4.7 Article

Fabrication and characterization of an actively protective Mg-Al LDHs/Al2O3 composite coating on magnesium alloy AZ31

期刊

APPLIED SURFACE SCIENCE
卷 487, 期 -, 页码 558-568

出版社

ELSEVIER
DOI: 10.1016/j.apsusc.2019.05.115

关键词

Magnesium alloy; LDHs coating; Electrophoretic deposition; Wear resistance; Corrosion resistance

资金

  1. National Natural Science Foundation of China [51701029, 51531002, 51474043]
  2. National Key Research and Development Program of China [2016YFB0301100]
  3. China Postdoctoral Science Foundation [2017M620410, 2018T110942]
  4. Chongqing Postdoctoral Science Special Foundation [Xm2017010]
  5. Chongqing Research Program of Basic Research and Frontier Technology [cstc2016jcyjA0388, cstc2017jcyjBX0040]
  6. Fundamental Research Funds for the Central Universities [2018CDGFCL005]

向作者/读者索取更多资源

A magnesium-aluminum layered-double-hydroxides (Mg-Al LDHs) coating was fabricated on the surface of Mg alloy AZ31, followed by electrophoretic deposition of an Al2O3 nanoparticles layer. The morphology, structure and composition of the composite coatings were investigated by field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and energy dispersive spectrometry (EDS). Ball on disc tests were carried out for measurements of the friction coefficient, wear loss and morphology of worn surfaces. Corrosion behavior of the coatings was investigated using potentiodynamic polarization curves and electrochemical impedance spectroscopy. Results indicate that the LDHs/Al2O3 composite coatings fabricated with 2.5 g/L Al2O3 nanoparticles solution exhibited best wear resistance, while best corrosion resistance was associated with the composite coating fabricated with 0.5 g/L Al2O3 nanoparticle solution. A sound mechanism for improving wear-resistance of the resulting coatings was proposed.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Engineering, Manufacturing

A Novel Approach of Customized Pelvic Implant Design Based on Symmetrical Analysis and 3D Printing

Yuan Chai, Xiao-Bo Chen, Jesse A. Estoque, Nick Birbilis, Qinghua Qin, Tomas Ward, Paul N. Smith, Rachel W. Li

Summary: This study analyzed the anatomical asymmetry of pelvic models and found that symmetrical analysis and deviation color maps can assist with implant selection and customized design, improving the accuracy and overall standard of 3D printed implants.

3D PRINTING AND ADDITIVE MANUFACTURING (2023)

Article Materials Science, Multidisciplinary

Effects of Laser Surface Remelting on Microstructure and Corrosion Properties of Mg-12Dy-1.1Ni Alloy

Guangli Bi, Siqi Chen, Jing Jiang, Yuandong Li, Tijun Chen, Xiao-Bo Chen, Duyao Zhang, Dong Qiu, Mark Easton

Summary: The effects of laser surface remelting (LSR) on microstructure and corrosion properties of as-cast Mg-12Dy-1.1Ni alloy were investigated. LSR treatment resulted in grain refinement and the formation of a continuous network of 18R-LPSO phase on dendrite boundaries, leading to improved corrosion resistance of the alloy.

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE (2023)

Article Metallurgy & Metallurgical Engineering

Development of Slippery Liquid-Infused Porous Surface on AZ31 Mg Alloys for Corrosion Protection

Wenhui Yao, Yonghua Chen, Yanning Chen, Liang Wu, Bin Jiang, Fusheng Pan

Summary: This study utilizes the slippery liquid-infused porous surface (SLIPS) technique to form a protective coating on AZ31 magnesium alloys. The results show that 120°C is the optimal condition for SLIPS to provide corrosion protection.

