4.7 Article

Mulberry-paper-based composites for flexible electronics and energy storage devices

期刊

CELLULOSE
卷 26, 期 16, 页码 8867-8875

出版社

SPRINGER
DOI: 10.1007/s10570-019-02686-5

关键词

Mulberry paper; Holocellulose; Composite; Flexible; Silver; Nanowire

资金

  1. National Research Foundation of Korea (NRF) - Korea government (MSIT) [2018R1C1B5043900]
  2. National Research Foundation of Korea [2018R1C1B5043900] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

向作者/读者索取更多资源

Mulberry paper comprising holocellulose shows excellent mechanical and chemical stability suitable for paper-based electronics. However, most studies pertaining to paper-based electronics have used conventional paper. Therefore, in this study, we demonstrated Ag nanoparticle (AgNP)/Ag nanowire (AgNW) flexible composites on mulberry-paper substrates. The AgNP/AgNW composites were fabricated by the dry transfer method, where the AgNP/AgNW layers were transferred from a polymer substrate with a hydrophobic surface to the toner-printed mulberry paper via hot pressing. Microstructural analysis showed that the mulberry papers contained thicker fibres than those in conventional papers, which limited the uniform transfer of the AgNP/AgNW layers on the mulberry papers. Therefore, we optimised the hot pressing conditions to 30 MPa and 80 degrees C, which allowed for the successful formation of the AgNP/AgNW composites on mulberry papers. Cyclic bending test results over 10,000 cycles revealed that the mulberry-paper-based composites showed better mechanical reliability with 30-40% smaller increases in resistance compared to those in conventional A4-paper-based composites. Lastly, a flexible supercapacitor fabricated using the mulberry-paper-based composite as the current collector showed excellent reliability without significant capacitance degradation over 100 bending cycles. Graphic abstract

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