4.6 Article

Strategy for highly sensitive optical ratiometric temperature measurement

期刊

OPTICAL MATERIALS EXPRESS
卷 9, 期 8, 页码 3260-3267

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OPTICAL SOC AMER
DOI: 10.1364/OME.9.003260

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  1. National Natural Science Foundation of China (NSFC) [61505045, 81571720]

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The Er3+ ion's F-4(7/2)-I-4(15/2) transition, which has been less reported in the past, is studied in CaWO4:Yb3+/Er3+ phosphors. It has been confirmed that this transition is from the two-photon upconversion mechanism when the 980 nm laser diode is used as the excitation source. Moreover, the transition has the same lifetime with the neighboring lower H-2(11/2)/S-4(3/2) states, suggesting that the F-4(7/2)/S-4(3/2) states are thermally linked. It is shown that the F-4(7/2)/S-4(3/2)-I-4(15/2) emissions can be used for ratiometric temperature measurement. Their relative thermal sensitivity is up to 2820/T-2, one of the largest sensitivities reported so far. It is very close to the theoretical maximum 2877/T-2. (C) 2019 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

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