Article
Engineering, Environmental
Weihua Fei, Jie Gao, Najun Li, Dongyun Chen, Qingfeng Xu, Hua Li, Jinghui He, Jianmei Lu
Summary: A unique visible-light active Ni foam@NiFe-LDH/Co3O4 composite was successfully prepared, which can efficiently remove BPA and Cr(VI) from water. The modified photoanode showed enhanced catalytic performance and environmental purification potential.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Physical
Giuseppe Prestopino, Riccardo Pezzilli, Nicola Jose Calavita, Claudio Leonardi, Christian Falconi, Pier Gianni Medaglia
Summary: Layered Double Hydroxides (LDHs) possess exceptional properties and can be ideal building blocks for pyroelectric nanogenerators due to their high gradients of composition and energy-levels, size effects, and simplicity of fabrication and tuning.
Article
Chemistry, Physical
Lianyang Zhang, Yue Meng, Hui Shen, Jinhua Li, Chunfang Yang, Bo Xie, Shengjie Xia
Summary: A core-shell structure S-scheme heterojunction catalyst (Bi2O3@LDHs) was synthesized and used for photodegradation of Rhodamine B. The effects of catalyst amount, light intensity, pH value, and reaction temperature on degradation performance were discussed, with the best removal rate reaching 90.36%. Radical characterization and DFT calculation were utilized to analyze the formation mechanism of built-in electric field and promotion of S-scheme electron transport path in the heterojunction, along with degradation intermediates and paths discussion.
APPLIED SURFACE SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Bayu Wiyantoko, Puji Kurniawati, Tri Esti Purbaningtias, Muhammad Husnu Jauhari, Amri Yahya, Muchammad Tamyiz, Is Fatimah, Ruey-an Doong
Summary: The present study aimed to prepare and characterize calcined Mg/Al layer double hydroxides (LDHs) for the adsorption of methyl orange in a batch system. The results showed that calcined LDHs were efficient adsorbents for the remediation of methyl orange at relatively high concentrations.
MATERIALS RESEARCH EXPRESS
(2022)
Article
Chemistry, Multidisciplinary
Xuefei Xu, Shaohua Shi, Yulin Tang, Guizhen Wang, Maofan Zhou, Guoqing Zhao, Xuechun Zhou, Shiwei Lin, Fanbin Meng
Summary: The newly developed NiAl-LDH/G composite, synthesized by atomic-layer-deposition-assisted in situ growth, exhibits excellent microwave absorption performance and corrosion resistance, showing great potential for practical applications.
Article
Chemistry, Physical
Xuefei Liu, Xiaoyan Wang, Beibei Yang, Junzheng Zhang, Jun Lu
Summary: In this study, Ni-Mn-Cu-Co-Fe-Al high-entropy layered oxides (HELOs) with a layered nanosheet structure were successfully constructed by a simple pathway of topological transformation under relatively low temperature. These HELOs exhibited excellent activity and selectivity for CO2 photoelectroreduction, and also showed improved performance in a photo-assisted Zn-CO2 battery.
Article
Chemistry, Physical
Zesheng Li, Kuncan Xiao, Changlin Yu, Hongqiang Wang, Qingyu Li
Summary: A newly 3-D architecture of AGC/MnCo-LDHs nanocomposites was prepared in this study. The nanocomposites showed excellent electrochemical performances as efficient bifunctional catalysts, with the key factors being the 3-D porous architecture of MnCo-LDHs and carrier effect of AGC. These materials have broad application prospects in various fields.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Engineering, Environmental
Xuefan Deng, Shiying Xia, Haixu Zhao, Zhengxi Wang, Bin Qi, Xiaohai Zhou, Haibo Zhang
Summary: Single-atom (SA) catalysts exhibit excellent catalytic activity, selectivity, and metal utilization, but their complex preparation methods limit their widespread application. In this study, layered double hydroxides (LDHs) with unique charge distributions were combined with the dodecahydro-closo-dodecaborate anion [closo-B12H12]2- to design two different gold (Au) catalysts. One is the composite dual-site Au SA/Au cluster catalyst (B12H12-MgAl-LDH-Au) prepared by utilizing the anion exchangeability and spatial domain-limiting properties of LDH and the reducibility of [closo-B12H12]2-. The other is Au nanoparticle catalysts (MgAl-LDH@B12H12@Au) obtained by immobilizing [closo-B12H12]2- on the LDH laminate. The B12H12-MgAl-LDH-Au catalyst efficiently catalyzes the selective reduction of 27 different nitrobenzene substrates to corresponding azoxybenzenes (AOBs) under 450 nm wavelength radiation. However, larger nanoparticles show higher efficiency in absorbing visible light energy, thus 10 different AOB compounds were prepared using the MgAl-LDH@B12H12@Au system.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
X. Chen, M. He, Y. Zhou, G. He, C. Meng, Q. Cheng, F. Li
Summary: Reasonably designing the structure of composite materials and effectively increasing electroactive sites of electrode materials can enhance the electrochemical performance for supercapacitors.
