期刊
ACS OMEGA
卷 4, 期 6, 页码 10302-10310出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.9b00710
关键词
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资金
- UGC Start-Up Research Grant [F.30-326/2016 (BSR)]
- RUSA - Phase 2 grant [24-51/2014-U]
Investigation on the formation mechanism of the beta-Nis@Ni(OH)(2) nanocomposite electrode for electrochemical water splitting application was attempted with the use of the hydrothermal processing technique. Formation of single-phase beta-Nis, Ni(OH)(2) and composite-phase beta-Nis@Ni(OH)(2) has been thoroughly analyzed by X-ray diffractometer (XRD) spectra. Three different kinds of morphologies such as rock-like agglomerated nanoparticles, uniformly stacked nanogills, and uniform nanoplates for beta-Nis,Ni(OH)(2) , and beta-Nis@Ni(OH)(2) materials, respectively, were confirmed by SEM images. The characteristic vibration modes of beta-Nis,Ni(OH)(2) and beta-Nis@Ni(OH)(2) nanocomposites were confirmed from Raman and Fourier transform infrared spectra. Near band edge emission and intrinsic vacancies present in the nanocomposites were retrieved by photoluminescence spectra. The optical band gaps of the synthesized nanocomposites were calculated as 2.1, 2.5, and 2.2 eV for beta-Nis,Ni(OH)(2), and beta-Nis@Ni(OH)(2) products, respectively. The high-performance electrochemical water splitting was achieved for the beta-Nis@Ni(OH)(2) nanocomposite as 240 mA/g at 10 mV/s from a linear sweep voltammogram study. The faster charge mobile mechanism of the same electrode was confirmed by electrochemical impedance spectra and a Tafel slope value of 53 mV/dec. The 18 h of stability was achieved with 95% retention, which was also reported for the beta-Nis@Ni(OH)(2) nanocomposite for continuous electrochemical water splitting applications.
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