ACTA METALLURGICA SINICA-ENGLISH LETTERS (2023)

Article Metallurgy & Metallurgical Engineering

EFFECT OF MINOR Ag and Ce ADDITIONS ON HOT TEARING SUSCEPTIBILITY OF Mg-10Gd-3Y-0.5Zr ALLOY

Jinge Liao, Jiangfeng Song, Gong Chen, Hua Zhao, Shengkun Tong, Jun Zhou, Bin Jiang, Junyao Xu, Fusheng Pan

Summary: Mg-10Gd-3Y-0.5Zr alloy castings show great potential for aerospace applications due to their excellent tensile and creep properties. The hot tearing behavior of these alloys, which is an important characteristic for engineering applications, is investigated in this study through the addition of minor amounts of Ag and Ce. The results show that the addition of Ag and Ce worsens the hot tearing resistance of the alloy, with Ag increasing the susceptible freezing range and coefficient of thermal expansion, and Ce increasing grain size and coefficient of thermal expansion.

INTERNATIONAL JOURNAL OF METALCASTING (2023)

Article Nanoscience & Nanotechnology

The enhanced Zn and Ca co-segregation and mechanical properties of Mg-Zn-Ce alloy with micro Ca addition

Xiaoying Qian, Yuyang Gao, Zhihua Dong, Bin Jiang, Chao He, Cuihong Wang, Ang Zhang, Baoqing Yang, Changyong Zheng, Fusheng Pan

Summary: The micro addition of Ca effectively increases the strength and ductility of Mg-Zn-Ce alloy by enhancing alloying segregation at grain boundary. The addition of Ca leads to enhanced Zn segregation and co-segregation of Zn, Ce, and Ca. This is attributed to the decreased segregation energy and promoted diffusion process of Zn by Ca, which accelerates the thermodynamic and kinetic process of segregation. The controllable segregation at grain boundary, induced by Ca, contributes to the development of advanced magnesium alloys by stabilizing grain boundary, refining grain size, inhibiting dislocation mobility, improving strength, and enhancing grain boundary cohesion and ductility.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2023)

Article Nanoscience & Nanotechnology

Achieving preeminent strength-ductility synergy of Mg-1Sb-1Mn alloy via trace co-addition of Sn and Zn

Lintao Liu, Shengwen Bai, Bin Jiang, Chao He, Qinghang Wang, Jianxin Zhou, Liping Wei, Xiaoying Qian, Zhihua Dong, Guangsheng Huang, Dingfei Zhang, Fusheng Pan

Summary: In this study, a novel alloy designing concept is proposed to prepare a Mg alloy with excellent strength-ductility synergy by refining grain size and depressing intergranular deformation simultaneously. Through extrusion at 220 degrees C, an ultrafine microstructure is achieved in the basic alloy, Mg-1Sb-1Mn (SM11). The co-addition of Sn and Zn is then conducted to inhibit intergranular deformation and improve the mechanical properties of the alloy. The results show that the strength of the extruded Mg-1Sb-1Mn-1Sn-0.2Zn (SMTZ1110) alloy is significantly improved while maintaining a high ductility, suggesting a promising approach for the development of Mg alloys with a balanced strength-ductility combination.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2023)

Article Metallurgy & Metallurgical Engineering

Improved Corrosion Resistance of Ultrafine-Grained Mg-Gd-Zr Alloy Fabricated by Surface Friction Treatment

Chunquan Liu, Xianhua Chen, Yulong Wu, Yaobo Hu, Wei Zhang, Yusheng Zhang, Jingying Bai, Fusheng Pan

Summary: A gradient ultrafine-grained (UFG) Mg-2Gd-0.4Zr alloy sheet with a UFG layer of about 118 nm on the surface was fabricated using sliding friction treatment (SFT). The SFT-processed UFG surface layer exhibited significantly improved corrosion resistance compared to the original coarse-grained (CG) structure, showing higher impedance and lower corrosion rate.

