Article
Thermodynamics
Wenwen Kong, Boxiong Shen, Jiao Ma, Jia Kong, Shuo Feng, Zhuozhi Wang, Lifu Xiong
Summary: The pyrolysis characteristics of Spirulina platensis, Tetradesmus obliquus, and Chlorella vulgaris were investigated by various techniques. The elemental and biochemical composition of different microalgae influenced their pyrolysis behavior. The pyrolysis process of the three microalgae could be divided into several stages, and the major reaction occurred at a certain temperature range. Different products and activation energies were observed for each microalgae. The pyrolysis of Spirulina platensis produced more CO2 and compounds containing C=O bonds, while Tetradesmus obliquus and Chlorella vulgaris produced slightly higher levels of hydrocarbons.
Article
Chemistry, Multidisciplinary
Yan Yang, Shin Ying Foong, Peter Nai Yuh Yek, Abdallah A. A. Mohammed, Meenaksi Verma, Hui Suan Ng, Sang-Chul Jung, Yifeng He, Wanxi Peng, Su Shiung Lam
Summary: This study aims to convert and reuse shellfish waste (SW) by performing pyrolysis to transform it into value-added products. The findings indicate that SW is not suitable for direct use as fuel due to its low high calorific value, but can be transformed into valuable chemicals through pyrolysis. These findings are significant for advancing sustainable waste management strategies and utilizing waste materials in various industries.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2023)
Article
Thermodynamics
Yuan Jiang, Peijie Zong, Bin Tian, Xue Ming, Fanfan Xu, Yuanyu Tian, Yingyun Qiao, Dawei Li, Qingshuo Song, Qiankun Yu
Summary: Studying the pyrolysis behavior of the saturate component in coal, which mainly consists of volatile substances, through the combined utilization of TG-FTIR and Py-GC/MS revealed a free radical reaction mechanism. The research provides a methodological model for exploring other group components and reveals specific details about the pyrolysis of coal.
Article
Environmental Sciences
Weijie Xu, Jingyong Liu, Ziyi Ding, Jiawei Fu, Fatih Evrendilek, Wuming Xie, Yao He
Summary: This study characterized and verified the pyrolysis mechanisms and volatiles products of medical mask belts, mask faces, and infusion tubes. The results are important for the treatment of medical wastes.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Chemistry, Analytical
Jiangfei Duan, Shengxia Feng, Weilong He, Rui Li, Peng Zhang, Yu Zhang
Summary: The manuscript utilized TG-FTIR, Py-GC/MS, and kinetic models to study the pyrolysis characteristics of electrolytic manganese residue. The pyrolysis process was divided into five stages, each with different kinetic mechanisms and released gases, with NH3, CO2, and SO2 as the major gases. The intermediate product of CO was unstable and participated in reactions promoting the formation of CO2 and SO2.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2021)
Article
Materials Science, Paper & Wood
Langui Xu, Yujian Zhang, Ziyong Wang, Shurui Guo, Yongxing Hao, Yuguo Gao, Min Xin, Yi Ran, Shuxun Li, Rui Ji, Hongmei Li, Huixia Jiang, Qingyan He, Ruyi Huang
Summary: This study investigates the pyrolysis performances and reaction kinetics of pine needles using thermogravimetric analysis, Fourier transform infrared spectroscopy, and pyrolysis-gas chromatography/mass spectrometry. It was found that pine needles showed higher pyrolysis efficiency at lower heating rates, while increased heating rates promoted the reaction. The activation energies of hemicellulose, cellulose, and lignin were calculated to be 156, 165, and 172 kJ/mol, respectively, using the King-Kai method. The main pyrolytic by-products identified were hydrocarbons, phenols, alcohols, ketones, and aldehydes. This study demonstrates the significant potential of pine needles as a suitable source for bioenergy.
Article
Thermodynamics
Zhi Wang, Yuechi Che, Jian Li, Wenzhu Wu, Beibei Yan, Yingxiu Zhang, Xutong Wang, Fan Yu, Guanyi Chen, Xiaoyu Zuo, Xiujin Li
Summary: This study investigated the effects of anaerobic digestion pretreatment on the pyrolysis characteristics of Sargassum. The results showed that increasing the anaerobic digestion duration decreased the content of extract and cellulose, while increasing the content of lignin in Sargassum. The fiber crystallinity and specific surface area of Sargassum were increased due to changes in chemical composition. Anaerobic digestion also affected the gaseous and liquid products of pyrolysis, enhancing the thermal stability of Sargassum. The composition and structure of the biomass were altered, affecting the quality of the pyrolytic products.
