期刊
CERAMICS INTERNATIONAL
卷 46, 期 1, 页码 46-55出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.08.229
关键词
Magnetic oxdes; Nano-crystals; Ferromagnetism; Raman spectra; Dielectric properties; Spin phonon coupling
资金
- UPEA-II
- University Grants Commission, India
3d based double perovskite materials have received much attention in recent years due to their exotic magnetic structure and magneto-electric coupling. In this work we have prepared and studied the nano-crystalline sample of Ho2CoMnO6. Structural, magnetic, Raman and dielectric properties have been studied in detail. The structural analysis shows that the sample crystallize in monoclanic crystal structure with P2(1)/n phase group. The X-ray photoelectron spectroscopy have been employed to confirms the charge state of cations presents in the material. Magnetic study shows that the sample undergoes a paramagnetic to ferromagnetic phase transition around T-c similar to 85 K. The isothermal magnetization measurements shows hysteresis curve hence confirm ferromagnetic behavior at low temperature. Temperature dependent Raman study reveals that there is spin phonon coupling in the sample marked by deviation in phonon mode from anharmonic behavior. Dielectric response of Ho2CoMnO6 shows the large dispersion and large dielectric constant. Impedance spectroscopy and electrical modulus study reveal that system shows deviation from ideal Debye model. AC conductivity have been studied as a function of both temperature and frequency. We found that the conduction mechanism is obeyed by Jonscher's model. The exponent factor n is suggest that the material deviates from ideal Debye model.
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