Article
Chemistry, Physical
Linsen Li, Xiang Gong, Zhuwei Yang, Riguang Zhang, Zhao Jiang, Tao Fang
Summary: Liquid organic hydrogen carriers (LOHCs) have advantages in hydrogen storage density and convenience of storage and transportation. This study used single-layer Ti3C2Tx MXene as a support to load Pt nanoparticles for the dehydrogenation reaction of 12H-NECZ. The 3 wt% Pt/S-Ti3C2Tx catalyst showed the best catalytic performance.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Environmental Sciences
Zhaolu Feng, Yindong Wang, Xuefeng Bai
Summary: This paper investigates the critical indicators of dehydrogenation reactions in hydrogen storage based on a liquid organic hydrogen carrier (LOHC) system, namely, speeding up the dehydrogenation rate and lowering the reaction temperature. By preparing Pd/SBA-15 catalysts and optimizing the reaction conditions, high dehydrogenation efficiency and catalytic stability were achieved.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Engineering, Chemical
Xiaoxuan Li, Fei Wu, Wenhua Zhou, Chao Chen, Jianghao Wang, Bolong Li, Hao Chen, Jie Fu
Summary: In this study, a PdCoOx-based bimetallic oxide catalyst was prepared and applied for the low-temperature dehydrogenation of 12H-NECZ to produce H2. The activity of Pd was enhanced by introducing Co and the catalyst's electronic state was tuned based on the interfacial effect between PdCoOx and Zr-C3N4 supports. The PdCo bimetallic oxide formation improved the electronic transfer rate and the interaction between the support and PdCoOx, thereby enhancing the catalytic dehydrogenation activity.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Engineering, Environmental
Wenjie Xue, Hongxia Liu, Baohua Mao, Honglei Liu, Minghuang Qiu, Chengguang Yang, Xinqing Chen, Yuhan Sun
Summary: Hydrogen, a promising candidate to replace fossil fuels, faces challenges in storage. A new reusable bimetallic Pd-Rh nanoparticles (NPs) catalyst shows potential for high-weight% hydrogen storage. The mechanism proposed for NEC hydrogenation over the Pd-Rh catalyst opens avenues for the development of LOHCs as energy vectors.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Environmental Sciences
Zhaolu Feng, Xiaomin Chen, Xuefeng Bai
Summary: In this study, Pd/C catalysts were synthesized via Ar glow-discharge plasma reduction, with Pd/C-A showing the best catalytic activity due to its smallest palladium nanoparticles and highest dispersion.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Chemistry, Physical
Hongen Yu, Xue Yang, Xiaojing Jiang, Yiman Wu, Shunpeng Chen, Wei Lin, Yong Wu, Lei Xie, Xingguo Li, Jie Zheng
Summary: In this study, it is demonstrated that LaNi5 alloy can efficiently catalyze reversible hydrogen storage in NEC. LaNi5.5 particles show excellent catalytic ability, achieving a high hydrogen storage capacity of over 5.5wt%. These results are promising for developing high-efficiency LOHC-based hydrogen storage systems.
Article
Chemistry, Applied
Zhaolu Feng, Xuefeng Bai
Summary: Highly dispersed Pd/KIT-6 catalysts were prepared via inorganometallic chemical adsorption and sonochemical reduction, exhibiting excellent performance in the dehydrogenation of dodecahydro-N-ethylcarbazole with a high efficiency of 97.4% and maintaining above 95% efficiency after 10 cycles.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Chemistry, Physical
Wenjie Xue, Hongxia Liu, Binbin Zhao, Lixia Ge, Shuai Yang, Minghuang Qiu, Jiong Li, Wei Han, Xinqing Chen
Summary: The researchers successfully designed an atomic dispersion structure of rhodium and cobalt nanoparticles for the hydrogenation of NEC and dehydrogenation of 12 H-NEC, enabling reversible hydrogen uptake and release. The catalyst achieved complete hydrogenation of NEC at a low temperature of 90 degrees Celsius, representing one of the lowest reported temperatures for the total hydrogenation of NEC. The excellent catalytic performance of the Rh1Co catalyst is attributed to the optimal electronic structure between the atomic dispersion of rhodium and cobalt nanoparticles, allowing fast electron transfer to intermediates.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Energy & Fuels
Zhaolu Feng, Xuefeng Bai
Summary: This study prepared bimetallic Pd-Ni/K6 catalyst through inorganometallic chemistry adsorption and ultrasonic-assisted isopropanol reduction, showing excellent dehydrogenation performance and cycle stability.