MATERIALS TODAY CHEMISTRY
(2021)
Article
Chemistry, Physical
Yongming Zhong, Siyuan Yang, Yueping Fang, Kaifeng Wang, Jianteng Sun, Wengang Wu
Summary: This study demonstrates the construction of a film-like photocatalyst ZnO-CdS(Ar)@Ni, which significantly enhances the hydrogen generation rate and can be used for efficient photoelectrochemical water splitting. The enhanced performance is attributed to the unique ZnO-CdS heterojunction structure, the combination of 1D nanorod array with 3D Ni foam substrate, and the efficient electron collection and transfer within the Ni foam.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Analytical
Akarapong Prakobkij, Purim Jarujamrus, Suticha Chunta, Runglawan Chawengkirttikul, Tinnagon Keawin, Nutthaporn Malahom, Suparb Tamuang, Maliwan Amatathongchai, Daniel Citterio
Summary: Nitrogen-doped carbon dots/Ni-MnFe-layered double hydroxides (N-CDs/Ni-MnFe-LDHs) are demonstrated to be superior peroxidase mimic antibody labels with efficient enzyme-like activity and high sensitivity, making them suitable for developing highly sensitive immunosensors.
Article
Materials Science, Multidisciplinary
Ying Zhang, Liang Li, Changlong Du, Gengping Wan, Qiyi Wei, Xueqing Zhou, Yanran Su, Yang Xu, Guizhen Wang
Summary: In this study, a corrosion-resistant microwave absorber was successfully prepared using an atomic layer deposition method. The composite material, consisting of 3D NiAl-layered double hydroxide/carbon nanofibers (NiAl-LDH/CNFs), demonstrated excellent microwave absorbing properties and strong corrosion resistance. The optimized NiAl-LDH/CNFs showed the strongest reflection loss and the widest effective absorption bandwidth, thanks to the cooperative effect of interfacial polarization loss, conduction loss, and three-dimensional porous structure. This work provides guidance for designing microwave absorbers that satisfy corrosion resistance.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Yi He, Xinyi Zhou, Shixiang Ding, Qiang Hu, Dunmin Lin, Xijun Wei
Summary: The study successfully synthesized ZnO/CoO@NiCoS nanohybrids with double-layer heterojunction, improving the electrode conductivity, providing sufficient active sites, and enhancing the physical chemical stability of ZnO/CoO nanowires. The obtained ZnO/CoO@NiCoS exhibited high specific capacity, power density, energy density, and cycling stability, showing potential for use in supercapacitors.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Environmental
Fengyan Shi, Mengna Ding, Haijian Tong, Yuping Yang, Junyang Zhang, Lianzhou Wang, Hexing Li, Yuning Huo
Summary: A new photoelectrocatalytic antibacterial system based on ZIF-67/ZnO@Co foil was developed, which captures bacteria using thorn-like ZnO nanorods and efficiently adsorbs leaked K+ ions using porous ZIF-67. The system achieves complete destruction of bacteria by decomposing their cell membranes and accelerating K+ leakage through visible-light photocatalytic activity. This system shows potential for future sterilization applications.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Xiaorui Yang, Jihui Wang, Zexing Ren, Wenbin Hu
Summary: The NiFe-LDHs film was fabricated on Q235 steel using a two-step hydrothermal method, and the superhydrophobic NiFe-LDH-PFDTES film was obtained by PFDTES modification. The structure and composition of the films were analyzed, and their wettability and corrosion resistance in a NaCl solution were evaluated. The results showed that the NiFe-LDH-PFDTES film exhibited excellent corrosion protection with a high contact angle and low sliding angle. The film achieved a superior corrosion resistance compared to the NiFe-LDHs film, indicating its potential for industrial applications.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Review
Chemistry, Multidisciplinary
Jiajie Ni, Qiyang Cheng, Sisi Liu, Mengfan Wang, Yanzheng He, Tao Qian, Chenglin Yan, Jianmei Lu
