期刊
ADVANCED MATERIALS INTERFACES
卷 6, 期 19, 页码 -出版社
WILEY
DOI: 10.1002/admi.201900858
关键词
Ag nanoparticle; core-shell structure; electrochemistry; energy storage; nickel-cobalt amorphous hydroxide
资金
- Key Project of Chinese National Programs for Research and Development [2016YFC0203800]
- National Natural Science Foundation of China [51578288]
- Natural Science Foundation of Jiangsu Province [BK20160834]
- Startup Foundation for Introducing Talent of NUIST, Industry-Academia Cooperation Innovation Fund Projects of Jiangsu Province [BY2016004-09]
- Jiangsu Province Scientific and Technological Achievements into a Special Fund Project [BA2016055, BA2017095]
- Top-notch Academic Programs Project of Jiangsu Higher Education Institutions
Herein, a silver@amorphous nickel-cobalt hydroxide (Ag@NCOH) battery-type electrode with the morphology of core-shell nanoparticle is successfully fabricated through coordination etching and precipitating route. This electrode exhibits excellent electrochemical performance, including superior specific capacity (approximate to 718.1 C g(-1) at 1 A g(-1)), excellent rate capability (71.9% capacity retention at 30 A g(-1)), as well as good cycling stability (83.2% capacity retention over 4000 cycles) for hybrid supercapacitors. According to the results of the characterization analysis and systematic electrochemical testing, the Ag nanoparticles in core-shell structure can significantly enhance the conductivity and accelerate the rate of electron transport. Meanwhile, the nanostructures and grain boundaries of amorphous hydroxide materials can effectively improve to expose the electrochemical active sites to electrolyte. Moreover, the hybrid supercapacitor assembled from Ag@NCOH and active carbon (AC) exhibits good performance (energy density of 39.88 W h kg(-1) at power density of 375 W kg(-1)) and superior cycling stability (85.39% capacitance retention over 9000 cycles). This work demonstrates an effective strategy to construct highly effective and stable amorphous electrode materials for hybrid supercapacitors.
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