Copper‐Catalyzed Domino Cyclization/Thiocyanation of Unactivated Olefins: Access to SCN‐Containing Pyrazolines

Visible Light-Induced Thiocyanation of Enaminone C-H Bond to Access Polyfunctionalized Alkenes and Thiocyano Chromones

(2019) Yong Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Electrosynthesis of (E)-Vinyl Thiocyanates from Cinnamic Acids via Decarboxylative Coupling Reaction

(2019) Shun-Ming Yang et al.   ORGANIC LETTERS

Electrochemical ipso‐Thiocyanation of Arylboron Compounds

(2019) Marco Dyga et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Trends in Iron-Catalyzed Reactions towards the Synthesis of Nitrogen-Containing Heterocycles

(2019) Radhakrishnan Sreedevi et al.   ADVANCED SYNTHESIS & CATALYSIS

Homogeneous and Nanoparticle Gold-Catalyzed Hydrothiocyanation of Haloalkynes

(2019) Xiaojun Zeng et al.   ORGANIC LETTERS

Metal-free visible-light-promoted thiocyanation/cyclization cascade for the synthesis of thiocyanato-containing isoquinolinediones

(2019) Yu-Jue Chen et al.   TETRAHEDRON

TMSCl-Catalyzed Electrophilic Thiocyano Oxyfunctionalization of Alkenes Using N-Thiocyano-dibenzenesulfonimide

(2019) Ai-Hui Ye et al.   ORGANIC LETTERS

Photocatalytic difunctionalisations of alkenes with N-SCN sulfoximines

(2018) Duo Zhang et al.   CHEMICAL COMMUNICATIONS

Ultrasound-promoted Brønsted acid ionic liquid-catalyzed hydrothiocyanation of activated alkynes under minimal solvent conditions

(2018) Chao Wu et al.   GREEN CHEMISTRY

Asymmetric Aza-Wacker-Type Cyclization of N-Ts Hydrazine-Tethered Tetrasubstituted Olefins: Synthesis of Pyrazolines Bearing One Quaternary or Two Vicinal Stereocenters

(2018) Xuezhen Kou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of acyloxyl pyrazolines by copper-mediated aminoacyloxylation of unsaturated ketohydrazones

(2018) Manman Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Organocatalyzed Direct α-Thiocyanation of Cyclic β-Ketoesters by N-Thiocyanatophthalimide

(2018) Jiashen Qiu et al.   ORGANIC LETTERS

Copper-Catalyzed Diamination of Alkenes of Unsaturated Ketohydrazones with Amines

(2018) Manman Chen et al.   ORGANIC LETTERS

Copper-Mediated Aminoazidation, Aminohalogenation, and Aminothiocyanation of β,γ-Unsaturated Hydrazones: Synthesis of Versatile Functionalized Pyrazolines

(2018) Li-Jing Wang et al.   ORGANIC LETTERS

Cu-Catalyzed Aminoacyloxylation of Unactivated Alkenes of Unsaturated Hydrazones with Manifold Carboxylic Acids toward Ester-Functionalized Pyrazolines

(2018) Rui-Hua Liu et al.   ORGANIC LETTERS

Aerobic intramolecular aminothiocyanation of unactivated alkenes promoted by in situ generated iodine thiocyanate

(2018) Yangyang Feng et al.   TETRAHEDRON

Visible Light-Driven C-3 Functionalization of Indoles over Conjugat-ed Microporous Polymers

(2018) Weijie Zhang et al.   ACS Catalysis

New Horizons of Photocatalytic Fluoromethylative Difunctionalization of Alkenes

(2018) Takashi Koike et al.   Chem

Organocatalytic Asymmetric Transformations Involving the Cyclic Imine Moiety in Indole and Isoindole Related Heterocycles

(2018) Dao-Juan Cheng et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of α-Trifluoromethylthiolated and α-Thiocyanated Ketones Using Umpoled Enolates

(2018) Xiaowen Xia et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Advances in the Intermolecular Oxidative Difunctionalization of Alkenes

(2018) Jie Lin et al.   CHEMICAL RECORD

Potassium Persulfate-Mediated Thiocyanation of 2H -Indazole under Iron-Catalysis

(2018) Amrita Dey et al.   ADVANCED SYNTHESIS & CATALYSIS

Dual Photoredox/Copper Catalysis for the Remote C(sp3 )−H Functionalization of Alcohols and Alkyl Halides by N -Alkoxypyridinium Salts

(2018) Xu Bao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ag-Catalyzed Thiocyanofunctionalization of Terminal Alkynes To Access Alkynylthiocyanates and α-Thiocyanoketones

(2018) Jie Yang See et al.   ORGANIC LETTERS

Recent Advances in Radical Difunctionalization of Simple Alkenes

(2017) Xing-Wang Lan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Dihydropyrazoles via Ligand-Free Pd-Catalyzed Alkene Aminoarylation of Unsaturated Hydrazones with Diaryliodonium Salts