ACTA METALLURGICA SINICA-ENGLISH LETTERS (2023)

Article Chemistry, Analytical

Universal N2O Reaction Gas To Remove Spectral Interferences of Nonmetallic Impurity Elements by Inductively Coupled Plasma Tandem Mass Spectrometry Analysis of High-Purity Magnesium Alloys

Liang Fu, Guangsheng Huang, Yaobo Hu, Xianhua Chen, Jingfeng Wang, Fusheng Pan

Summary: A new strategy using N2O as a reaction gas for the simultaneous determination of nonmetallic impurity elements in high-purity magnesium alloys by ICP-MS/MS was proposed. Through O-atom and N-atom transfer reactions, spectral interferences were eliminated and higher sensitivity and lower LODs were achieved compared to other reaction modes. The accuracy of the method was evaluated and it showed consistent results with SF-ICP-MS. This study provides a systematic method for precise quantification of impurity elements and can be applied to other fields.

ANALYTICAL CHEMISTRY (2023)

Article Thermodynamics

Interdiffusion and atomic mobility of the Mg-Sn-Zn system

Li Yang, Yuan Yuan, Qin Li, Jiajia Wu, Tao Chen, Jun Wang, Xiaojing Zuo, Aitao Tang, Lijun Zhang, Nele Moelans, Fusheng Pan

Summary: In this study, diffusion couples of Mg-Sn-Zn/hcp-Mg, Mg-Zn/Mg-Sn, and Mg-X (X = Sn or Zn)/hcp-Mg were assembled to determine the interdiffusion coefficients of Mg-X (X = Sn or Zn) binary systems and Mg-Sn-Zn ternary system. The kinetic description of the hcp-Mg phase in the Mg-Sn-Zn system was constructed. The features of interdiffusion coefficients of different elements were discussed.

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY (2023)

Article Materials Science, Multidisciplinary

Annealing hardening effect aroused by solute segregation in gradient ultrafine-grained Mg-Gd-Zr alloy

Chunquan Liu, Xianhua Chen, Domonkos Tolnai, Yaobo Hu, Wei Zhang, Yusheng Zhang, Fusheng Pan

Summary: A remarkable annealing hardening effect was observed in gradient ultrafine-grained Mg-0.32Gd-0.11Zr (at.%) alloy sheet fabricated by sliding friction treatment. The annealed ultrafine-grained structure showed a higher hardening response than the annealed coarse-grained structure. The segregation of solute Gd atoms along grain boundaries and around defects contributed to the significant segregation hardening effect.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2023)

Article Materials Science, Ceramics

Enhancement of hydrogen storage properties from amorphous Mg85Ni5Y10 alloy

H. Zhou, Z. Ding, Y. A. Chen, Z. Q. Lan, S. F. Guo, F. Spieckermann, V. Zadorozhnyy, J. Tan, F. S. Pan, J. Eckert

Summary: The hydrogen storage properties of amorphous and crystalline Mg85Ni5Y10 alloys were compared, and the melt-spun alloy showed higher storage capacity and faster kinetics than the induction-melted alloy. The reversible storage capacity of the melt-spun alloy was 4.2 wt% H2, while the induction-melted sample had 3.8 wt% at 200 degrees C. Furthermore, the melt-spun alloy could release 4.1 wt% H2 within 30 min at temperatures above 275 degrees C, close to its theoretical hydrogen storage capacity of 4.2 wt%.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2023)

Article Chemistry, Physical

g-C3N4 in situ derived ionic-electronic dual-conducting interlayer with N-rich sites for long lifespan sodium metal anodes

Jin Wang, Zhixiao Liu, Baihua Qu, Zhipeng Li, Yiming Zhang, Chunliu Xu, Zhao Chen, Qingshui Xie, Ming-Sheng Wang, Miao Lu, Junmei Zhao, Jingfeng Wang, Dong-Liang Peng, Fusheng Pan, Yong-Sheng Hu

Summary: By constructing an ionic-electronic dual-conducting interlayer with abundant N-sites on the Na metal anode, the stability of the electrode/electrolyte interaction is improved, resulting in prolonged cycling lifespan and enhanced electrochemical performance of Na-based batteries.