Summary: Electrochemical reduction of CO2 (CO2RR) and nitrogen (NRR) has potential as an alternative to fossil fuel-based technologies for producing valuable chemicals. However, the low energy and Faradaic efficiencies hinder their practical application, despite efforts to overcome these limitations. This review focuses on the different electrolytes used in CO2RR and NRR, including aqueous and non-aqueous electrolytes such as acidic, neutral, alkaline, water-in-salt, organic, and ionic-liquids electrolytes. The roles of these electrolytes and their potential for improving electrocatalytic performance are discussed, with suggestions for future research priorities to enhance understanding and guide selection for next-generation gas-involved electrochemical reactions.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Sisi Liu, Mengfan Wang, Haoqing Ji, Lifang Zhang, Jiajie Ni, Najun Li, Tao Qian, Chenglin Yan, Jianmei Lu
Summary: Photocatalytic nitrogen reduction reaction (PNRR) is a sustainable approach for ammonia synthesis. By combining porous framework materials with a novel solvent-in-gas system, the activity of PNRR can be significantly improved. This system-level strategy is also applicable in photocatalytic CO2 reduction, making it an important component of photosynthetic methodology.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Yibo Zhang, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: Multidimensional hierarchical hollow Co3O4/ZnIn2S4 tubular core-shell heterostructures were prepared by growing ultrathin 2D ZnIn2S4 nanosheets on 1D hollow Co3O4 nanotubes using a solvothermal method. This design not only prevents the self-assembly aggregation of ZnIn2S4 nanosheets, but also broadens their light-absorption range and enhances the utilization of visible light. The p-n heterojunction in the photocatalyst generates an internal electric field, which facilitates the separation and migration of photogenerated charge carriers and effectively suppresses their recombination.
APPLIED SURFACE SCIENCE
(2023)
Article
Engineering, Environmental
Bingke Xie, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: This study synthesized Cs3Bi2Br9 lead-free perovskite and formed Cs3Bi2Br9/g-C3N4 heterojunctions for photocatalytic removal of NOx, resulting in enhanced NO removal efficiency. The experimental results were consistent with photocurrent and electrochemical impedance spectroscopy data, confirming the mechanism and formation of products. This study provides insights into the potential applications of lead-free perovskite-based heterostructures in the field of photocatalysis.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Yunchong Liu, Xunxun Li, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jinghui He, Jianmei Lu
Summary: This study presents the first construction of Ce-Co oxide thin-walled nanoboxes, which enhance catalytic performance by activating bulk-phase lattice oxygen and increasing the surface-adsorbed oxygen content, achieving complete catalytic oxidation of toluene.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Chemistry, Physical
Guping Zhang, Xunxun Li, Mengmeng Wang, Xueqing Li, Yaru Wang, Shuting Huang, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: This research constructs a stable p-n heterojunction of 2D/2D Co3O4/ZnIn2S4 with a strong built-in electric field, resulting in a highly efficient visible-light photocatalytic hydrogen generation. The improved photocatalytic performance is attributed to enhanced light absorption, abundant active sites, short charge transport distance, and high separation efficiency of photogenerated carriers. This study provides a new approach for the rational design and manufacturing of highly efficient 2D/2D heterojunction photocatalysts.
Article
Horticulture
Jian-mei Lu, Sven Landrein, Xing-zhen Song, Min Wu, Chun-fen Xiao, Peng Sun, Hui-zhen Jia, Jia-rui Yue, You-kai Xu
Summary: This study investigated the effect of polyploidy on phenotypic traits in different variants of Kaempferia. The results showed significant differences in traits such as leaf width and stomatal density. Furthermore, pentaploid individuals had higher (E)-Ethyl-p-methoxycinnamate content in their rhizomes but lower content in their leaves. These findings provide valuable references for plant identification and breeding in Kaempferia.
