4.6 Article

Gamma rays irradiation effects in thin film polyethylene terephthalate polymer

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RADIATION PHYSICS AND CHEMISTRY
卷 162, 期 -, 页码 18-22

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.radphyschem.2019.04.034

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Polyethylene terephthalate; Gamma rays; FTIR; XRD; UV-vis

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The effect of gamma rays irradiation on structural properties of polyethylene terephthalate (PET) has been studied using Fourier Transform Infrared Spectroscopy (FTIR), X-rays diffraction (XRD) and UV-Visible spectrophotometry techniques. The gamma rays irradiations were performed, using Co-60 source with mean energy of 1.25 MeV, at Nuclear Research Centre of Algiers, Algeria. The gamma absorbed dose rate was about 1.3 kGy/h as measured using the Frick dosimeter. Several PET samples with a thickness of 6 mu m were irradiated at room temperature with the presence of air atmosphere at different doses (0.05-5 MGy). The FTIR analysis reveals that the intensities of the different absorption bands decrease with increasing gamma rays dose. This is attributed to the chain scission induced by gamma rays irradiation. It is found from XRD analysis that the crystallinity is reduced after irradiation. The variation in crystallite size is also observed. The UV-vis spectra show a large absorption band extended from 310 to 355 nm assigned to the formation of extended systems of conjugate bonds with the creation of carbon clusters. The optical absorbance in this range increases linearly with the gamma rays dose. An empirical relation is established to estimate gamma dose from this correlation. Both direct and indirect energy gaps are found to decrease with increasing gamma rays dose indicating the appearance of new electronic transitions. Moreover, it is also observed that the Urbach energy increases with the gamma rays dose. This indicates the disorganization of the PET structure after irradiation.

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