reaction, Au24Cu6 exhibited superior catalytic activity compared to other homometallic and Au-Cu alloy NCs, such as Au-25 and Au38-xCux. Control experiments and DFT calculations revealed that the pi conjugation among the Cu-S bonds played a pivotal role. This study demonstrates a unique pi conjugation established among the Cu-S bonds as a critical structural motif in the nanocluster, which facilitates the catalysis of a ring-opening reaction.
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