ENERGY CONVERSION AND MANAGEMENT
(2022)
Article
Environmental Sciences
Lu Tian, Tingting Liu, Jinzhong Yang, Haoyue Yang, Zewei Liu, Youcai Zhao, Qifei Huang, Zechun Huang
Summary: The pyrolysis behaviors of waste solvent-based automotive paint sludge (OAPS) and water-based automotive paint sludge (WAPS) were quantified using TG-FTIR and Py-GC/MS analyses. The pyrolysis kinetics and reaction mechanisms were investigated using FWO, KAS, and master-plots method. The main pyrolysis reaction mechanisms of both OAPS and WAPS matched with 3rd and 2nd order random nucleation model. The evolved gas species and pyrolysis products were identified using TG-FTIR and Py-GC/MS techniques.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2023)
Article
Engineering, Environmental
Ziyi Ding, Huashan Chen, Jingyong Liu, Haiming Cai, Fatih Evrendilek, Musa Buyukada
Summary: This study characterized the pyrolysis process of medical plastic wastes through TG-FTIR and Py-GC/MS analyses, finding that medical bottles showed better pyrolysis performance with lower residue content.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Analytical
Fan Zhang, Yunan Sun, Jianyuan Li, Hong Su, Zongsheng Zhu, Beibei Yan, Zhanjun Cheng, Guanyi Chen
Summary: This study investigated the pyrolysis characteristics of 3D printed PLA waste (3DP-PLAW) using TG-FTIR/GC-MS and found two main pyrolysis stages, with the occurrence of the second stage attributed to changes in the physicochemical properties of PLA during 3D printing. It was also found that 3DP-PLAW had a higher heating value than raw PLA, highlighting its potential value for energy recovery.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2022)
Article
Engineering, Multidisciplinary
Jiaqing Zhang, Yi Guo, Qingtao Chen, Chao Luo
Summary: This paper investigates the pyrolysis mechanisms of Nomex insulation paper in nitrogen and air environments. The results show that the pyrolysis behaviors in air differ significantly from those in nitrogen, with higher mass loss rate and lower thermal stability. Organic substances in the solid residue are mostly oxidized in air, leading to the production of larger amounts of H2O, CO2, CO, and NOx.
Article
Chemistry, Analytical
Jiuling Yang, Haoliang Wang, Wei Huang, Xiaofeng Peng, Bo Yuan, Yuqi Hu
Summary: This study analyzes the pyrolysis characteristics and gas evolution behavior of forest duff under different heating rates and pyrolysis temperatures. The research reveals the decomposition temperature ranges of different components in forest duff and identifies the main functional groups and volatile products produced during pyrolysis. The study also emphasizes the importance of considering heating rate and pyrolysis temperature in the development of bioenergy and value-added chemicals from forest duff.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2023)
Article
Chemistry, Analytical
Peng Ling, Jun Xu, Tao Liu, Xiaoxue An, Xin Wang, Mohamed E. Mostafa, Hengda Han, Kai Xu, Long Jiang, Yi Wang, Sheng Su, Song Hu, Jun Xiang
Summary: This study investigated the pyrolysis kinetics and pyrolytic products distribution of coal slime and compared it with raw coal. The results showed that the pyrolysis of coal slime consists of three reaction stages, with the decomposition of volatiles as the main stage. The presence of inorganic minerals significantly influenced the pyrolysis reaction, and the alkene content of pyrolysis products decreased while the contents of CO2 and aromatics increased in coal slime compared to raw coal. These findings provide theoretical and practical guidance for the efficient thermochemical conversion and utilization of coal slime.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2022)
Article
Engineering, Environmental
Rui Cao, Ruishi Zhou, Yongqi Liu, Duo Ma, Jing Wang, Yulei Guan, Qiuxiang Yao, Ming Sun
Summary: The pyrolysis treatment of waste printed circuit boards (WPCBs) shows great potential for sustainable treatment and hazard reduction. The thermal weight loss, product distribution, and kinetics of WPCBs pyrolysis were studied. The results showed that fast pyrolysis reduces the final weight loss and produces phenols and aromatics, while multi-step pyrolysis generates benzene and diphenyl phenol.
