期刊
JOURNAL OF POWER SOURCES
卷 432, 期 -, 页码 1-7出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2019.05.066
关键词
Na2FePO4F; Poly 3,4-ethylenedioxythiophene; Na-ion batteries; Advanced analysis; Cathode
资金
- Korea Institute of Materials Science (KIMS) [PNK6080]
- National Research Council of Science & Technology (NST), Republic of Korea [PNK6080] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Na2FePO4F encircled by a nanolayer composed of a conductive polymer, poly(3,4-ethylenedioxythiophene) (PEDOT), is prepared using a simple low-temperature process, and X-ray diffraction analysis indicates that the Na2FePO4F-PEDOT composite is the pure phase without any impurities. The existence and uniform encapsulation of PEDOT on the surface of the Na2FePO4F particles are clearly confirmed through Fourier-transform infrared spectroscopy and transmission electron microscopy. The PEDOT coating results in remarkably enhanced electrochemical performance compared with that of pristine Na2FePO4F. At C/5 (1C = 124 mA g(-1)), the Na2FePO4F-PEDOT composite retains a specific capacity of similar to 123.1 mAh g(-1), which is close to its theoretical capacity. Even at 10C, the Na2FePO4F-PEDOT composite delivers a capacity of similar to 76.1 mAh g(-1), which is similar to 10 times higher than that of pristine Na2FePO4F under the same conditions. Furthermore, the Na2FePO4F-PEDOT composite maintains similar to 70% of its initial discharge capacity over 700 cycles at 1C.
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