Article
Spectroscopy
Zhaoqing Cai, Zheng Wang
Summary: The use of solution anode glow discharge (SAGD) in hydrogen-helium mixture was evaluated for optical emission spectrometry (OES) of arsenic (As) in solution. The enclosed structure and non-electrode hollow channel were adopted to integrate the functions of vapor generation, atomization, and excitation of As. The study found that propionic acid had the best amplification effect, and the detection limit of SAGD-OES for As was better than that of the fully open-to-air discharge system. SAGD was more susceptible to chemical interferences induced by transition metal elements compared to alkali metals and alkaline earth metals.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2023)
Article
Chemistry, Analytical
Jun-Hang Dong, Chun Yang, Han-Qing Ding, Peng-Ju Xing, Fei-Yang Zhou, Huan Tian, Xing Liu, Hong-Tao Zheng, Sheng-Hong Hu, Zhen-Li Zhu
Summary: A portable, rapid, accurate, and cost-effective method for serum lithium determination was developed, utilizing MUN and APAD technologies, with detection completed in 40 seconds, no need for extra treatment of serum samples, and good tolerance to coexisting high concentration of other elements.
ANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Applied
Krzysztof Greda, Pawel Pohl
Summary: A new method of optical emission spectrometry (OES) using micmplasma source was developed for the determination of Na, K, Mg, Ca, and Zn in wine, without the need for acid digestion. The study also found that red wines have higher levels of K and Mg, and different grape varieties can be distinguished based on the concentrations of K and Ca.
Review
Chemistry, Multidisciplinary
Xiaoxu Peng, Zheng Wang
Summary: The article provides an overview of the development of solution electrode glow discharge (SEGD) in various fields and discusses its discharge mechanism. SEGD has unique advantages for optical emission spectrometry and mass spectrometry, and it has broad research potential in biology and medicine, material synthesis, electrochemistry, etc.
CHINESE CHEMICAL LETTERS
(2022)
Article
Chemistry, Analytical
Meng Zhang, Qingsong Tang, Peixia Li, Lin He, Xiandeng Hou, Xiaoming Jiang
Summary: A new compact tandem excitation source was designed and constructed using an array point discharge microplasma for a miniaturized optical emission spectrometer. The ArrPD microplasma was constructed by arranging three pairs of point discharges in sequence in a narrow discharge chamber, improving excitation capability through serial excitation. The enlarged discharge plasma region allowed for increased interception of gaseous analytes, leading to improved excitation efficiency and OES signal.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Analytical
Meng Zhang, Qingsong Tang, Peixia Li, Lin He, Xiandeng Hou, Xiaoming Jiang
Summary: A new compact tandem excitation source was designed and constructed using an array point discharge microplasma for a miniaturized optical emission spectrometer. The ArrPD microplasma consisted of three pairs of point discharges arranged in sequence in a narrow discharge chamber, which significantly improved the excitation capability and efficiency. The proposed ArrPD source was compared to a commonly used microplasma source and showed 3-6-fold improvement in analytical sensitivities for seven elements.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Analytical
Yinchenxi Zhang, Jaime Orejas, Jonatan Fandino, David Blanco Fernandez, Jorge Pisonero, Nerea Bordel
Summary: This study investigated the influence of sodium chloride (NaCl) on the analytical response and performance of solution-cathode glow discharge coupled to optical emission spectroscopy (SCGD-OES). It was found that signal stability degraded at higher NaCl concentrations, but discharge reductive capacity was enhanced. NaCl inhibited potential interfering molecular emission and affected atomic emission of different elements differently.
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2022)
Article
Chemistry, Analytical
Quanfang Lu, Yan Feng, Hui Luo, Jie Yu, Yuejing Kang
Summary: A miniature atomic emission spectrometry (AES) was developed using a liquid cathode glow discharge (LCGD) as an excitation source and optical fiber spectrometer as the detection system. The instrument was employed for the sensitive determination of lithium (Li). The addition of surfactants improved the Li emission and eliminated the interference of Al3+ and SO42-. The method showed low cost, small size, and low power consumption.
ANALYTICAL LETTERS
(2022)
Article
Spectroscopy
Jaime Orejas, Yinchenxi Zhang, Cristian Soto-Gancedo, Luis Javier Fernandez-Menendez, Jorge Pisonero, Nerea Bordel
Summary: The Solution-Cathode Glow Discharge (SCGD) is a plasma source that provides simplicity and low consumption for elemental analysis. When combined with Optical Emission Spectrometry (OES), it can achieve ng/mL limits of detection for multiple elements. This study focuses on fundamental plasma diagnostics of SCGD and investigates how dissolved ions in the sample solution affect the performance of the analysis.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2023)
Article
Spectroscopy
Monika Gorska, Pawel Pohl
Summary: This study tested tubes of different diameters and materials for their suitability in a flowing liquid cathode atmospheric pressure glow discharge system. The impact of different tube combinations on discharge stability and signal intensity was evaluated. Tungsten and corundum tubes were found to perform well in terms of discharge stability and signal intensity.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2023)
Article
Spectroscopy
Nikola Ivanovic, Nikodin Nedic, Ivan R. Videnovic, Dj. Spasojevic, Nikola Konjevic
Summary: We studied the emission spectra of Ne I 503.775 nm and Ne I 508.038 nm atomic lines in two different DC glow discharge sources. Our modified discharge source allows recording of complex line shapes from two optical directions, enabling spatially resolved Stark polarization spectroscopy. The observed correlation between the electric field strength in the cathode sheath and the recorded spectral shifts provides insights into the cathode sheath parameters.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2023)
Article
Spectroscopy
Zdenek Weiss, Florence Concepcion-Mairey, Juliet C. Pickering, Petr Smid
Summary: Extensive analysis of Ti and Fe emission spectra from both plane and hollow cathode glow discharges in argon reveals deviations from simple models of laboratory plasmas assuming local thermodynamic equilibrium. Ionization of analytes in both discharge modes is dominated by charge transfer between Ar+ ions and neutral analyte atoms, with more pronounced process in plane cathode than hollow cathode discharge. This overpopulation of long-lived ground term and metastable analyte ions spreads into high-energy levels of neutral atoms by collisional 3-body recombination with electrons, indicating conditions not close to local thermodynamic equilibrium.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2021)
Article
Chemistry, Analytical
Peichao Zheng, Yuanjiang Luo, Jinmei Wang, Yang Yang, Qiang Hu, Xuefeng Mao, Chunhong Lai
Summary: An improved micro-plasma source was developed for the quantitative analysis of heavy metal elements by solution cathode glow discharge-optical emission spectrometry (SCGD-OES). The source, fabricated using a geometrically optimized stainless steel auxiliary cathode solution and a tungsten anode, achieved optimum discharge at reduced solution flow rates. With detection limits for multiple heavy metal elements and good agreement in recoveries compared to ICP-OES, this study may contribute to the design of glow discharge sources for in situ determination of metal elements in complex water samples.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Analytical
Zhongchen Wu, Zongcheng Ling, Jiang Zhang, Xiaohui Fu, Changqing Liu, Yanqing Xin, Bo Li, Le Qiao
Summary: Laboratory simulation is essential for studying Martian environmental conditions and mineral features, linking the laboratory with Mars exploration. The Mars environment chamber (MEC) at Shandong University in China is equipped with multiple in situ spectral sensors to simulate and collect data on Martian environmental parameters. This platform provides a solid foundation for future analysis and interpretation of real Martian spectral data, contributing to China's Mars mission preparations.
Article
Chemistry, Analytical
Monika Gorska, Pawel Pohl
Summary: In this study, novel atmospheric pressure microplasma systems were investigated for the determination of Ga and In by optical emission spectrometry (OES), with optimized working parameters and the addition of low molecular weight organic compounds (LMWOCs) into the solution. The impact of concomitant ions on the signals intensity of Ga and In was also studied, showing the resistance to matrix effects. The detection limits obtained under optimized conditions were comparable to those obtained by large-scale instrumentation, confirming the accuracy and reliability of the developed FLC-APGD-OES method.
Article
Chemistry, Applied
Krzysztof Greda, Pawel Pohl
Summary: A new method of optical emission spectrometry (OES) using micmplasma source was developed for the determination of Na, K, Mg, Ca, and Zn in wine, without the need for acid digestion. The study also found that red wines have higher levels of K and Mg, and different grape varieties can be distinguished based on the concentrations of K and Ca.
Article
Chemistry, Analytical
Krzysztof Swiderski, Krzysztof Greda, Pawel Pohl, Piotr Jamroz
Summary: This study evaluated the application of hanging drop cathode atmospheric pressure glow discharge coupled with a Dove prism as an efficient excitation microsource for optical emission spectrometry. The operating conditions were optimized using a design of experiment approach, and it was found that the addition of formic acid significantly enhanced the atomic emission lines of Ag, Pb, and Tl, resulting in improved detection limits for these elements.
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2022)
Article
Chemistry, Analytical
Monika Gorska, Pawel Pohl
Summary: Novel atmospheric pressure glow discharge microplasma systems were investigated for the direct determination of Br and Cl, showing resistance to foreign ions at relatively high concentrations in water and juices samples.
Article
Chemistry, Applied
Anna Dzimitrowicz, Pawel Pohl, Magda Caban, Piotr Jamroz, Piotr Cyganowski, Mateusz Bykowski, Aleksandra Klimczak, Aleksandra Bielawska-Pohl
Summary: This research proposed a method for functionalizing orange juice using direct current atmospheric pressure glow discharge, which increased the concentration of certain substances and prolonged the shelf life of the juice. The treated juice showed no toxicity towards non-malignant cells, but exhibited cytotoxicity towards malignant cells, making it a potential alternative to untreated juice.
Article
Chemistry, Applied
Pawel Pohl, Anna Dzimitrowicz, Piotr Cyganowski, Piotr Jamroz
Summary: Cold atmospheric pressure plasma (CAPP) technology can be used to treat fruit and vegetable beverages, not only extending their shelf-life, but also improving their nutritional properties and anticancer activity. The presence of numerous reactive oxygen and nitrogen species (RONS) at the plasma-liquid interface can increase the content of nutritional and bioactive compounds in the beverages.
Article
Chemistry, Analytical
Pawel Pohl, Maja Welna, Anna Szymczycha-Madeja, Krzysztof Greda, Piotr Jamroz, Anna Dzimitrowicz
Summary: The Box-Behnken response surface design and individual desirability functions were used to develop a new and simplified sample preparation method for coffee brews. The method showed high precision and accuracy, and was successfully applied to the multielement analysis of different types of coffee and various brewing devices.
Article
Multidisciplinary Sciences
Anna Dzimitrowicz, Magda Caban, Dominik Terefinko, Pawel Pohl, Piotr Jamroz, Weronika Babinska, Piotr Cyganowski, Piotr Stepnowski, Ewa Lojkowska, Wojciech Sledz, Agata Motyka-Pomagruk
Summary: A continuous-flow reaction-discharge system was developed for efficient removal of doxycycline from liquid solutions. The treated doxycycline solution lost its antimicrobial properties towards Escherichia coli and significantly decreased biocidal activities for certain bacteria.
SCIENTIFIC REPORTS
(2022)
Article
Engineering, Chemical
Piotr Cyganowski, Magda Caban, Mujahid Ameen Khan, Mateusz M. Marzec, Andrzej Zak, Pawel Pohl, Piotr Jamroz, Andrzej Bernasik, Anna Dzimitrowicz
Summary: Monosaccharide- and polysaccharide biopolymer-stabilized rhenium oxide nanoparticles have been effectively applied for the deactivation of furazolidone and chloramphenicol dissolved in solutions. The optical and granulometric properties of the stabilized nanoparticles were revealed using various experimental techniques. The raw nanoparticles showed a high efficiency in reducing both furazolidone and chloramphenicol, while the saccharide-stabilized nanostructure was less effective in reducing chloramphenicol.
PLASMA CHEMISTRY AND PLASMA PROCESSING
(2023)
Article
Engineering, Environmental
Dominik Terefinko, Magda Caban, Agata Motyka-Pomagruk, Weronika Babinska, Pawel Pohl, Piotr Jamroz, Piotr Cyganowski, Wojciech Sledz, Ewa Lojkowska, Piotr Stepnowski, Anna Dzimitrowicz
Summary: The high demands from the medical and husbandry sectors have caused a global production of 100,000 tonnes of various antibiotics annually. To address the subsequent increase in resistance of virulent human bacterial pathogens due to exposure to sublethal doses of antibiotics, there is an urgent need for novel methods and techniques for antibiotic degradation in aqueous solutions. In this study, high-throughput continuous flow plasma pencil and plasma brush methods were developed and evaluated for their effectiveness in removing antibiotics from solutions. The plasma brush method showed significantly higher degradation rates compared to the plasma pencil method.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Biochemistry & Molecular Biology
Maja Welna, Anna Szymczycha-Madeja, Pawel Pohl
Summary: A fully validated ICP-OES-based method combined with simplified sample preparation was proposed for the determination of elements in YM drinks. Acidification with HNO3 and US provided the best results with LODs at 0.11-8.5 ng g(-1), precision below 5%, and trueness better than 5%. YM drinks commercially available in Poland were analyzed and found to have low bioaccessibility of essential elements but relatively high bioaccessible caffeine content.
Article
Environmental Sciences
Mujahid Ameen Khan, Anna Dzimitrowicz, Magda Caban, Piotr Jamroz, Dominik Terefinko, Wlodzimierz Tylus, Pawel Pohl, Piotr Cyganowski
Summary: The common utilization of antimicrobial agents in medicine and veterinary creates serious problems with multidrug resistance. This study used a DBD-CAPP system as a tool to deactivate nitrobased pharmaceuticals in solutions. The reactive species generated in the DBD-CAPP-treated liquid played a dual role in the degradation of the drugs and the production of Re nanoparticles. The catalytically enhanced DBD-CAPP achieved higher removal of Furazolidone and Chloramphenicol in waste solutions compared to DBD-CAPP alone.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Bachir Ben Seghir, Meriem Hima, Fatima Moulatti, Ibtihal Sahraoui, Ilham Ben Amor, Soumeia Zeghoud, Hadia Hemmami, Imane Kouadri, Asma Ben Amor, Mohammed Messaoudi, Shakeel Ahmed, Abdelkrim Rebiai, Pawel Pohl
Summary: The green approach-based nanoparticle synthesis is a cost-effective and ecologically responsible method. This article describes a simple method for producing MgO and ZnO nanoparticles using aqueous extracts of Zingiber officinale and Glycyrrhiza roots, and investigates their characterization and antibacterial activity.
Article
Engineering, Chemical
Maja Welna, Anna Szymczycha-Madeja, Pawel Pohl
Summary: An analytical method for determining total Sn in canned tomatoes was developed using hydride generation (HG) coupled to inductively coupled plasma optical emission spectrometry (ICP OES) without laborious sample preparation. Different reagents were tested for ultrasound-assisted extraction to replace the traditional wet sample digestion, and aqua regia showed the best results. The developed method had a detection limit of 0.74 ng g(-1), a precision of better than 6%, and a trueness of 98.4-104%.
Article
Chemistry, Analytical
Monika Gorska, Joanna Weiss, Pawel Pohl
Summary: In this study, an atmospheric pressure glow discharge (APGD) system was used to determine Zn, Mg, Ca, Na, and K in selected beverages commonly chosen by athletes. The analysis was performed by optical emission spectrometry (OES) using a flowing liquid cathode (FLC) and a gas jet anode. The simplified sample preparation procedure involved dilution and acidification with HNO3. The optimized conditions for analysis and instrument detection limits were determined, and the results were validated using an alternative reference method (ICP-OES).
ANALYTICAL METHODS
(2023)
Article
Materials Science, Biomaterials
Rita Gelli, Monica Tonelli, Francesca Ridi, Dominik Terefinko, Anna Dzimitrowicz, Pawel Pohl, Aleksandra Bielawska-Pohl, Piotr Jamroz, