Article
Chemistry, Physical
Jing Shi, Yunxia Zhao, Jiayi He, Tangyuan Li, Fangyuan Zhu, Wenchao Tian, Xiao Liu
Summary: This study developed high-temperature dielectric materials based on Bi0.5Na0.5TiO3 (BNT) near the morphotropic phase boundary, which exhibit excellent energy storage performance. The random distribution of polar nanoregions induced by composition modulation disrupts the long-range dipolar alignment and weakens the coupling between ferroelectric domains, resulting in slender and deferred polarization-electric field hysteresis loops with relatively high saturation polarization. The relaxors in this study demonstrate reversible nano-domain orientation and growth, leading to negligible remnant polarization and superior energy storage properties, outperforming state-of-the-art dielectric energy storage materials under similar conditions.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Materials Science, Ceramics
Han Wang, Qiang Li, Yuxin Jia, Arun Kumar Yadav, Benben Yan, Mengyuan Li, Qifeng Quan, Weijia Wang, Huiqing Fan
Summary: Lead-free (Bi0.5Na0.5)0.94Ba0.06Ti1-x(Y0.5Nb0.5)xO3 perovskite ceramics doped with (Y0.5Nb0.5)4+ ions showed a shift in transition temperature towards ambient temperature with increased composition, making the transformation of ferroelectric-to-relaxor phase easier under applied electric field at room temperature. Additionally, the ceramic composition x = 0.01 exhibited a large unipolar strain and excellent fatigue resistance under specific field conditions, indicating potential applications in electronic devices like actuators and sensors.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Multidisciplinary
Yafeng Xu, Jialong Duan, Jian Du, Xiya Yang, Yanyan Duan, Qunwei Tang
Summary: This study successfully fabricated a flexible CsPbBr3 PSC with an efficiency of 5.71% using a heat-resistant conductive muscovite substrate, achieving high mechanical flexibility and providing a new path for increasing efficiency in the future without lowering the crystallization temperature of state-of-the-art materials.
Article
Materials Science, Multidisciplinary
Li-Min Wang, Qing-Xiang Liu, Di Zhou
Summary: A series of (1-x)BaTiO3-xBi(Li1/3Hf2/3)O-3 ceramics were prepared and characterized, with the 0.88BaTiO3-0.12Bi(Li1/3Hf2/3)O-3 composition showing the highest energy densities and efficiency.
Article
Nanoscience & Nanotechnology
Ajinkya A. Deshmukh, Chao Wu, Omer Yassin, Lihua Chen, Stuti Shukla, Jierui Zhou, Ashish R. Khomane, Rishi Gurnani, Ting Lei, Xidong Liang, Rampi Ramprasad, Yang Cao, Gregory Sotzing
Summary: Exploration of novel polymer dielectrics with high electric-field stability, high energy density, and high efficiency at elevated temperatures is crucial for energy-storage technologies. In this study, the effect of fluorine groups on the energy-storage properties of polyoxanorbornene imide polymers was investigated. The results showed that fluorination improved the breakdown strength and discharged energy density of the polymers. However, it also increased the conduction loss despite the larger band gap. The understanding of the impact of fluorination on the polymer energy-storage properties contributes to the design of scalable and efficient polymer dielectrics.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Engineering, Environmental
Xuqing Zhang, Yongping Pu, Yating Ning, Bo Wang, Lei Zhang, Xian Zhang, Yangchao Shang, Zhemin Chen
Summary: This study demonstrates the possibility of achieving high energy storage density and efficiency in dielectric materials through appropriate preparation methods, and improving their breakdown strength and insulation performance. The introduction of Sm3+ and control of oxygen vacancy production effectively enhance the performance and stability of the material.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Nanoscience & Nanotechnology
Yufeng Min, Junyi Yu, Pengpeng Xu, Peng Li, Suibin Luo, Baojin Chu, Shuhui Yu
Summary: This study reports a surface engineering strategy to give metallized polyimide films self-healing capabilities. The polyimide films impregnated with epoxy resin not only show enhanced dielectric characteristics but also maintain excellent performance after multiple electrical breakdown cycles at high temperature.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Ceramics
Shihui Yu, Chunmei Zhang, Muying Wu, Helei Dong, Zheng Sun, Lingxia Li
Summary: The lead-free BMN1.5-BMN2 thin film, deposited by RF magnetron sputtering, exhibits very low loss tangent and high dielectric constant. It also shows superior energy storage properties with slim P-E loops, large maximum polarization, high charge storage density, high energy storage density, and energy conversion efficiency. Moreover, it provides new ideas for the design of lead-free linear dielectrics with ultrahigh energy storage density, making it a promising candidate for electrostatic energy storage capacitors.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Multidisciplinary
Shiwei Wang, Yixuan Wang, Qi Wei, Junling Wang
Summary: Organic-inorganic hybrid perovskites have received much attention for their opto-electronic applications. The study shows that external illumination can lead to larger size perovskite single crystals and improved film quality. The light-enhanced growth phenomenon can be explained by the photo-inhibition nucleation mechanism.
