期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 36, 页码 12646-12654出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201905972
关键词
biomimetic nanocones; cation permselective membranes; ion-selective transport; membranes; polyaniline
资金
- National Natural Science Foundation of China [21490581, 91534203, 21875233]
- International Partnership Program of Chinese Academy of Sciences [21134ky5b20170010]
- National Key RAMP
- D Program of China [2018YFB1502301]
- Key Technologies RAMP
- D Program of Anhui Province [18030901079]
- CAS-TWAS Fellowship Council
- Fundamental Research Funds for the Central Universities
Artificial counterparts of conical-shaped transmembrane protein channels are of interest in biomedical sciences for biomolecule detection and selective ion permeation based on ionic size and/or charge differences. However, industrial-scale applications such as seawater desalination, separation of mono- from divalent cations, and treatment of highly-saline industrial waste effluents are still big challenges for such biomimetic channels. A simple monomer seeding experimental approach is used to grow ionically conductive biomimetic charged nanocone pores at the surface of an acid-functionalized membrane. These readily scalable nanocone membranes enable ultra-fast cation permeation (Na+=8.4x vs. Mg2+=1.4x) and high ion charge selectivity (Na+/Mg2+=6x) compared to the commercial state-of-the-art permselective membrane (CSO, Selemion, Japan) owing to negligible surface resistance and positively charged conical pore walls.
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