SCIENTIA HORTICULTURAE
(2023)
Article
Chemistry, Multidisciplinary
Chang Zhou, Qi-Meng Sun, Qiang Cao, Jing-Hui He, Jian-Mei Lu
Summary: Atomically dispersed Fe on three-dimensional N-doped carbon supports shows promise as a catalyst for microwave remediation of soil contaminated by Chloramphenicol (CAP). Due to the synergistic effect of microwave hot spots and reactive oxygen species, the catalyst can rapidly and effectively remove CAP from the soil.
Article
Chemistry, Physical
Liujun Jin, Rui Ji, Haibo Wan, Jinghui He, Peiyang Gu, Hongzhen Lin, Qingfeng Xu, Jianmei Lu
Summary: A simple hydrothermal method was reported to fabricate novel heterostructure nanoarrays comprising NiSe nanorods evenly integrated with nickel-terephthalic acid (Ni-TPA) nanosheets. In the A-C heterostructure electrocatalyst, highly conductive NiSe nanorods facilitate axial charge transfer in the interconnection network. TPA-induced formation of crystalline-amorphous heterostructures exposes more active sites and regulates the electronic structure of Ni. The optimal Ni-TPA@NiSe/NF electrode presents a low potential of 1.37 V to deliver 100 mA cm-2 for UOR while maintaining impressively robust stability at high current densities for at least 40 h. In situ electrochemical Raman spectroscopy and differential electrochemical mass spectrometry analyses reveal that the superior UOR activity originates from NiOOH species and the terminal product of nitrogen is generated via intramolecular N-N coupling in the urea molecule. More importantly, this study offers deep insights into designing and fabricating effective UOR electrocatalysts with abundant A-C grain boundaries.
Article
Electrochemistry
Hao-Yu Zhang, Lan-Xin Li, Wu-Ji Sun, Jing-Hui He, Qing-Feng Xu, Jian-Mei Lu
Summary: The high dispersion of Bi2O3 nanosheets can be achieved through in-situ growth on Ti3C2Tx MXene nanosheets, improving the efficiency of charge transmission and thus enhancing the electrocatalytic ammonia production performance.
Article
Chemistry, Inorganic & Nuclear
Xiaofang Liu, Jianhua Zhang, Liujun Jin, Chunchao Chen, Jinghui He, Qingfeng Xu, Jianmei Lu
Summary: Urea degradation is crucial in the nitrogen cycle, and understanding the electro-oxidation mechanism and designing catalysts is significant. A stable and active catalyst (PBA@NiFe/NF) loaded on nickel foam was synthesized, and in situ Raman spectra showed the maintenance of stable Ni(II) state during urea oxidation. The participation of iron significantly improved the electro-oxidation of urea. This work provides new insights for prolonging Ni(II) activity in urea electrocatalytic oxidation.