ENERGY STORAGE MATERIALS (2023)

Article Materials Science, Coatings & Films

(AlCrNiTiZr)N-x high-entropy nitride coatings with enhanced hardness via tailoring N-2 flow rates for anti-wear applications

Jia Zheng, Cunxiu Zhang, Jingchuan Li, Junyi Chen, Yifan Dong, Sam Zhang, Jian Zhang, Deen Sun

Summary: (AlCrNiTiZr)N-x high-entropy nitride coatings with enhanced hardness were prepared by reactive magnetron cosputtering. The chemical composition, microstructure, as well as mechanical and tribological properties of the coatings were systematically studied. Increasing the nitrogen content improved the hardness of the coating, with the highest hardness of 31.77 GPa achieved at a nitrogen flow rate of 12 SCCM. The wear resistance of the coating was influenced by the hardness, adhesion strength, and damage tolerance of the coating.

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A (2023)

Article Nanoscience & Nanotechnology

The ultrahigh damping capacity of Mg-Sn-Y alloy

Lunchao Zhang, Yuan Yuan, Jun Wang, Tao Chen, Jingfeng Wang, Fusheng Pan

Summary: High temperature heat treatment Mg-0.69Sn-0.69Y alloy exhibited a high damping capacity (0.201 at epsilon=1 x 10-3) and a very low critical strain amplitude at room temperature (epsilon cr1=2.97 x 10-5), which can be ascribed to the combined effects of purified matrix phase and subgrain interfaces. The substructure is unstable and the damping capacity decreases with temperature increment.

SCRIPTA MATERIALIA (2023)

Article Chemistry, Physical

Inhibitory behaviour and adsorption stability of benzothiazole derivatives as corrosion inhibitors towards galvanised steel

Qiushi Deng, Jose Maria Castillo-Robles, Ernane de Freitas Martins, Pablo Ordejon, Jan-Niclas Gorges, Philipp Eiden, Xiao-Bo Chen, Patrick Keil, Ivan Cole

Summary: This study investigates the distinct adsorption behaviors induced by different chemical functionalities on the corrosion of zinc steel. The results show that both inhibitors exhibit corrosion inhibition effects on zinc steel through different mechanisms.

MOLECULAR SYSTEMS DESIGN & ENGINEERING (2023)

Article Chemistry, Physical

Multifunctional continuous solid solution Na0.9Mg0.45Ti3.55O8-Na2Fe2Ti6O16: Preparation, characterization, magnetism, dual absorption, adsorption, and photocatalysis

Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou

Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.

APPLIED SURFACE SCIENCE (2024)

Review Chemistry, Physical

Critical advances in the field of magnetron sputtered bioactive glass thin-films: An analytical review

George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira

Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Corrosion mode evaluation of Fe-based glassy alloys with metalloid elements by electrochemical noise (EN)

Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang

Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Impacts of Zr content of HfZrOx-Based FeFET memory on resilience towards proton radiation

Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu

Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Excellent crystalline silicon surface passivation by transparent conductive Al-doped ZnO/ITO stack

Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong

Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Hydrogen sensing capabilities of highly nanoporous black gold films

Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata

Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Abnormal stability of hydrogenic defects and magnetism near the HSrCoO2.5(001) surface

Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu

Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Space variant fiber nanogratings induced by femtosecond laser direct writing

Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng

Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Wetting mechanisms in the mass transfer process of CuSi3 droplets on the TC4 and 304SS multi-metal system controlled by the hybrid shielding gas atmosphere

Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun

Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Size-regulated Co-doped hetero-interfaced 3D honeycomb MXene as high performance electromagnetic absorber with anti-corrosion performance

Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu

Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Ultrafine Ru nanoparticles on nitrogen-doped CNT arrays for HER: A CVD-based protocol achieving microstructure design and strong catalyst-support interaction

Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng

Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Novel biphenylene as cisplatin anticancer drug delivery carrier; insight from theoretical perspective

Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty

Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Platform for surface-enhanced Raman scattering in layered quantum materials

Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong

Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Cyclotriphosphazene (P3N3) derived FeOx@SPNO-C core-shell nanospheres as peroxymonosulfate activator for degradation via non-radical pathway

Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun

Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Hierarchical confinement of Prussian blue nanoparticles via NH2-MIL-88B (Fe): Rational design and electrocatalytic application

Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan

Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.

APPLIED SURFACE SCIENCE (2024)