Geochemistry of arc-related mantle peridotites and gabbros from the Chaldoran ophiolite, NW Iran

The Neo-Tethys-related Chaldoran ophiolite peridotites in NW Iran are remnants of mantle lithosphere, exhumed tectonically during the Late Cretaceous. Harzburgite is the predominant peridotite type, associated with oceanic lower crust cumulate gabbros occasionally. The ophiolite rocks are unconformably overlain by Late Cretaceous-Paleocene sediments. New whole-rock geochemistry of the variably serpentinized harzburgites shows a depleted nature, exemplified by low Al2O3, CaO, TiO2, V and Y and high Ni, Cr and Mg and also low rare earth element (REE) contents. The harzburgites present LREE enrichment. Positive correlations between some LREEs and high field strength elements (HFSE) suggest enrichment of LREEs by melt re-fertilization processes. Cr-spinels have Cr number of [Cr# = Cr/(Cr + Al) = 0.53-0.67], showing medium to high degree of partial melting (F = similar to 17-20%). Both whole-rock and mineral chemistry data show a supra-subduction zone setting and progressive depletion along with increase in spinel Cr# (MOR to fore arc). The cumulate gabbros have high MgO and SiO2, low TiO2 and Ti/V < 10 and also low chondrite normalized Dy (<8.5). The gabbro samples show enriched LREEs and LILEs and depleted HREEs and HFSEs with respect to MORBs. Subduction initiation (SI) model in a fore-arc/proto-fore-arc environment is suggested for the upper mantle evolution of the Chaldoran ophiolite. The rocks have experienced depletion in a second melting process at the later stages of SI and compositions were probably modified by extraction of island arc tholeiitic (IAT) and possibly boninitic (BON) melts. The chemostratigraphic progression for 'subduction initiation rule (SIR)' is likely traceable in Chaldoran mafic-ultramafic sequence, which corresponds to the most Neo-Tethyan ophiolites and is similar to MOR to supra-subduction zone (SSZ) evolution of most Iranian 'Inner' and 'Outer Zagros' ophiolitic peridotites.