Solid-phase fluorescence excitation emission matrix for in-situ monitoring of membrane fouling during microfiltration using a polyvinylidene fluoride hollow fiber membrane

Controlling membrane fouling is challenging and information regarding the causes of fouling is critical for this. While liquid-phase fluorescence spectroscopy excitation emission matrix (LPF-EEM) has previously been applied to identify the characteristics of membrane foulants, we applied EEM measurements to solid samples to identify foulants accumulated on the membrane. This solid-phase fluorescence EEM (SPF-EEM) enables sensitive and nondestructive identification of different organic solids. LPF-EEMs and SPF-EEMs were used on natural organic matter (NOM) isolated from secondary-treated wastewater, which revealed differences in peak positions and in spectral shapes. SPF-EEMs and LPF-EEMs of hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions showed that peaks of HPO fraction disappeared while those of TPI and HPI fractions shifted to a longer excitation and emission position through solidification. Then, the surface of the membrane fiber was continuously monitored using SPF-EEM during filtration. Three peaks appeared as expected during membrane fouling progression, indicating that in-situ monitoring of foulants was successful. Comparison of the EEM peaks between foulants and isolated NOM fractions shows the presence of both liquid-phase proteinaceous substances and gels formed from HPI and TPI fractions. Changes in peak intensity confirmed that the former proteinaceous substances were responsible for both reversible and irreversible fouling, while the latter gels mainly contributed to the irreversible fouling. We demonstrated the functionality of the SPF-EEM as an in-situ fouling monitoring tool. (C) 2019 Elsevier Ltd. All rights reserved.