Article
Chemistry, Physical
Xiang Gong, Shuyi Guo, Zhao Jiang, Bolun Yang, Tao Fang
Summary: A series of Pd-M/Al2O3 bimetallic catalysts were successfully synthesized in this study, showing higher hydrogen release amount and NECZ selectivity by fine-tuning the alloy degree and nanoparticle size. The increase in NECZ selectivity mainly comes from the enhancement of the kinetic constant of the rate-limiting step.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Materials Science, Multidisciplinary
Chunguang Tang, Preetham Permude, Shunxin Fei, Terry J. Frankcombe, Sean C. Smith, Yun Liu
Summary: Understanding the atomistic steps during the dehydrogenation process of liquid organic hydrogen carriers (LOHCs) is crucial for designing efficient LOHC catalysts. Using density functional theory (DFT), we investigated the thermodynamics and kinetics of the complete dehydrogenation path of perhydro-N-ethylcarbazole (12H-NEC) on Ru(0001) surface. Our results suggest that more efficient dehydrogenation can be achieved by engineering the catalyst surface or using different catalyst materials, and possible dealkylation may occur at elevated temperatures.
COMPUTATIONAL MATERIALS SCIENCE
(2023)
Article
Chemistry, Physical
Bin Wang, Shu-han Lu, Shi-yuan Wang, Pei-ya Li, Tao Fang
Summary: By studying three different Ru catalysts supported on zirconium-based supports, we have identified the effects of supported metal-support strong interaction (SMSI), metal-support anion interaction (MSAI) and hydrogen spillover on the hydrogenation reaction path and the occurrence of isomerization in 12H-NEC product.
APPLIED SURFACE SCIENCE
(2023)
Article
Energy & Fuels
Jinjian Li, Fengya Tong, Yi Li, Xiaohui Liu, Yong Guo, Yanqin Wang
Summary: In this study, the dehydrogenation of 12H-NECZ over supported spinel catalysts in a continuous flow fixed bed reactor was investigated. Pd/MgAl2O4 catalyst showed the best performance due to the strong interaction between Pd and MgAl2O4, resulting in smaller Pd particles and more positively charged Pd species.
Article
Chemistry, Physical
Ziting Liu, Zhaolu Feng, Xuefeng Bai
Summary: In this paper, Ni/MCM-41 catalyst was prepared by chemical reduction method, and Nin@Pd1/M41 core-shell nanocatalysts were prepared by ultrasound-assisted galvanic replacement method. The results showed that Nin@Pd1/M41 had electron transfer and SMSI effect, promoting its catalytic performance. The dehydrogenation efficiency of H12-NEC reached 100% at 180°C for 4 h and at 170°C for 6 h, and 97.58% for 6 h at 160°C, with a TOF of 5080.6 h-1, which was better than that reported in the literature. The excellent catalytic performance of Ni6@Pd1/M41 can mainly be attributed to the synergistic effect of coordination and strain effects between the bimetals.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Energy & Fuels
Yindong Wang, Zhaolu Feng, Xuefeng Bai
Summary: A negatively charged silica surface (-Si-O-) was formed on SBA-15 by treating it with alkali, and ultrafine Pd nanoparticles (Pd NPs) were supported on SBA-15 via NaBH4 reduction. The as-prepared Pd/SBA15 catalyst exhibited excellent catalytic performance for dehydrogenation of H12-NEC. Characterization results revealed that Pd NPs were uniformly dispersed on the pore surface of SBA-15 with high Pd dispersion, and the coordination of Pd NPs with hydroxyl on the SBA-15 surface improved catalytic stability.
Article
Chemistry, Physical
Adil Murtaza, Wen-Liang Zuo, Awais Ghani, Muhammad Yaseen, Azhar Saeed, Tieyan Chang, Zhiyong Dai, Chao Zhou, Yin Zhang, Sen Yang, Xiaoping Song, Yang Ren
Summary: The study investigated the magnetostructural transition, magnetocaloric effect, and critical behavior of Nd(Co0.8Fe0.2)(2) alloy near the ferromagnetic transition. Results showed that the alloy crystallizes in the cubic phase at room temperature and undergoes a structural transition to the tetragonal phase below the Curie temperature, exhibiting good magnetic entropy change and cooling power. The alloy also displayed metallic behavior and the critical exponents derived were consistent with the 3D-Ising class.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Crystallography
Ronghui Kou, Tieyan Chang
Summary: This study aims to investigate the local structure evolution of the terminal compound TbFe2 in the Laves compounds Tb1-xDyxFe2 and provide information about interatomic bonding. The pair distribution function (PDF) results suggest that the compound exhibits rhombohedral local crystal symmetry, and the lattice at the local scale shows abnormal thermal expansion. The different roles of TbFe bond and FeFe bond in affecting the crystal lattice are revealed.
