Article
Chemistry, Multidisciplinary
Wanzhen Xu, Wenjie Zhu, Junliang Shen, Mingyue Kuai, Yi Zhang, Weihong Huang, Wenming Yang, Mengmeng Li, Sheng Yang
Summary: Graphene oxide (GO) has various applications in energy devices, biomedicine, environmental protection, and composite materials. A stepwise electrochemical method for fast GO preparation is reported, which involves spontaneous persulfate intercalation and anodic electrolytic oxidation. This method avoids uneven intercalation and insufficient oxidation, significantly shortening the overall duration, and resulting in GO with higher oxygen content and enhanced adsorption capacity compared to traditional methods.
Article
Chemistry, Multidisciplinary
Eduart Gutierrez-Pineda, Ahmed Subrati, Maria Jose Rodriguez-Presa, Claudio A. Gervasi, Sergio E. Moya
Summary: This paper presents an electrochemical exfoliation method for producing graphene oxide and characterizes it using electrochemical techniques. The electrochemical behavior of the produced graphene oxide was studied through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Additionally, various characterization techniques such as X ray Photoelectronic Spectroscopy (XPS), Raman spectroscopy, Transmission Electron Microscopy (TEM), and Atomic Force Microscopy (AFM) were employed to analyze the structural and chemical properties of the exfoliated graphene oxide. The results demonstrate that the electrochemical exfoliation method allows for the production of graphene oxide materials with varying degrees of oxidation, defect density, and crystallite size.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Physics, Multidisciplinary
Ashamoni Neog, Rajib Biswas, Nishant Bharali
Summary: A green route for synthesizing graphene oxide (GO) from waste Zn-C dry cell batteries was comprehensively reported in this study. LiCl was used as the electrolyte for electrochemical synthesis of GO from graphite rods extracted from waste batteries. The satisfactory yield and confirmatory characterizations confirmed the feasibility and efficiency of the synthesis.
Article
Chemistry, Multidisciplinary
Pratiksha M. Biranje, Ashwin W. Patwardhan, Jyeshtharaj B. Joshi, Jyoti Prakash, Kinshuk Dasgupta
Summary: A kinetic study was conducted on the synthesis of graphene oxide (GO) by electrochemical exfoliation of graphite in acidic and alkaline electrolytes. The study examined the effects of temperature, sulfuric acid concentration, pH, current density, and graphite density on the rate of GO formation. It was found that the rate of GO exfoliation increased with sulfuric acid concentration and temperature. The mechanism and rate law were proposed based on the findings, and the synthesized GO was characterized using various techniques.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Article
Chemistry, Physical
Jiaxi Zeng, Xiaoli Zhao, Hongbin Lu
Summary: This study demonstrates a liquid-phase sewing strategy to construct carbon foams (CFs) directly from flake graphite, overcoming the challenge of constructing CFs with desired structures and intact lattice integrity. The CFs constructed through this method exhibit high conductivity and high-performance electromagnetic interference shielding effectiveness.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Physical
Damilola Momodu, Moshawe J. Madito, Ashutosh Singh, Farbod Sharif, Kunal Karan, Milana Trifkovic, Steven Bryant, Edward P. L. Roberts
Summary: Precise control of electrochemical intercalation and exfoliation conditions can tune the properties of graphene. The study shows that careful selection of intercalation time is crucial in controlling the defects in graphene, and phosphorus and nitrogen-doping can enhance graphene properties. Additionally, extending intercalation times deteriorated electrical conductivity but improved thermal stability.
Article
Chemistry, Physical
C. Justin Raj, Ramu Manikandan, Pugalenthiyar Thondaiman, Periyasamy Sivakumar, A. Dennyson Savariraj, Won-Je Cho, Byung Chul Kim, Hyun Jung
Summary: Graphene synthesized via electrochemical exfoliation of graphite is a simple, fast, and scalable technique suitable for supercapacitor electrodes. Pulse sonication assisted electrochemical exfoliation significantly enhances the process, with the nature of electrolyte and intercalation ions playing a crucial role in the quality and performance of graphene. The presence of various defect sites on the surface and edges of graphene exfoliated in acidic and neutral electrolytes contributes to improved electrochemical performance.
