期刊
ORGANIC LETTERS
卷 21, 期 16, 页码 6259-6263出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02142
关键词
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资金
- National Natural Science Foundation of China [21772202, 21831008, S1534004, U1362110]
- Beijing Municipal Science & Technology Commission [Z181100004218004]
- Beijing National Laboratory for Molecular Sciences [BNLMS-CXXM-201901]
The [4 + 1] annulation of benzamides and aldehydes for phthalide synthesis was achieved via rhenium-catalyzed C-H activation, which demonstrates an unprecedented reaction pattern distinct from those of other transition-metal catalyses. The reaction also features readily available starting materials, a wide scope for both electro-rich and electro-deficient substrates, and the elimination of homoannulation byproducts.
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