Article
Chemistry, Analytical
Yansheng Huang, Daniel Takyi Sekyere, Jinhong Zhang, Yuanyu Tian
Summary: The fast pyrolysis behavior of mushroom bran (MB) and corn straw (CS) with high ash and high nitrogen content was studied using high heating rate TG-FTIR and PyGC/MS. The study found that at higher heating rates, there is an overlap of the decomposition of starch and hemicellulose, potentially promoting the formation of furan and furfural. Nitrogen tends to migrate from hydrogen cyanide to NH3 before 450 degrees C. Deoxidation and denitrification primarily occur between the pyrolysis temperature range of 300 degrees C to 350 degrees C. Staged pyrolysis interrupts the oil's continuous deoxidation process, and it reduces the selectivity of aldehydes and ketones in MB and CS pyrolysis. This study provides detailed pyrolysis characteristics for high nitrogen and ash content biomass.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2023)
Article
Chemistry, Applied
Fawei Lin, Xiao Jiang, Nuttakorn Boreriboon, Chunshan Song, Zhihua Wang, Kefa Cen
Summary: Binary supports such as TiO2-CeO2 and TiO2-ZrO2 significantly enhance CH3OH formation and selectivity, with Pd-Cu/Ti0.1Zr0.9O2 exhibiting the best catalytic performance. Lowering temperature further enhances CH3OH selectivity.
Article
Chemistry, Multidisciplinary
Paulo Torres, Merce Balcells, Ramon Canela-Garayoa
Summary: The Diels-Alder reaction generates products with different stereochemical configurations, which can often be predicted by the endo rule when the dienophile has a single electron-withdrawing substituent. The use of chiral eutectic solvents has become a novel tool in asymmetric synthesis to improve reaction yields and selectivity, maintaining sustainability in organic synthesis.
Article
Environmental Sciences
Hengdi Ye, Qian Li, Hongdi Yu, Li Xiang, Jinchao Wei, Fawei Lin
Summary: This paper comprehensively investigates the pyrolysis characteristics of iron-rich rolling sludge (FeRS) and explores the effects of pyrolytic temperature, atmosphere, heating rate, and stirring on the pyrolysis process. The study finds that pyrolysis effectively removes organics, but the yield of oil and gas is low. The solid residues can be used for water pollution control and soil remediation.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH
(2022)
Article
Chemistry, Multidisciplinary
Hairong Tang, Zhihua Wang, Jiaming Shao, Fawei Lin, Peixi Liu, Yong He, Yanqun Zhu
Summary: This study investigated the application of four manganese oxides with different crystal structures in an ozone synergistic-oxidation system. Among them, a cactus-like MnO2-IV nanosphere exhibited the highest ozone decomposition activity and showed good tolerance to water vapor and SO2/H2O. The interference mechanism of O-2/O-3/H2O/SO2 molecules on MnO2-IV was revealed.
Article
Chemistry, Physical
Diana Cosovanu, Alberto Millan Acosta, Pau Cabaneros Lopez, Krist Gernaey, Qian Li, Rene Lametsch, Ramon Canela-Garayoa, Jordi Eras, Gemma Villorbina
Summary: This study focused on the biotransformation of HMF into DHMF using low-cost protein hydrolysates obtained from meat industry waste residues. The hydrolysis of protein was optimized using two commercial proteases, leading to higher DHMF yield compared to using commercial peptones. The use of these hydrolysates as a nitrogen source improved sporulation of the fungus, resulting in a higher conversion yield.
Article
Engineering, Environmental
Li Xiang, Fawei Lin, Bohang Cai, Kaiwen Wang, Zhihua Wang, Beibei Yan, Guanyi Chen, Chi He
Summary: The study evaluated the poisoning effect of complex components in practical gas on DCM catalytic ozonation and found that Ca/Pb loading weakens catalytic performance, while the presence of As leads to excessive acidity and the formation of byproducts. The catalytic ozonation of DCM displays a distinctive advantage in metal antipoisoning.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Energy & Fuels
Fawei Lin, Fa Zheng, Jiantao Li, Bingyan Sun, Lei Che, Beibei Yan, Guanyi Chen
Summary: This study investigated the catalytic effects of steel slag and red mud in the pyrolysis of oily sludge. It was found that red mud had better catalytic performance and oil recovery effect. The study also discovered that metal oxides could enhance gas production, reduce oil production, and improve the quality of oil.
