期刊
ORGANIC LETTERS
卷 21, 期 18, 页码 7602-7608出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02870
关键词
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资金
- National Natural Science Foundation of China [21772183]
- Fundamental Research Funds for the Central Universities [WK2060190086]
- 1000-Youth Talents Plan start-up funding
- University of Science and Technology of China
Reported is a nickel-catalyzed reductive arylalkylation of unactivated alkenes tethered to aryl iodides with redox active N-hydroxyphthalimide esters as the alkyl source through successful merging of migratory insertion and decarboxylative cross-coupling in a cascade. This new method avoids the use of pregenerated organometallic reagents and thus enables the synthesis of diverse benzene-fused carbo- and heterocyclic compounds with high tolerance of a wide range of functional groups.
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