CRYSTAL RESEARCH AND TECHNOLOGY
(2022)
Article
Chemistry, Physical
Pagnareach Tin, Alexandria N. Bone, Nhat N. Bui, Yi-Quan Zhang, Tieyan Chang, Duncan H. Moseley, Mykhaylo Ozerov, J. Krzystek, Yongqiang Cheng, Luke L. Daemen, Xiaoping Wang, Likai Song, Yu-Sheng Chen, Dong Shao, Xin-Yi Wang, Xue-Tai Chen, Zi-Ling Xue
Summary: This study investigates the magnetic and phonon properties of a two-dimensional coordination polymer Co-TODA using advanced spectroscopies and computations. The results show that Co-TODA exhibits easy-plane magnetic anisotropy. The study provides a comprehensive understanding of the magnetic properties and phonon characteristics of this coordination polymer.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Physical
Linzhi Jiang, Tieyan Chang, Guixiang Zhang, Yugang Zhao, Haoxin Chen, Ning Liu, Xue Liu
Summary: This study investigates the formation mechanism of Al2O3/Fe-based composite spherical magnetic abrasive particles (MAPs) prepared via gas-solid atomization and their morphology and distribution. The results show that the breaking mechanism of gas-solid two-phase flow to molten metal is different from pure gas, and the average particle size of MAPs prepared by gas-solid atomization is smaller. The Al2O3 abrasives are mainly distributed on the surface of the iron matrix with almost no distribution inside.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Crystallography
Oluwagbemiga P. Ojo, Winnie Wong-Ng, Tieyan Chang, Yu-Sheng Chen, George S. Nolas
Summary: Single crystals of a new ternary chalcogenide Cu3InSe4 were successfully synthesized by induction melting, and their crystal structure was thoroughly investigated using high-resolution single-crystal synchrotron X-ray diffraction. The results reveal that Cu3InSe4 crystallizes in a cubic structure with three unique crystallographic sites. The chemical bonding nature was studied using electron localization function calculations, and first-principle electronic structure calculations were also performed.
Article
Chemistry, Physical
Bin Wang, Shu-han Lu, Shi-yuan Wang, Pei-ya Li, Tao Fang
Summary: By studying three different Ru catalysts supported on zirconium-based supports, we have identified the effects of supported metal-support strong interaction (SMSI), metal-support anion interaction (MSAI) and hydrogen spillover on the hydrogenation reaction path and the occurrence of isomerization in 12H-NEC product.
APPLIED SURFACE SCIENCE
(2023)
Article
Crystallography
Xiaoli Wang, Shilei Wang, Chao Liu, Chuanyan Fan, Lu Han, Feiyu Li, Tieyan Chang, Yu-Sheng Chen, Shanpeng Wang, Xutang Tao, Junjie Zhang
Summary: Single crystals of the perovskite nickelate NdNiO3 have been grown using the flux method at a temperature of 400 degrees C and oxygen pressure of 200 bar. The crystals were characterized using various techniques and showed a metal-insulator transition at around 180 K. The successful growth of these crystals at relatively low temperatures and oxygen pressure provides an alternative approach for preparing other perovskite materials.
Article
Chemistry, Multidisciplinary
Bin Wang, Qian Dong, Si-Yao Wang, Pei-Ya Li, Shi-Yuan Wang, Shu-Han Lu, Tao Fang
Summary: This study synthesized a Ni-Mo alloy catalyst supported by commercial activated carbon and optimized its ratio and preparation conditions. The results showed that Mo doping significantly promoted the hydrogenation reaction of N-ethylcarbazole. The catalyst achieved high hydrogenation rate in a short time and effectively improved the selectivity of fully hydrogenated products.
