4.7 Article

Versatile deep-red Mg2TiO4:Mn4+ phosphor for photoluminescence, thermometry, and latent fingerprint visualization

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 801, 期 -, 页码 394-401

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.06.028

关键词

Multifunctional phosphor; Thermometry; Latent fingerprint visualization

资金

  1. Ministry of Science and Technology of the Republic of China, Taiwan
  2. MOST [107-2221-E-992-068]

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The deep-red multifunctional Mg2TiO4:Mn4+ phosphor was synthesized for photoluminescence (PL), thermometry, and latent fingerprint visualization applications. Phosphors synthesized using a solid-state reaction (SSR) were composed of a binary phase consisting of 67.4% Mg2TiO4 and 32.6% MgTiO3. In addition, a single-phase Mg2TiO4 phosphor was prepared using a citric-acid-assisted sol-gel process, which exhibited a 2.24-fold PL enhancement compared to the phosphor prepared by SSR. Thermometry analysis revealed a linear relationship between PL intensity (I) and temperature (T) within the range of 293-393 K: T= -142.81 + 432.4. The absolute and relative sensitivities were determined to be 7.0 x 10(-3) and 25.4 x 10(-3) K-1, respectively, at 393 K. Furthermore, the Mg2TiO4:Mn(4+)phosphor was shown to be capable of visualizing latent fingerprints and identified level 1 and 2 features well. We demonstrated that Mg2TIO4:Mn4+ is a multifunctional phosphor that is suitable for use in PL, thermometry, and latent fingerprint visualization applications. (C) 2019 Elsevier B.V. All rights reserved.

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