Article
Environmental Sciences
Kubra Ulucan-Altuntas, Senem Yazici Guvenc, Emine Can-Guven, Fatih Ilhan, Gamze Varank
Summary: This study investigated the degradation of oxytetracycline by heat-activated peroxydisulfate and peroxymonosulfate processes. Response surface methodology was used to evaluate the effect of process parameters on oxytetracycline removal efficiency, showing significant results for both processes. The predicted oxytetracycline removal efficiencies for the PDS and PMS processes were 89.7% and 84.0%, respectively, with the PDS process having higher kinetic constants at all pH values than the PMS process.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Environmental Sciences
Rohith K. Ramakrishnan, Abhilash Venkateshaiah, Klaudiusz Grubel, Edyta Kudlek, Daniele Silvestri, Vinod V. T. Padil, Farshid Ghanbari, Miroslav Cernik, Stanislaw Waclawek
Summary: Sulfate radical-based advanced oxidation processes (SR-AOPs) are being recognized as an effective alternative for removing persistent pollutants in water. Persulfates, such as peroxydisulfate (PDS) and peroxymonosulfate (PMS), are commonly used sulfate radical donors. UV-activated PDS and PMS can efficiently degrade anthraquinone dye (AB129) and inhibit the formation of by-products. This research demonstrates the reduced ecotoxicity of treated water after degradation, confirming the environmental friendliness of sulfate radical-based processes.
ENVIRONMENTAL RESEARCH
(2023)
Article
Engineering, Environmental
Minjie Chen, Xiao Ling, Anhong Cai, Jing Deng, Shijun Zhu, Hanxuan Zeng, Xueyan Li
Summary: In this study, the dewaterability of waste activated sludge (WAS) was investigated using pyrite activated peroxydisulfate (PDS) conditioning, and the intrinsic mechanism was explored. The experimental results showed that the specific resistance to filtration (SRF) and sludge water content (Wc) decreased significantly with optimal pyrite and PDS dosages. Further analysis revealed that the reactive radicals generated through the reaction of pyrite/PDS destroyed the hydrophilic functional groups in the extracellular polymeric substances (EPS), leading to the release of bound water and the collapse of sludge floc structure. Additionally, the protein structure became looser, exposing the hydrophobic structures and contributing to improved sludge dewaterability.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Na Qiu, Chanchan Shen, Yongxia Liu, Xiuqing Li, Guangyin Jia, Jingping Qin, Xinglei Wang
Summary: This study investigated the degradation mechanism of ibuprofen in aqueous solutions and the factors influencing the degradation process, and proposed a possible degradation pathway. The results showed that ferric ion activated peroxydisulfate coupled with electro-oxidation could effectively remove ibuprofen from water bodies.
Article
Engineering, Environmental
Anna Wang, Zhechao Hua, Zihao Wu, Chunyan Chen, Shaodong Hou, Bangjie Huang, Yuge Wang, Ding Wang, Xuchun Li, Chuanhao Li, Jingyun Fang
Summary: This study examined the effects of bromide (Br-) at fresh water levels on radical chemistry in the UV/peroxydisulfate (UV/PDS) process. The presence of Br- promoted the conversion from sulfate radical (SO4-) to hydroxyl radical (HO-) and secondary reactive bromine species (RBS), significantly altering the radical chemistry of the process. Co-existing Cl- further enhanced the conversion from SO4- to HO- when combined with Br-.
Article
Engineering, Chemical
Wei-Jie Liu, Eilhann Kwon, Bui Xuan Thanh, Ta Cong Khiem, Duong Dinh Tuan, Jia-Yin Lin, Thomas Wi-Afedzi, Chechia Hu, Sanya Sirivithayapakorn, Kun-Yi Andrew Lin
Summary: With the increasing consumption of ionic liquids (ILs), the release of ILs into water environments poses risks to aquatic ecology. This study aims to develop a useful heterogeneous catalyst to activate peroxydisulfate (PDS) for degrading 1-Butyl-3-methylimidazolium chloride (BMIM). The FeNiC catalyst derived from a unique Hofmann-type MOF exhibits advantageous features and shows promising catalytic activity.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Energy & Fuels
Yan Wang, Chi Ma, Yangxian Liu
Summary: This paper investigates the use of rice straw biochar-activated peroxydisulfate oxidation technology to oxidize nitric oxide (NO) from flue gas. The main factors affecting NO removal, removal products, and free radicals are studied. Results show that the main product of NO oxidation removal is NO3- and .OH and SO4-. are identified as important free radicals for oxidizing NO. The maximum NO removal efficiency reaches 95.2% under optimized process parameters.