FRONTIERS IN CHEMISTRY
(2022)
Article
Chemistry, Physical
Bin Wang, Pei-ya Li, Qian Dong, Li-qin Chen, Hai-qiang Wang, Pei-long Han, Tao Fang
Summary: This paper prepared four kinds of Ni/Co bimetallic catalysts with different proportions by the impregnation method. The effects of the Ni/Co molar ratio and the reduction temperature on the hydrogenation performance of N-ethylcarbazole (NEC) were studied. The design and application of highly efficient nonprecious metal hydrogenation catalysts provide more feasibility to promote the commercial development of liquid organic hydrogen carrier technology.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Energy & Fuels
Bin Wang, Shi-yuan Wang, Shu-han Lu, Pei-ya Li, Tao Fang
Summary: In this study, a series of Ru nanoparticle-supported Ni/Al hydrotalcite-derived oxides (LDOs) with different Ni/Al ratios and preparation methods were prepared and investigated for the hydrogenation of N-ethylcarbazole (NEC). The results showed that the catalyst with 1.5 wt% Ru supported on Ni1Al2-LDO300 exhibited the best catalytic performance, achieving up to 5.5 wt% hydrogen absorption at 150℃ and 8 MPa for 12 minutes, and 100% yield of 12H-NEC conversion within 60 minutes.
Article
Chemistry, Multidisciplinary
Anna L. Poptic, Ying-Pin Chen, Tieyan Chang, Yu-Sheng Chen, Curtis E. Moore, Shiyu Zhang
Summary: This study investigates the assembly of MnIIFeII cofactors in class Ic ribonucleotide reductases (RNRIc) and R2 like ligand-binding oxidases (R2lox). The authors report the selective formation of MnIIFeII complex even in the absence of a protein scaffold. X-ray diffraction reveals that MnIIFeII exhibits the same site selectivity as RNRIc and R2lox. The assembly mechanism of MnIIFeII is elucidated.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Bin Wang, Pei-ya Li, Shi-yuan Wang, Shu-han Lu, Tao Fang
Summary: The liquid organic hydrogen carrier (LOHC) technology shows great potential in hydrogen storage and delivery. N-ethylcarbazole (NEC) is a promising hydrogen storage carrier that can undergo reversible hydrogenation and dehydrogenation reactions. However, during the dehydrogenation reaction, side reactions involving C-N bond cleavage often occur. In this study, it was found that using a Pd catalyst supported on Mg-Al spinel can reduce side reactions, improve dehydrogenation activity and selectivity, and decrease the amount of noble metal Pd used. The improvement in catalyst activity is attributed to the smaller active metal particles and the valence distribution of Pd, while the reduction of C-N bond cleavage is related to the moderate acid site density of the catalyst, the synergy effect between metal and acid sites, and the weak adsorption capacity of dehydrogenation products.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Anna L. Poptic, Ying-Pin Chen, Tieyan Chang, Yu-Sheng Chen, Curtis E. Moore, Shiyu Zhang
Summary: Class Ic ribonucleotide reductases (RNRIc) and R2-like ligand-binding oxidases (R2lox) assemble heterobimetallic (MnFeII)-Fe-II cofactors through carefully constructed protein structures. This study demonstrates the selective formation of (MnFeII)-Fe-II complex in the absence of a protein scaffold. The successful assembly of (MnFeII)-Fe-II is attributed to Fe-deficient conditions, site differentiation, and the inability of the ligand to accommodate a dimanganese complex.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Bin Wang, Pei-ya Li, Qian Dong, Li-qin Chen, Hai-qiang Wang, Pei-long Han, Tao Fang
Summary: This paper discusses the preparation of four kinds of Ni/Co bimetallic catalysts and their effects on the hydrogenation performance of NEC. The results show that the addition of 50% cobalt achieves the most significant hydrogenation activity, with 100% NEC conversion and 98.99% 12H-NEC selectivity. The catalyst exhibits a hydrogenation capacity of 5.77 wt % at a reduction temperature of 450 degrees C. The synergistic interaction between Ni/Co metals is identified as the key factor for the remarkable catalytic activity. The development and application of highly efficient nonprecious metal hydrogenation catalysts contribute to the commercialization of LOHC technology.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Chao Zhou, Tieyan Chang, Zhiyong Dai, Yuanliang Chen, Chenyang Guo, Yoshitaka Matsushita, Xiaoqin Ke, Adil Murtaza, Yin Zhang, Fanghua Tian, Wenliang Zuo, Yu-sheng Chen, Sen Yang, Xiaobing Ren
Summary: This paper investigates the nature of phase transitions in TbCo2, a Laves-phase rare-earth-transition metal intermetallic compound. Through experimental evidence and interpretation using Landau theory, it is determined that the transition in TbCo2 is a first-order transition. This study contributes to a deeper understanding of phase transitions in magnetic materials involving both magnetic and structural transitions.
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)