INORGANIC CHEMISTRY
(2023)
Article
Polymer Science
Wu-Ji Sun, Xiong-Jun Liu, Li-Juan Yuan, Han Xiao, Jian-Mei Lu
Summary: Polyethylene has limitations in HV/UHV power cables due to its low thermal stability and breakdown strength, despite its excellent electrical insulation. A new organic peroxide, Bi25, has been developed to efficiently trigger the crosslinking of polyethylene (Bi25-XLPE). Bi25-XLPE, with void-free nature, higher crosslinking density, and crystallinity, meets the insulation standard for 500 kV power cables. The breakdown strength (up to 61.66 kV/mm) and stability of Bi25-XLPE are confirmed by a constructed 500 kV power cable model using COMSOL.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Physical
Xueqing Li, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: In this study, an all-organic S-scheme heterojunction (PDINH/PCN) was obtained by in situ recrystallization of perylene-3, 4, 9, 10-tetracarboxylic diimide (PDINH) on the surface of porous carbon nitride (PCN). This structure enables the light-driven reaction of oxygen and water to produce hydrogen peroxide (H2O2), converting solar energy into green products. The design of a hierarchical porous photocatalyst improved mass transfer, enhanced light absorption, and increased specific surface area. The S-scheme heterojunction formed at the interface of PDINH and PCN facilitated carrier separation and transfer. The H2O2 production rate reached 922.4 lmol g-1h-1, which was 2.6 and 53.3 times higher than that of PCN and PDINH, respectively. Therefore, the all-organic S-scheme heterojunction provides insight for enhancing photocatalytic H2O2 production.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
Jinyan Huo, Liujun Jin, Chunchao Chen, Dongyun Chen, Zhichuan Xu, Cecilia Devi Wilfred, Qingfeng Xu, Jianmei Lu
Summary: This study demonstrates the production of sulfur using a sulfide oxidation reaction (SOR) technique, and shows that a NiS-doped cobalt sulfide NiS-CoS-supported NiCo alloy foam can serve as a superior electrocatalyst with high stability. It also reveals the sulfurophobicity feature of the catalyst, preventing electrode corrosion during the SOR process. Additionally, the study unveils the chain-growth mechanism of the SOR.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Engineering, Chemical
Bingshu Jiang, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: This study reports a photocatalyst based on reduced graphene oxide and CdS nanoparticles, modified with anthraquinone-2-sulfonate (AQS), which achieved a photocatalytic H2O2 yield of 558 μmol g(-1) h(-1) in purified water. The high performance of this composite photocatalyst is attributed to the combination of graphene and CdS promoting charge-carrier separation/transfer, increasing the quantity of adsorption and reaction sites, and the selective two-electron oxygen reduction capacity of AQS.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Energy & Fuels
Siddharth Sradhasagar, Omkar Subhasish Khuntia, Srikanta Biswal, Sougat Purohit, Amritendu Roy
Summary: In this study, machine learning models were developed to predict the bandgap and its character of double perovskite materials, with LGBMRegressor and XGBClassifier models identified as the best predictors. These models were further employed to predict the bandgap of novel bismuth-based transition metal oxide double perovskites, showing high accuracy, especially in the range of 1.2-1.8 eV.
Article
Energy & Fuels
Wei Shuai, Haoran Xu, Baoyang Luo, Yihui Huang, Dong Chen, Peiwang Zhu, Gang Xiao
Summary: In this study, a hybrid model based on numerical simulation and deep learning is proposed for the optimization and operation of solar receivers. By applying the model to different application scenarios and considering multiple performance objectives, small errors are achieved and optimal structure parameters and heliostat scales are identified. This approach is not only applicable to gas turbines but also heating systems.
Article
Energy & Fuels
Mubashar Ali, Zunaira Bibi, M. W. Younis, Muhammad Mubashir, Muqaddas Iqbal, Muhammad Usman Ali, Muhammad Asif Iqbal
Summary: This study investigates the structural, mechanical, and optoelectronic properties of the BaCuF3 fluoroperovskite using the first-principles modelling approach. The stability and characteristics of different cubic structures of BaCuF3 are evaluated, and the alpha-BaCuF3 and beta-BaCuF3 compounds are found to be mechanically stable with favorable optical properties for solar cells and high-frequency UV applications.
Article
Energy & Fuels
Dong Le Khac, Shahariar Chowdhury, Asmaa Soheil Najm, Montri Luengchavanon, Araa mebdir Holi, Mohammad Shah Jamal, Chin Hua Chia, Kuaanan Techato, Vidhya Selvanathan
Summary: A novel recycling system is proposed in this study to decompose and reclaim the constituent materials of organic-inorganic perovskite solar cells (PSCs). By utilizing a one-step solution process extraction approach, the chemical composition of each layer is successfully preserved, enabling their potential reuse. The proposed recycling technique helps mitigate pollution risks, minimize waste generation, and reduce recycling costs.
Article
Energy & Fuels
Peijie Lin, Feng Guo, Xiaoyang Lu, Qianying Zheng, Shuying Cheng, Yaohai Lin, Zhicong Chen, Lijun Wu, Zhuang Qian
Summary: This paper proposes an open-set fault diagnosis model for PV arrays based on 1D VoVNet-SVDD. The model accurately diagnoses various types of faults and is capable of identifying unknown fault types.