(2017) Meng-Nan Yang et al.   ORGANIC LETTERS

Photocatalytic Hydrazonyl Radical-Mediated Radical Cyclization/Allylation Cascade: Synthesis of Dihydropyrazoles and Tetrahydropyridazines

(2017) Quan-Qing Zhao et al.   ORGANIC LETTERS

Dioxygen Activation via Cu-Catalyzed Cascade Radical Reaction: An Approach to Isoxazoline/Cyclic Nitrone-Featured α-Ketols

(2017) Xie-Xue Peng et al.   ACS Catalysis

Regioselective Synthesis of Thiocyanate-Containing Isoxazolines via FeIII /K2 S2 O8 -Mediated Radical Thiocyanation/Cyclization Cascade Reaction of β,γ-Unsaturated Oximes

(2017) Fei Ji et al.   Asian Journal of Organic Chemistry

Direct thiocyanation of ketene dithioacetals under transition-metal-free conditions

(2017) Qiao Chen et al.   Organic Chemistry Frontiers

Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds

(2016) Takashi Koike et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center

(2016) Guoyin Yin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Recent Developments in the Stereoselective Synthesis of Nitrogen-Containing Heterocycles usingN-Acylimines as Reactive Substrates

(2016) Enrico Marcantoni et al.   ADVANCED SYNTHESIS & CATALYSIS

Solvent-dependent copper-catalyzed synthesis of pyrazoles under aerobic conditions

(2016) Florian Pünner et al.   CHEMICAL COMMUNICATIONS

A visible-light photocatalytic N-radical cascade of hydrazones for the synthesis of dihydropyrazole-fused benzosultams

(2016) Quan-Qing Zhao et al.   CHEMICAL COMMUNICATIONS

Recent advances in the chemistry of organic thiocyanates

(2016) Thomas Castanheiro et al.   CHEMICAL SOCIETY REVIEWS

Organophotocatalytic Generation of N- and O-Centred Radicals Enables Aerobic Oxyamination and Dioxygenation of Alkenes

(2016) Xiao-Qiang Hu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-metal free thiocyanooxygenation of functionalized alkenes: facile routes to SCN-containing dihydrofurans and lactones

(2016) Li-Na Guo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Various difunctionalizations of acrylamide: an efficient approach to synthesize oxindoles

(2016) Chen-Chen Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

TEMPO-Mediated Aza-Diels–Alder Reaction: Synthesis of Tetrahydropyridazines Using Ketohydrazones and Olefins

(2016) Xiu-Long Yang et al.   ORGANIC LETTERS

Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation

(2016) Xiao-Qiang Hu et al.   Nature Communications

Copper-Catalyzed Oxidative Oxyamination/Diamination of Internal Alkenes of Unsaturated Oximes with Simple Amines

(2016) Rui-Hua Liu et al.   ACS Catalysis

Synthesis of Difluoromethyl Thioethers from Difluoromethyl Trimethylsilane and Organothiocyanates Generated In Situ

(2015) Bilguun Bayarmagnai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical aryl migration reactions and synthetic applications

(2015) Zhi-Min Chen et al.   CHEMICAL SOCIETY REVIEWS

Iron-Catalyzed Decarboxylation of Trifluoroacetate and Its Application to the Synthesis of Trifluoromethyl Thioethers

(2015) Benjamin Exner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Aryl Tri- and Difluoromethyl Thioethers via a CH-Thiocyanation/Fluoroalkylation Cascade

(2015) Kévin Jouvin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Peptide/Protein Stapling and Unstapling: Introduction of s-Tetrazine, Photochemical Release, and Regeneration of the Peptide/Protein

(2015) Stephen P. Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF3-Containing Allyl Azides and Thiocyanates

(2015) Na Zhu et al.   ORGANIC LETTERS

Transition-Metal-Free Tandem Radical Thiocyanooxygenation of Olefinic Amides: A New Route to SCN-Containing Heterocycles

(2015) Hua Yang et al.   ORGANIC LETTERS

Activation of Aryl Thiocyanates Followed by Aryne Insertion: Access to 1,2-Thiobenzonitriles

(2015) Martin Pawliczek et al.   ORGANIC LETTERS

Hydrazonyl Radical-Participated Tandem Reaction: A Strategy for the Synthesis of Pyrazoline-Functionalized Oxindoles

(2015) Xiao-Yong Duan et al.   ORGANIC LETTERS

Photocatalytic Radical Trifluoromethylation/Cyclization Cascade: Synthesis of CF3-Containing Pyrazolines and Isoxazolines

(2015) Qiang Wei et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3-Containing Alkyl Thiocyanates