Article
Environmental Sciences
Peng Zhou, Dan Zeng, Xutong Wang, Lingyu Tai, Wenwu Zhou, Qiongda Zhuoma, Fawei Lin
Summary: This study investigated the pollution levels and risks of heavy metals in the soil around a landfill site in Lhasa, Tibet. The results showed that the concentrations of heavy metals were relatively low, but cadmium (Cd) and arsenic (As) were the most serious pollutants.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH
(2022)
Article
Chemistry, Physical
Peixi Liu, Lichun Chen, Hairong Tang, Jiaming Shao, Fawei Lin, Yong He, Yanqun Zhu, Zhihua Wang
Summary: Different transition metal catalysts supported on gamma-Al2O3 were prepared and investigated for catalytic ozonation of acetone under industrial complex conditions. Among them, the Cr1.5% catalyst achieved the best activity and showed good applicability in industrial application. It also exhibited satisfactory resistance to sulfur and water vapor.
Article
Environmental Sciences
Jiaming Shao, Yunchu Zhai, Luyang Zhang, Li Xiang, Fawei Lin
Summary: This study focused on the low-temperature catalytic oxidation and degradation of benzene and other volatile organic compounds (VOCs) by ozone. The effects of ozone on catalytic oxidation of VOCs and catalysts' activity were studied, with 0.75% Pt-10% Fe/HZSM(200) identified as the optimal catalyst for benzene degradation.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH
(2022)
Article
Engineering, Environmental
Jiantao Li, Fawei Lin, Hongdi Yu, Xin Tong, Zhanjun Cheng, Beibei Yan, Yingjin Song, Guanyi Chen, Li'an Hou, John C. Crittenden
Summary: This study investigates an integrated strategy of biochar-assisted catalytic pyrolysis (BCP) of oily sludge (OS) and residue utilization for soil reclamation, which can effectively remove recalcitrant petroleum hydrocarbons, stabilize heavy metals, and improve soil microbial communities, facilitating plant germination and secondary removal of petroleum hydrocarbons.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Engineering, Environmental
Fawei Lin, Hongdi Yu, Jiantao Li, Kyriacos Zygourakis, Rundong Li, Zhanjun Cheng, Beibei Yan, Guanyi Chen
Summary: This study investigates the pyrolysis of oily sludges (OSs) using different soils and crude oils. The results show that soils with high organic matter content weaken the catalytic effect of soil minerals on crude oil pyrolysis. The addition of minerals promotes cracking and cyclization reactions, but also promotes dehydrogenation. Almost complete removal of total petroleum hydrocarbons (TPHs) was achieved after pyrolysis, and the pyrolytic residues can effectively restore soil fertility.
ACS ES&T ENGINEERING
(2023)
Article
Chemistry, Physical
Li Xiang, Yongtao Li, Fawei Lin, Beibei Yan, Guanyi Chen
Summary: This study synthesized MnO2 catalysts with different crystal structures and found that 8-MnO2 catalyst exhibited excellent activity, good stability, and the potential for collaborative degradation of multiple pollutants during catalytic ozonation of CH2Cl2.
APPLIED SURFACE SCIENCE
(2023)
Article
Energy & Fuels
Hongdi Yu, Jiantao Li, Fawei Lin, Menglan Zeng, Rundong Li, Beibei Yan, Guanyi Chen
Summary: Pyrolysis of oily sludge is commonly used for its efficient removal and recovery of petroleum hydrocarbons. However, little research focuses on evaluating the solid products from this process. This study found that the fly ash and pyrolysis residue still contain trace amounts of petroleum hydrocarbons, and the combustion of the solid samples was more effective than pyrolysis. These findings suggest that the solid products have potential for combustion utilization.
Article
Chemistry, Multidisciplinary
Yaxin Duan, Peixi Liu, Fawei Lin, Yong He, Yanqun Zhu, Zhihua Wang
Summary: Five Mn-loaded catalysts were synthesized on different supports and their catalytic ozonation performance for DCM was evaluated under industrial conditions. The results showed that all catalysts achieved over 90% DCM conversion, with Mn/nanoAl2O3 exhibiting the best performance. Both H2O and SO2 affected the catalyst activity, with the inhibition caused by H2O being reversible.
Article
Energy & Fuels
Yingna Du, Chen Huang, Wei Jiang, Qiangwei Yan, Yongfei Li, Gang Chen
Summary: In this study, anionic surfactants modified hydrotalcite was used as a flow improver for crude oil under low-temperature conditions. The modified hydrotalcite showed a significant viscosity reduction effect on crude oil. The mechanism of the modified hydrotalcite on viscosity and pour point of crude oil was explored through characterization and analysis of the modified hydrotalcite and oil samples.
