期刊
CHINESE CHEMICAL LETTERS
卷 30, 期 12, 页码 2231-2235出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2019.08.055
关键词
Fered-fenton like; Heterogeneous iron cycle; Iron-oxalate complexes; Surface electron transfer; Persulfate
资金
- National Natural Science Foundation of China [21677055, 21407052]
- Fundamental Research Funds for the Central Universities, HUST [2017KFXKJC004, 2016YXMS287]
In this study, efficient sulfamethoxazole (SMX) degradation was demonstrated in a novel neutral Fered-Fenton like/oxalate (electro-Fe2+/PDS/Ox, Fered-FL/Ox) system adopting pre-anodized Ti@TiO2 cathode. Optimization of operational parameters was conducted and the whole reaction mechanism based on the critical solid-liquid interfacial reactions was explored. An efficient neutral heterogeneous-homogenous iron cycle would exist in the Fered-FL/Ox system, depending on the formation of specific C-O-Ti bonds through the inner sphere surface complex (ISSC) of Fe(C2O4)(3)(3-). It would induce ultra fast electron transfer from the cathode to the Fe-III core, effectively accelerating the neutral Fenton-like reactions and complete mineralization of SMX with relative low dosage of ferrous catalyst and applied voltage. The result of this study is expected to supply a good alternative in treating complex neutral industrial wastewaters. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
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