4.7 Article

Formation of MgCO3•3H2O in the CO2 mineralization system using Mg(OH)2 as an intermediate at 20 °C

期刊

出版社

ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2019.03.043

关键词

MgCO3 center dot 3H(2)O; Mg(OH)(2); CO2 mineralization; Growth mechanism

资金

  1. National Nature Science Foundation of China [U1707603]
  2. Key Research and Development Project of Shanxi Province of China [201603D312003]
  3. Program for Sanjin Scholars of Shanxi Province

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The formation of MgCO3 center dot 3H(2)O in the CO2 mineralization system was investigated using Mg(OH)(2) as an intermediate at 20 degrees C. Liquid and solid analyses were done for qualitative and quantitative composition characterizations of the reacted samples. Results showed that the morphology of Mg(OH)(2) had an obvious effect on the growth rate, size and morphology of MgCO3 center dot 3H(2)O . The formation of MgCO3 center dot 3H(2)O might be explained by the dissolution-recrystallization mechanism. Larger bundle-like MgCO3 center dot 3H(2)O which composed of middle-binding rod crystals was obtained from the plate-like Mg(OH)(2). These findings could pave the way for controllable crystallization of MgCO3 center dot 3H(2)O in a CO2 mineralization system. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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