Article
Chemistry, Physical
M. Rkhis, S. Laasri, S. Touhtouh, E. K. Hlil, M. Bououdina, R. Ahuja, K. Zaidat, S. Obbade, A. Hajjaji
Summary: In this study, the bonding length, electronic structure, stability, and dehydrogenation properties of the Perovskite-type ZrNiH3 hydride under different uniaxial/biaxial strains were investigated through ab-initio calculations. The results show that compressive and tensile strains cause structural deformation of the ZrNiH3 crystal structure, and the magnitude of deformation becomes more significant with decreasing or increasing strain. The strain not only reduces the stability of ZrNiH3 but also decreases the dehydrogenation enthalpy and decomposition temperature. The densities of states analysis suggests that the strain-induced variation in the properties of ZrNiH3 is related to the Fermi level value of total densities of states.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Nanoscience & Nanotechnology
Zhaozhen Wang, Zunpeng Feng, Hongsong Tang, Junhao Wang, Ziming Cai, Ke Bi, Yanan Hao
Summary: This study theoretically analyzes the effects of orientation angles and aspect ratios of nanofiber fillers on the breakdown behavior and dielectric properties of composites. The results show that a higher inclination of the nanofiber fillers leads to a higher nominal breakdown strength, due to obstruction of conductive channels. However, the dielectric constant shows an opposite trend. Additionally, a higher aspect ratio of the nanofiber fillers helps achieve a higher breakdown strength with a slight sacrifice of the dielectric constant.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Qi-Kun Feng, Yong-Xin Zhang, Di -Fan Liu, Yan-Hui Song, Lei Huang, Zhi-Min Dang
Summary: This study proposes an all-organic sandwich-structured film as an energy storage dielectric material for film capacitors, using poly(vinylidene fluoride-hexafluoropropylene) and poly(ethylene tere-phthalate) as the materials and conducting comprehensive performance tests. The results show that the sandwich-structured film has excellent interlaminar interfaces, improved thermal stability and dielectric properties, but some degradation in loss factor and breakdown strength. With the increase of temperature, the film still maintains stable performance and exhibits high energy density and charge-discharge efficiency.
MATERIALS TODAY ENERGY
(2022)
Review
Energy & Fuels
Sachit K. Das, Debasrita Bharatiya, Biswajit Parhi, Sarat K. Swain
Summary: This article reviews the importance of transition metal oxide (TMO) nanocomposites in dielectric and energy storage applications, and discusses the peer analysis of different synthesis techniques and factors affecting their dielectric properties. The review provides a comprehensive understanding of the multi-dimensional aspects of TMO nanocomposites and their promising performance in various applications.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Physical
Zhihui Yi, Zhuo Wang, Yanxin Li, Dan Wu, Ying Xue, Jinteng Kang, Ting Zhao, Ronghui Ye
Summary: The development of portable electronic equipment, hybrid electric vehicles, and pulse power systems requires new dielectric materials with higher performance, making flexible polymer dielectrics desirable. In this study, Barium strontium titanate nanoparticles were successfully prepared using oxalate, and PVDF/BaxSr1-xTiO3 nanoparticles nanocomposites were synthesized. The micro-structure and electrical properties of the nanocomposites were analyzed to understand the effects of composition and intrinsic properties on their performance. Among all the groups, the 1 vol% PVDF/Ba0.6Sr0.4TiO3@DA NPs exhibited the highest discharge energy density and an excellent discharge energy efficiency of 65% at 300 kV/mm. This research provides experimental guidance and theoretical foundation for the development and application of high energy storage density dielectric materials in energy storage capacitors.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Zhaoting Zhang, Hong Yan, Zhen Huang, Xiao Chi, Changjian Li, Zhi Shiuh Lim, Shengwei Zeng, Kun Han, Ganesh Ji Omar, Kexin Jin, Ariando Ariando
Summary: The magnetic properties of epitaxial double-perovskite Sr2FeReO6 films can be tuned by adjusting the deposition pressure of oxygen and lattice mismatch. Epitaxial strain modulates B-site ordering by affecting elemental valence, leading to changes in magnetic behavior.