Article
Energy & Fuels
Mohammad Saeid Rostami, Mohammad Mehdi Khodaei
Summary: In this study, a hybrid structure, MIL-53(Al)@MWCNT, was synthesized by combining MIL-53(Al) particles and -COOH functionalized multi-walled carbon nanotube (MWCNT). The hybrid structure was then embedded in a polyethersulfone (PES) polymer matrix to prepare a mixed matrix membrane (MMM) for CO2/CH4 and CO2/N2 separation. The addition of MWCNTs prevented MIL-53(Al) aggregation, improved membrane mechanical properties, and enhanced gas separation efficiency.
Article
Energy & Fuels
Yunlong Li, Desheng Huang, Xiaomeng Dong, Daoyong Yang
Summary: This study develops theoretical and experimental techniques to determine the phase behavior and physical properties of DME/flue gas/water/heavy oil systems. Eight constant composition expansion (CCE) tests are conducted to obtain new experimental data. A thermodynamic model is used to accurately predict saturation pressure and swelling factors, as well as the phase boundaries of N2/heavy oil systems and DME/CO2/heavy oil systems, with high accuracy.
Article
Energy & Fuels
Morteza Afkhamipour, Ebad Seifi, Arash Esmaeili, Mohammad Shamsi, Tohid N. Borhani
Summary: Non-conventional amines are being researched worldwide to overcome the limitations of traditional amines like MEA and MDEA. Adequate process and thermodynamic models are crucial for understanding the applicability and performance of these amines in CO2 absorption, but studies on process modeling for these amines are limited. This study used rate-based modeling and Deshmukh-Mather method to model CO2 absorption by DETA solution in a packed column, validated the model with experimental data, and conducted a sensitivity analysis of mass transfer correlations. The study also compared the CO2 absorption efficiency of DETA solution with an ionic solvent [bmim]-[PF6] and highlighted the importance of finding optimum operational parameters for maximum absorption efficiency.
Article
Energy & Fuels
Arastoo Abdi, Mohamad Awarke, M. Reza Malayeri, Masoud Riazi
Summary: The utilization of smart water in EOR operations has gained attention, but more research is needed to understand the complex mechanisms involved. This study investigated the interfacial tension between smart water and crude oil, considering factors such as salt, pH, asphaltene type, and aged smart water. The results revealed that the hydration of ions in smart water plays a key role in its efficacy, with acidic and basic asphaltene acting as intrinsic surfactants. The pH also influenced the interfacial tension, and the aged smart water's interaction with crude oil depended on asphaltene type, salt, and salinity.
Article
Energy & Fuels
Dongao Zhu, Kun Zhu, Lixian Xu, Haiyan Huang, Jing He, Wenshuai Zhu, Huaming Li, Wei Jiang
Summary: In this study, cobalt-based metal-organic frameworks (Co-based MOFs) were used as supports and co-catalysts to confine the NHPI catalyst, solving the leaching issue. The NHPI@Co-MOF with carboxyl groups exhibited stronger acidity and facilitated the generation of active oxygen radicals O2•, resulting in enhanced catalytic activity. This research provides valuable insights into the selection of suitable organic linkers and broadens the research horizon of MOF hybrids in efficient oxidative desulfurization (ODS) applications.
Article
Energy & Fuels
Edwin G. Hoyos, Gloria Amo-Duodu, U. Gulsum Kiral, Laura Vargas-Estrada, Raquel Lebrero, Rail Munoz
Summary: This study investigated the impact of carbon-coated zero-valent nanoparticle concentration on photosynthetic biogas upgrading. The addition of nanoparticles significantly increased microalgae productivity and enhanced nitrogen and phosphorus assimilation. The presence of nanoparticles also improved the quality of biomethane produced.
Article
Energy & Fuels
Yao Xiao, Asma Leghari, Linfeng Liu, Fangchao Yu, Ming Gao, Lu Ding, Yu Yang, Xueli Chen, Xiaoyu Yan, Fuchen Wang
Summary: Iron is added as a flocculant in wastewater treatment and the hydrothermal carbonization (HTC) of sludge produces wastewater containing Fe. This study investigates the effect of aqueous phase (AP) recycling on hydrochar properties, iron evolution and environmental assessment during HTC of sludge. The results show that AP recycling process improves the dewatering performance of hydrochar and facilitates the recovery of Fe from the liquid phase.