Article
Biotechnology & Applied Microbiology
Stanislaw Waclawek, Holger Lutze, Virender K. Sharma, Ruiyang Xiao, Dionysios Dionysiou
Summary: Many aspects of sulfate radical-advanced oxidation processes, particularly under alkaline medium, are widely debated. This review examines the possible mechanisms of activation of peroxydisulfate (PDS) and peroxymonosulfate (PMS) under alkaline conditions based on available literature. The formation of various products (SO52-, HO2-) is discussed, highlighting their complex interactions and potential roles in persulfate activation and radical scavenging. The activation of persulfates in alkaline conditions is highly pH-dependent due to the dissociation centers in both PMS and HO2-. There is a need for more detailed mechanistic studies to address inconsistencies in the current literature. Additionally, the relevance of sulfate radical-based oxidation of hydroxide ions and the importance of hydroxyl radicals differ in chloride-poor and chloride-rich environments.
CURRENT OPINION IN CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Yangjian Zhou, Yu Lei, Qingqing Kong, Xin Lei, Jianglin Peng, Yufeng Xie, Shuangshuang Cheng, Yanpeng Gao, Junlang Qiu, Xin Yang
Summary: This study reported a novel pathway for the generation of sulfate radical (SO4 center dot-) during the oxidation of neonicotinoids by peroxydisulfate (PDS) without any additional chemicals. Thiamethoxam (TMX) was found to activate PDS via TMX anion radical (TMX center dot-), leading to the generation of SO4 center dot-. This pathway was also applicable to other neonicotinoids.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Engineering, Chemical
Seydeh Sakineh Rezaei, Babak Kakavandi, Mohammad Noorisepehr, Ali Akbar Isari, Shirin Zabih, Parnia Bashardoust
Summary: The study synthesized TiO2 decorated ferroferric oxides coupled with activated carbon (TFOC) as a magnetic heterogeneous catalyst for degrading tetracycline (TC) using UV light and peroxydisulfate (PS) activation. The TFOC material showed enhanced photocatalytic activity towards TC degradation under UV light, demonstrating its potential for efficient treatment.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Environmental
Jin Zhu, Yinan Song, Liuwei Wang, Zhuorong Zhang, Jing Gao, Daniel C. W. Tsang, Yong Sik Ok, Deyi Hou
Summary: In this study, a biochar supported iron sulfide composite was synthesized and utilized as a persulfate activator for benzene removal from contaminated groundwater. The system showed excellent performance in benzene adsorption and degradation, with the optimal conditions of 1 g L-1 dosage of the composite and 3 mM PS concentration. The FexSy@biochar exhibited long-term effectiveness for PS activation and could be a sustainable alternative for contaminated groundwater remediation.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Lu Wang, Ke Jing, Baowei Hu, Junhe Lu
Summary: The formation of halogenated oxidation by-products in sulfate radical based advanced oxidation process has raised concerns. Addition of hydrogen peroxide can significantly suppress the generation of halogenated-OBPs, but the formation of organic bromines is still a concern.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Taozhen Li, Jingwen Pan, Xiaoning Wang, Zihao Fan, Tao Shi, Lei Wang, Baoyu Gao
Summary: In this study, Fe and Mo co-doped carbon catalysts were synthesized, and it was found that Mo doping can promote the cycling of Fe(II)/Fe(III) in the catalysts, accelerate the generation of SO4•- to enhance the degradation activity. In addition, the intermediates formed in the Fe/Mo@C-PDS system exhibited lower bio-toxicity.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Lili Liu, Haosheng Mi, Meng Zhang, Feifei Sun, Rui Zhan, Hanbin Zhao, Siqi He, Lei Zhou
Summary: CoFe2O4 magnetic nanoparticles were used as heterogeneous catalysts to activate PMS for efficient removal of MOX. The degradation of MOX followed a pseudo-first order kinetic reaction equation, with SO4•- playing a dominant role in the degradation process. Five probable degradation pathways of MOX were proposed based on identified intermediates, and the presence of certain ions had negative effects on MOX removal efficiency.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Environmental Sciences
Lijing Zhu, Mengya Li, Haiqiang Qi, Zhirong Sun
Summary: An iron-copper graphite felt electrode was prepared and used as the cathode in an electro-activated peroxydisulfate system to degrade Diuron. This system activated peroxydisulfate through electrochemical processes and transition metal catalysis, leading to the degradation of Diuron.
Article
Engineering, Chemical
S. Aitali, O. Kebiche-Senhadji, M. Benamor
MEMBRANE AND WATER TREATMENT
(2016)
Article
Engineering, Chemical
Aitali Salima, Kebiche-Senhadji Ounissa, Hammache Fadila, Benamor Mohamed
DESALINATION AND WATER TREATMENT
(2016)
Article
Engineering, Environmental
Karima Dibene, Idris Yahiaoui, Lamia Yahia Cherif, Salima Aitali, Abdeltif Amrane, Farida Aissani-Benissad
WATER SCIENCE AND TECHNOLOGY
(2020)
Proceedings Paper
Engineering, Multidisciplinary
Aitali Salima, Kebiche-Senhadji Ounissa, Mansouri Lynda, Benamor Mohamed
Proceedings Paper
Materials Science, Multidisciplinary
T. Belaid, S. Aitali, M. Benamor, K. Belhamel
THIN FILMS AND POROUS MATERIALS
(2009)