期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 167, 期 1, 页码 -出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0032001JES
关键词
-
资金
- Nanostructures for Electrical Energy Storage (NEES), an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DESC0001160]
- U.S. Department of Energy's National Nuclear Security Administration [DE-NA0003525]
- [NSF-1751553]
At high operating voltages, metals like Mn, Ni, and Co dissolve from Li-ion cathodes, deposit at the anode, and interfere with the performance of the solid-electrolyte interphase (SEI) to cause constant Li loss. The mechanism by which these metals disrupt SEI processes at the anode remains poorly understood. Experiments from Part I of this work demonstrate that Mn, Ni, and Co all affect the electronic properties of the SEI much more than the morphology, and that Mn is the most aggressively disruptive of the three metals. In this work we determine how a proposed electrocatalytic mechanism can explain why Mn contamination is uniquely detrimental to SEI passivation. We develop a microkinetic model of the redox cycling mechanism and apply it to experiments from Part I. The results show that the thermodynamicmetal reduction potential does not explain why Mn is the most active of the three metals. Instead, kinetic differences between the three metals are more likely to govern their reactivity in the SEI. Our results emphasize the importance of local coordination environment and proximity to the anode within the SEI for controlling electron transfer and resulting capacity fade. (C) The Author(s) 2019. Published by ECS.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据