Review
Chemistry, Multidisciplinary
Masato Komoda, Yuta Nishina
Summary: Oxidation of graphite is a promising method for large-scale production of graphene-like materials, and electrochemical oxidation has emerged as a simple, safe, and controllable production method. Different electrochemical conditions and forms of starting graphite can lead to products with varying oxygen content, providing an option for controlled production of graphene-like materials.
Article
Chemistry, Physical
Hongfang Sun, Gang Xu, Weixing Lian, Gediminas Kastiukas, Jinlong Zhang, Xiaogang Zhang, Wei Liu, Feng Xing, Jie Ren
Summary: Graphene oxide (GO) sheets were successfully synthesized using tap water as the electrolyte in an electrochemical exfoliation method. The properties of the resulting GO materials were influenced by electrode materials and different intensities of electrical current, with increasing current leading to higher GO concentration, more defects and carboxyl groups, and smaller particle sizes. Carbon fiber sheets were found to be preferable for large-scale productions of GO due to controllable size range and higher concentration compared to graphite rods at a given electrical current.
CHEMICAL PHYSICS LETTERS
(2022)
Article
Biochemistry & Molecular Biology
Yuting Lei, Ludmila dos Santos Madalena, Benjamin D. Ossonon, Fausto Eduardo Bimbi Junior, Jiyun Chen, Marcos R. Lanza, Ana C. Tavares
Summary: This study presents a one-step method to prepare graphene oxide materials functionalized with aminobenzoic acid. The resulting material showed smaller flake size and higher density of oxygenated functional groups compared to bare graphene oxide. The electrochemical studies demonstrated that the functionalized materials had higher activity for the oxygen reduction reaction and exhibited excellent cycling performance.
Article
Biochemistry & Molecular Biology
Michael Salverda, Antony Raj Thiruppathi, Farnood Pakravan, Peter C. Wood, Aicheng Chen
Summary: A new automated electrochemical process for the production of graphene oxide (GO) from graphite has been reported. The morphology, structure, and composition of the electrochemically exfoliated GO (EGO) were analyzed and compared with GO prepared using the traditional chemical method. The automated electrochemical process was found to be effective, and the electrochemical properties of EGO, CGO, and other carbon-based materials were further investigated and compared. The automated electrochemical exfoliation of natural graphite powder is a facile, cost-effective, and easy-to-scale-up method for the large-scale production of graphene-based nanomaterials.
Article
Chemistry, Physical
Xinyu Mao, Liqun Zhu, Huicong Liu, Haining Chen, Wen Li, Rui Cao, Weiping Li
Summary: In this study, graphene was successfully prepared by electrochemical exfoliation and directly dispersed in CuSO4 solutions without adding surfactants, overcoming the obstacle of dispersing graphene in aqueous solutions. The co-deposited graphene affected the oxidation reaction rate and preferred orientation of the coatings, reducing the oxidation degree of the Cu/graphene composite coatings.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Alberto Adan-Mas, Jacob Olchowka, Lydie Bourgeois, Philippe Legros, Patrizia Paradiso, Fatima Montemor, Liliane Guerlou-Demourgues
Summary: Nickel-cobalt oxyhydroxide has been delaminated by tetrabutylammonium intercalation, which increases the number of electrochemically active sites and enhances the material's capacity. This technique shows promise for improving the performance of electrode materials for electrochemical energy storage.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Mariana C. F. Costa, Valeria S. Marangoni, Pei Rou Ng, Hang T. L. Nguyen, Alexandra Carvalho, A. H. Castro Neto
Summary: Graphene oxide (GO) obtained through an environmentally friendly modified Hummers method shows unique physical and chemical properties suitable for various industrial applications. The absence of intercalant agents leads to a significantly reduced reaction time, making it a promising alternative for applications in different fields.