Article
Energy & Fuels
He Liang, Tao Wang, Zhenmin Luo, Jianliang Yu, Weizhai Yi, Fangming Cheng, Jingyu Zhao, Xingqing Yan, Jun Deng, Jihao Shi
Summary: This study investigated the influence of inhibitors (carbon dioxide, nitrogen, and heptafluoropropane) on the lower flammability limit of hydrogen and determined the critical inhibitory concentration needed for complete suppression. The impact of inhibitors on explosive characteristics was evaluated, and the inhibitory mechanism was analyzed with chemical kinetics. The results showed that with the increase of inhibitor quantity, the lower flammability limit of hydrogen also increased. The research findings can contribute to the safe utilization of hydrogen energy.
Article
Energy & Fuels
Zonghui Liu, Zhongze Zhang, Yali Zhou, Ziling Wang, Mingyang Du, Zhe Wen, Bing Yan, Qingxiang Ma, Na Liu, Bing Xue
Summary: In this study, high-performance solid catalysts based on phosphotungstic acid (HPW) supported on Zr-SBA-15 were synthesized and evaluated for the one-pot conversion of furfural (FUR) to γ-valerolactone (GVL). The catalysts were characterized using various techniques, and the ratio of HPW and Zr was found to significantly affect the selectivity of GVL. The HPW/Zr-SBA-15 (2-4-15) catalyst exhibited the highest GVL yield (83%) under optimized reaction conditions, and it was determined that a balance between Bronsted acid sites (BAS) and Lewis acid sites (LAS) was crucial for achieving higher catalytic performance. The reaction parameters and catalyst stability were also investigated.
Article
Energy & Fuels
Michael Stoehr, Stephan Ruoff, Bastian Rauch, Wolfgang Meier, Patrick Le Clercq
Summary: As part of the global energy transition, an experimental study was conducted to understand the effects of different fuel properties on droplet vaporization for various conventional and alternative fuels. The study utilized a flow channel to measure the evolution of droplet diameters over time and distance. The results revealed the temperature-dependent effects of physical properties, such as boiling point, liquid density, and enthalpy of vaporization, and showed the complex interactions of preferential vaporization and temperature-dependent influences of physical properties for multi-component fuels.
Article
Energy & Fuels
Yuan Zhuang, Ruikang Wu, Xinyan Wang, Rui Zhai, Changyong Gao
Summary: Through experimental validation and optimization of the chemical kinetic model, it was found that methanol can accelerate the oxidation reaction of ammonia, and methanol can be rapidly oxidized at high concentration. HO2 was found to generate a significant amount of OH radicals, facilitating the oxidation of methanol and ammonia. Rating: 7.5/10.
Article
Energy & Fuels
Radwan M. EL-Zohairy, Ahmed S. Attia, A. S. Huzayyin, Ahmed I. EL-Seesy
Summary: This paper presents a lab-scale experimental study on the impact of diethyl ether (DEE) as an additive to waste cooking oil biodiesel with Jet A-1 on combustion and emission features of a swirl-stabilized premixed flame. The addition of DEE to biodiesel significantly affects the flame temperature distribution and emissions. The W20D20 blend of DEE, biodiesel, and Jet A-1 shows similar flame temperature distribution to Jet A-1 and significantly reduces UHC, CO, and NOx emissions compared to Jet A-1.
Article
Energy & Fuels
Jiang Bian, Ziyuan Zhao, Yang Liu, Ran Cheng, Xuerui Zang, Xuewen Cao
Summary: This study presents a novel method for ammonia separation using supersonic flow and develops a mathematical model to investigate the condensation phenomenon. The results demonstrate that the L-P nucleation model accurately characterizes the nucleation process of ammonia at low temperatures. Numerical simulations also show that increasing pressure and concentration can enhance ammonia condensation efficiency.
Article
Energy & Fuels
Shiyuan Pan, Xiaodan Shi, Beibei Dong, Jan Skvaril, Haoran Zhang, Yongtu Liang, Hailong Li
Summary: Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method for achieving negative emissions. This study develops a reliable data-driven model based on the Transformer architecture to predict the flowrate and CO2 concentration of flue gas in real time. The model validation shows high prediction accuracy, and the potential impact of meteorological parameters on model accuracy is assessed. The results demonstrate that the Transformer model outperforms other models and using near-infrared spectral data as input features improves the prediction accuracy.