期刊
WATER RESEARCH
卷 159, 期 -, 页码 214-222出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.watres.2019.05.002
关键词
Advanced water treatment; Dissolved organic matter; Orbitrap mass spectrometry; Unknown disinfection by-product; Unknown screening analysis
资金
- Core Research for Evolutional Science and Technology (CREST) project - Japan Science and Technology Agency under the Development of well-balanced urban water use system adapted to climate change program
- JSPS KAKENHI [17H03330]
- Grants-in-Aid for Scientific Research [17H03330] Funding Source: KAKEN
We investigated semiquantitative changes in almost 1000 dissolved organic matter (DOM) features during oxidation with 1 mg of O-3 per liter (mg OA), 4 mg O-3/L, or 4 mg O-3/L + 2.5 mg of H2O2 per liter (advanced oxidation process, AOP) by unknown screening analysis with Orbitrap mass spectrometry. The consequential effects on formation of unknown disinfection by-products (DBPs) by chlorination were evaluated in laboratory-scale experiments. Several hundred unsaturated DOM features with positive oxygen-subtracted double bond equivalents per carbon ((DBE-O)/C) were decomposed by the ozone only treatment and AOP. The AOP decomposed some saturated (negative (DBE-O)/C)) and reduced molecules, which had negative carbon oxidation states (C-os). Several hundred saturated oxidation by-products were detected after ozonation and the AOP. After chlorination, the samples pre-treated with ozone alone resulted in higher formation of unknown DBPs than the AOP pre-treated sample or the sample without oxidation. Over half of the DBP precursors, estimated by electrophilic substitution, were not totally decomposed by any oxidation process, but they were increased after the ozone-only process and AOR DBP precursors produced by the ozone-only process or AOP formed unique unknown DBPs. Therefore, post-treatment processes after oxidation and before chlorination are important to minimize formation of unknown DBPs. (C) 2019 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据