Article
Materials Science, Multidisciplinary
Pankaj Kumar Singh, Pradeep Kumar Singh, Kamal Sharma
Summary: This study investigates the effect of thermal annealing on the microstructural characteristics and properties of graphene oxide. The results show that thermal annealing has a substantial impact on the crystallite size, structural disorder, and surface topography of the thermally reduced graphene oxide (TrGO), but has little effect on thermal stability and oxygen-containing functional groups.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Chemistry, Applied
Jie Deng, Siyuan Fang, Yan Fang, Qianqian Hao, Lei Wang, Yun Hang Hu
Summary: Metal-air batteries show great potential as next-generation energy conversion and storage devices due to their high theoretical energy densities. However, the slow kinetics of oxygen reduction and evolution reactions hinder their practical energy densities and voltages. Graphene-based electrocatalysts have attracted much attention in materials science and interface chemistry to address this issue, thanks to their tunable catalytic properties, high electrical conductivities, and large surface areas. In this review, the principles of oxygen electrocatalytic reactions and the requirements for efficient graphene-based electrocatalysts are discussed, along with the progress and challenges in this field.
Article
Chemistry, Multidisciplinary
Shaoqin Chen, Siyuan Fang, Zongwei Sun, Zhangyang Li, Chunling Wang, Yun Hang Hu
Summary: A novel three-phase catalytic system with an in situ generated and dynamically updated thin water film covered on the noble-metal-free TiO2-based catalyst has been reported for highly efficient CO2 hydrogenation, achieving a four-time enhancement compared to the catalyst suspended in water. The water film performs dual roles in the reaction by directly participating and removing the produced oxygenates from the catalyst surface.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Applied
Zichen Du, Fuping Pan, Xiaokun Yang, Lingzhe Fang, Yang Gang, Siyuan Fang, Tao Li, Yun Hang Hu, Ying Li
Summary: In this study, Ni-based catalysts with improved activity and stability for solar-driven photothermochemical dry reforming of methane (PTC-DRM) were developed by supporting Ni nanoparticles on CeO2 incorporated ZrO2. The Ni-CeO2/ZrO2 catalyst exhibited significantly higher production rates of H2 and CO compared to Ce-free Ni/ZrO2. The introduction of CeO2 lowered the activation energies of CH4 and CO2 conversions, and the plasmonic effect from Ni mitigated coke deposition and enhanced the PTC-DRM activities and stability. This study is important for designing cost-effective Ni-based catalysts and reaction systems for greenhouse gases conversion using sustainable solar energy.
Article
Chemistry, Multidisciplinary
Siyuan Fang, Wei Zhang, Kai Sun, Yun Hang Hu
Summary: This study demonstrates the efficient degradation of antibiotics using WS2 catalyst under visible light irradiation and in situ-generated heat. The thermophotocatalytic process shows significantly higher removal and mineralization rates compared to thermal catalysis and room-temperature photocatalysis, while reducing the toxicity of degradation products.
ENVIRONMENTAL CHEMISTRY LETTERS
(2023)
Article
Energy & Fuels
Siyuan Fang, Yun Hang Hu
Summary: This study investigates the influence of temperature, pressure, and molecular adsorption on the redox potentials of CO2 reduction reactions. It finds that adsorption-state redox potentials are sensitive to temperature, and significant differences in redox potentials can impact the thermodynamics and kinetics of reactions.
ENERGY SCIENCE & ENGINEERING
(2022)
Article
Engineering, Environmental
Yang Gang, Boyang Li, Siyuan Fang, John Pellessier, Lingzhe Fang, Fuping Pan, Zichen Du, Yun Hang Hu, Tao Li, Guofeng Wang, Ying Li
Summary: Metal-nitrogen doped carbon catalysts for electrochemical reduction of CO2 to CO have been developed using a simple and sustainable method. The catalysts exhibit high performance and selectivity in the conversion process.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Environmental Sciences
Siyuan Fang, Wei Zhang, Kai Sun, Tian Tong, Aniqa Ibnat Lim, Jiming Bao, Zichen Du, Ying Li, Yun Hang Hu
Summary: In this study, tetracycline was demonstrated to have multiple self-promotion effects on ZnO nanorods as a band adjuster, photo-sensitizer, and charge transfer promoter, enabling efficient visible-light photocatalytic degradation with a removal efficiency of 91.1% within 2 hours. The study also evaluated the influence of realistic factors and identified the active species and degradation products. This research paves the way for a novel self-driven visible-light photocatalysis.
Article
Chemistry, Multidisciplinary
Zichen Du, Cullen Petru, Xiaokun Yang, Fan Chen, Siyuan Fang, Fuping Pan, Yang Gang, Hong-Cai Zhou, Yun Hang Hu, Ying Li
Summary: In this work, Ce-substituted LaNiO3 perovskite catalysts were used for solar-driven photothermochemical dry reforming of methane. It was found that Ce substitution improved the distribution of Ni active sites, mitigated sintering and carbon formation, and enhanced the reaction rates.
JOURNAL OF CO2 UTILIZATION
(2023)
Article
Energy & Fuels
Siyuan Fang, Yun Hang Hu
Summary: This study reports for the first time the effects of temperature, pressure, and adsorption on the redox potentials of 18 CO conversion reactions. The experimental results show that the gas-phase, aqueous-phase, and adsorption-state redox potentials exhibit different trends with increasing temperature, and they also respond differently to pressure changes. These differences highlight the necessity of using operando redox potentials in CO conversion reactions.
ENERGY SCIENCE & ENGINEERING
(2023)
Article
Energy & Fuels
Siyuan Fang, Yun Hang Hu
Summary: This study reports the temperature, pressure, and adsorption-dependent redox potentials of 13 CH4 oxidation reactions. It was found that the redox potentials decrease with temperature at an accelerated rate, and their responses to pressure change differ. This enriched database supports the application of CH4 oxidation reactions.
ENERGY SCIENCE & ENGINEERING
(2023)
Article
Environmental Sciences
Shaoqin Chen, Siyuan Fang, Aniqa Ibnat Lim, Jiming Bao, Yun Hang Hu
Summary: Converting waste plastic into valuable carbon materials as supercapacitor electrodes is a sustainable solution for plastic-related environmental issues. In this study, MgO-templated pyrolysis with chemical activation was used to convert waste PET plastic bottles into 3D meso/macroporous carbon with large surface area. The resulting carbon material exhibited high capacitance (191.4 F/g) and excellent rate capability (86.3% retention from 0.5 to 10 A/g). This work provides a facile method to synthesize 3D meso/macroporous carbon materials and contributes to mitigating plastic pollution.
Article
Multidisciplinary Sciences
Siyuan Fang, Xingyi Lyu, Tian Tong, Aniqa Ibnat Lim, Tao Li, Jiming Bao, Yun Hang Hu
Summary: Large numbers of leaves fall off trees each autumn. Here, the authors turn dead leaves into an active material which acts as bioplastic and shows high performance in solar water evaporation, photocatalytic H-2 production and antibiotic degradation.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Yang Gang, John Pellessier, Zichen Du, Siyuan Fang, Lingzhe Fang, Fuping Pan, Manuel Suarez, Kirk Hambleton, Fan Chen, Hong-Cai Zhou, Tao Li, Yun Hang Hu, Ying Li
Summary: This study developed a simple and scalable synthesis method to convert metal-impurity-containing commercial carbon nanotubes (CNTs) and nitrogen-containing organic precursors into metal-and nitrogen-doped carbon (M-N-C) catalysts. The catalysts exhibited high CO selectivity and durability, outperforming benchmark catalysts and overcoming the short-term stability issues of other M-N-C catalysts reported in the literature. The scalable and cost-effective synthesis approach paves the way for practical CO2 reduction applications.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Multidisciplinary Sciences
Siyuan Fang, Motiar Rahaman, Jaya Bharti, Erwin Reisner, Marc Robert, Geoffrey A. Ozin, Yun Hang Hu
Summary: Using sunlight to power CO2 conversion into value-added chemicals and fuels is a promising technology. This Primer provides a step-by-step guide for the experimentation of photocatalytic CO2 reduction, including catalyst synthesis and characterization, reactor construction, photocatalytic testing, and exploration of mechanism. It also discusses the state-of-the-art results, highlights important considerations for practical application, and proposes strategies to enhance energy conversion efficiency and product selectivity.
NATURE REVIEWS METHODS PRIMERS
(2023)
Article
Chemistry, Multidisciplinary
Siyuan Fang, Xiao Tong, Dario Stacchiola, Yun Hang Hu
Summary: In this study, we report the formation of solid-state crystals through assembly of the dense HB phosphorous-nitrogen isomers via P···H and P···N bonds and axial D···D interactions. This novel reaction provides a new approach for designing and constructing various molecular crystal materials.
CHEMICAL COMMUNICATIONS
(2023)