(2015) Zhaoli Liang et al.   ORGANIC LETTERS

Selective Access to 4-Substituted 2-Aminothiazoles and 4-Substituted 5-Thiocyano-2-aminothiazoles from Vinyl Azides and Potassium Thiocyanate Switched by Palladium and Iron Catalysts

(2015) Binhui Chen et al.   ORGANIC LETTERS

Difunctionalization of Acrylamides through C–H Oxidative Radical Coupling: New Approaches to Oxindoles

(2015) Jin-Heng Li et al.   SYNTHESIS-STUTTGART

Catalytic Diamination of Olefins via N–N Bond Activation

(2014) Yingguang Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition from π Radicals to σ Radicals: Substituent-Tuned Cyclization of Hydrazonyl Radicals

(2014) Xiao-Yong Duan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photocatalytic Generation of N-Centered Hydrazonyl Radicals:  A Strategy for Hydroamination of β,γ-Unsaturated Hydrazones

(2014) Xiao-Qiang Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylation of Alkenes with Concomitant Introduction of Additional Functional Groups

(2014) Hiromichi Egami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Epoxidation and Aziridination of Olefins and Their Synthetic Applications

(2014) Yingguang Zhu et al.   CHEMICAL REVIEWS

Addition of CF3 across unsaturated moieties: a powerful functionalization tool

(2014) Estíbaliz Merino et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in heterobimetallic palladium(ii)/copper(ii) catalyzed domino difunctionalization of carbon–carbon multiple bonds

(2014) Egle M. Beccalli et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iminoxyl Radical-Promoted Dichotomous Cyclizations: Efficient Oxyoximation and Aminooximation of Alkenes

(2014) Xie-Xue Peng et al.   ORGANIC LETTERS

Tandem Radical Cyclization of N-Arylacrylamides: An Emerging Platform for the Construction of 3,3-Disubstituted Oxindoles

(2014) Jia-Rong Chen et al.   SYNTHESIS-STUTTGART

Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

(2014) Grégory Danoun et al.   Chemical Science

Microwave-assisted synthesis of asymmetric disulfides

(2014) Xiaogang Lu et al.   RSC Advances

Radical-Mediated Diamination of Alkenes with Phenylhydrazine and Azodicarboxylates: Highly Diastereoselective Synthesis oftrans-Diamines from Cycloalkenes

(2013) Ming-Kui Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrazone Radical Promoted Vicinal Difunctionalization of Alkenes and Trifunctionalization of Allyls: Synthesis of Pyrazolines and Tetrahydropyridazines

(2013) Xiao-Yong Duan et al.   JOURNAL OF ORGANIC CHEMISTRY

Pyrazolines: A Biological Review

(2013) Akranth Marella et al.   MINI-REVIEWS IN MEDICINAL CHEMISTRY

Catalytic Aminohalogenation of Alkenes and Alkynes

(2013) Sherry R. Chemler et al.   ACS Catalysis

Oxime Radical Promoted Dioxygenation, Oxyamination, and Diamination of Alkenes: Synthesis of Isoxazolines and Cyclic Nitrones

(2012) Bing Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted-Acid-Catalyzed Asymmetric Multicomponent Reactions for the Facile Synthesis of Highly Enantioenriched Structurally Diverse Nitrogenous Heterocycles

(2011) Jie Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis and Biological Activity of Chiral Dihydropyrazole: Potential Lead for Drug Design

(2011) X.-H. Liu et al.   MINI-REVIEWS IN MEDICINAL CHEMISTRY

New pyrazoline derivatives and their antidepressant activity

(2010) Zafer Asım Kaplancıklı et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Simple and quick preparation of α-thiocyanate ketones in hydroalcoholic media. Access to 5-aryl-2-imino-1,3-oxathiolanes

(2009) Fabricio R. Bisogno et al.   GREEN CHEMISTRY

Catalytic Enantioselective Synthesis of α,β-Diamino Acid Derivatives

(2009) Le Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design, synthesis, and biological evaluation of 1-(4-sulfamylphenyl)-3-trifluoromethyl-5-indolyl pyrazolines as cyclooxygenase-2 (COX-2) and lipoxygenase (LOX) inhibitors

(2008) M.V. Ramana Reddy et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Atom transfer radical addition and polymerization reactions catalyzed by ppm amounts of copper complexes

(2008) Tomislav Pintauer et al.   CHEMICAL SOCIETY REVIEWS

Synthesis, molecular modeling studies and selective inhibitory activity against MAO of N1-propanoyl-3,5-diphenyl-4,5-dihydro-(1H)-pyrazole derivatives

(2008) Franco Chimenti et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Synthesis of novel thiazolone-based compounds containing pyrazoline moiety and evaluation of their anticancer activity

(2008) Dmytro Havrylyuk et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY