期刊
ACS CATALYSIS
卷 9, 期 11, 页码 10418-10425出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b03380
关键词
B-H activation; rhodium; o-carborane; dioxazolone; amidation
资金
- National Research Foundation of Korea (NRF) - Korea government [2011-0018355, 2017R1A4A1015405]
A rhodium-catalyzed direct and regioselective amidation of the cage B(4)-H bond in a wide range of o-carboranes with alkyl-, aryl-, and heteroaryl-substituted dioxazolones is demonstrated by carboxylic acid-assisted B(4)-H bond activation in carborane clusters, providing a number of amidated o-carboranes in high yields with the release of carbon dioxide. Moreover, the selective 2-fold decarboxylative amidation reaction of the cage B(4)-H bond in o-carborane was accessed.
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