期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2019, 期 38, 页码 6566-6570出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201900993
关键词
Boronates; Biaryls; Boronic acid; Cross-coupling; Orthogonality; Homogeneous catalysis
资金
- Natural Sciences and Engineering Research Council (NSERC) of Canada
One of the most useful chemical transformations of organoboronic acids is the Suzuki-Miyaura cross-coupling reaction. Although it has vast application, it possesses some limitations: boronic acids can be difficult to quantify accurately due to their tendency to form oligomeric anhydrides and they must be activated under basic conditions. To address these problems, a new class of boronic acid derivatives is described. Phenoxy-dialkoxy borates are prepared under mild conditions and show good solubility in common organic solvents. These adducts can be used in base-free metal-catalysed cross-coupling reactions, including orthogonal reactions with MIDA boronates and trifluoroborates.
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