期刊
ACS CENTRAL SCIENCE
卷 5, 期 9, 页码 1507-1513出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscentsci.9b00403
关键词
-
资金
- STROBE, an NSF STC [DMR 1548924]
- University of California, Riverside
- National Science Foundation [CHE-1455348, CHE1626673, DGE-1650604]
- Arnold and Mabel Beckman Foundation
- Pew Charitable Trusts
- Searle Scholars Program
- U.S. Department of Energy [DE-FC0202ER63421]
- National Institutes of Health
- National Institute of General Medical Sciences [P41 GM102403, R35 GM128867]
- David and Lucile Packard Foundation
- Alfred P. Sloan Foundation
Here we apply microcrystal electron diffraction (MicroED) to the structural determination of transition-metal complexes. We find that the simultaneous use of 300 keV electrons, very low electron doses, and an ultrasensitive camera allows for the collection of data without cryogenic cooling of the stage. This technique reveals the first crystal structures of the classic zirconocene hydride, colloquially known as Schwartz's reagent, a novel Pd(II) complex not amenable to solution-state NMR or X-ray crystallography, and five other paramagnetic and diamagnetic transition-metal complexes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据