Article
Materials Science, Ceramics
Chao Wang, Qiang Li, Weiming Zhang, Benben Yan, Arun Kumar Yadav, Haijun Peng, Huiqing Fan
CERAMICS INTERNATIONAL
(2020)
Article
Chemistry, Analytical
Jiangwei Ma, Huiqing Fan, Weiming Zhang, Jianan Sui, Chao Wang, Mingchang Zhang, Nan Zhao, Arun Kumar Yadav, Weijia Wang, Wenqiang Dong, Shuren Wang
SENSORS AND ACTUATORS B-CHEMICAL
(2020)
Article
Nanoscience & Nanotechnology
Mingchang Zhang, Huiqing Fan, Yong Gao, Nan Zhao, Chao Wang, Jiangwei Ma, Longtao Ma, Arun Kumar Yadav, Weijia Wang, Wee Siang Vincent Lee, Ting Xiong, Junmin Xue, Zhenhai Xia
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Materials Science, Ceramics
Mengyuan Li, Qiang Li, Benben Yan, Arun Kumar Yadav, Hao Wang, Guangzhi Dong, Huiqing Fan
Summary: A series of novel lead-free ceramics (BNST-100xMN) were designed and fabricated, and their properties were systematically investigated. The substitution by MN dopant resulted in a more homogeneous microstructure, leading to improved breakdown strength and energy storage density.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Han Wang, Qiang Li, Yuxin Jia, Arun Kumar Yadav, Benben Yan, Mengyuan Li, Qifeng Quan, Weijia Wang, Huiqing Fan
Summary: Lead-free (Bi0.5Na0.5)0.94Ba0.06Ti1-x(Y0.5Nb0.5)xO3 perovskite ceramics doped with (Y0.5Nb0.5)4+ ions showed a shift in transition temperature towards ambient temperature with increased composition, making the transformation of ferroelectric-to-relaxor phase easier under applied electric field at room temperature. Additionally, the ceramic composition x = 0.01 exhibited a large unipolar strain and excellent fatigue resistance under specific field conditions, indicating potential applications in electronic devices like actuators and sensors.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Yuxin Jia, Huiqing Fan, Han Wang, Arun Kumar Yadav, Benben Yan, Mengyuan Li, Qifeng Quan, Guangzhi Dong, Weijia Wang, Qiang Li
Summary: Lead-free (1-x)[0.94(Bi0.5Na0.5)TiO3-0.06BaTiO(3)]-xBa(Sn0.70Nb0.24)O-3 (abbreviated as BNTBT-100xBSN) ceramics with a relative density greater than 96% exhibit a pseudo-cubic perovskite structure and dense surface morphology. Doping BSN effectively reduces dielectric loss and improves relaxation properties. The replacement of randomly distributed ferroelectric phase with polar nano regions enhances the electro-strain and energy storage performance of the system.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Han Wang, Qiang Li, Arun Kumar Yadav, Yuxin Jia, Benben Yan, Qifeng Quan, Qi Shen, Lin Lei, Weijia Wang, Huiqing Fan
Summary: The introduction of AgNbO3 dopants into BNBT-100xAN ceramics significantly improved their dielectric and piezoelectric properties, allowing them to perform well under high voltage and temperature conditions. XRD patterns and Raman spectra showed successful diffusion of AN modifiers into the lattice with a pseudo-cubic symmetry structure. These results demonstrate the potential of BNBT-100xAN ceramics for strain sensors and high-temperature capacitors.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Analytical
Jiangwei Ma, Huiqing Fan, Zhexin Li, Yuxin Jia, Arun Kumar Yadav, Guangzhi Dong, Weijia Wang, Wenqiang Dong, Shuren Wang
Summary: This study explores a novel flexible gas sensor, using ethylenediamine-treated polyethylene terephthalate fibers substrate and amino group-exposed multi-walled carbon nanotubes to achieve better sensing performance for ammonia gas, providing new development potential for the field of flexible gas sensors.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Materials Science, Ceramics
Fan Yang, Han Wang, Qiang Li, Arun Kumar Yadav, Huiqing Fan
Summary: Relaxor ferroelectrics, such as BNST-100xBS ceramics, show promising energy storage properties. The addition of BaSnO3 dopants influences the energy storage and dielectric temperature-stable properties of the ceramics. BNST-2.5BS ceramic demonstrates excellent recoverable energy density, while BNST-7.5BS shows outstanding temperature-stable dielectric permittivity, making them suitable for energy storage equipment and other device applications.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Han Wang, Qiang Li, Yuxin Jia, Arun Kumar Yadav, Benben Yan, Qi Shen, Mengyuan Li, Qifeng Quan, Huiqing Fan
Summary: The lead-free relaxor ceramics BNTBT-100xYN were designed and prepared using traditional solid-state sintering technique. The introduction of complex ions improved the temperature stability and recoverable energy density of the ceramics. The addition of composition reduced activation energy and generated oxygen vacancies, showing ergodic relaxor behavior.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Engineering, Electrical & Electronic
Arun Kumar Yadav, Huiqing Fan, Benben Yan, Weijia Wang, Wenqiang Dong, Shuren Wang
Summary: Polycrystalline Ba(1-x)(La0.50Li0.50)(x)TiO3 ceramics were fabricated using solid-state reaction technique, to increase dielectric permittivity and potentially apply in capacitor applications.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Physical
Lin Lei, Weijia Wang, Yanyan Shang, Jin Li, Arun Kumar Yadav, Han Wang, Qiang Li, Huiqing Fan
Summary: This study proposes a novel strategy to obtain highly efficient g-C3N4 by tailoring molecular structures and intermolecular interactions of intermediates. The protonated melem derived g-C3N4 fabricated in this study exhibits favorable crystalline order and porous structure with a large specific surface area, showing promising photocatalytic activity for hydrogen production under visible light.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Han Wang, Qiang Li, Yuxin Jia, Arun Kumar Yadav, Benben Yan, Mengyuan Li, Qi Shen, Qifeng Quan, Weijia Wang, Guangzhi Dong, Huiqing Fan
Summary: This study synthesized lead-free perovskite ceramics using a traditional solid reaction and investigated the effects of Li+ ion doping on the relaxation mechanism and piezoelectric performance. The ceramics showed excellent electro-strain and energy storage properties, making them suitable for electronic equipment applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Ceramics
Shiqi Zheng, Qiang Li, Shuwen Zhu, Arun Kumar Yadav, Jinwei Miao, Weijia Wang, Huiqing Fan
Summary: Three-dimensional flower-shaped tin dioxide nanosheets (SnO2 NSs) were successfully prepared using tin dichloride dihydrate as raw material through magnetic stirring, hydrothermal reaction, and ice bath rapid cooling. Compared with tin oxide nanoparticles (SnO2 NPs) prepared by natural cooling, SnO2 NSs exhibit stronger gas sensitive response value and selectivity, as well as large potential as gas sensor material.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Lin Lei, Weijia Wang, Zhengfeng Xie, Xiaobo Wu, Arun Kumar Yadav, Peter Muller-Buschbaum, Huiqing Fan
Summary: Controlling molecular defects through element doping is an effective strategy for tailoring electronic structures and charge separation in photocatalysts. In this study, carbon self-doped graphitic carbon nitride was successfully synthesized, which showed extended light harvesting, tunable optical bandgap, and enhanced charge separation for high photocatalytic hydrogen evolution. This green and economical method provides a promising approach for efficient energy conversion applications.
SUSTAINABLE ENERGY & FUELS
(2021)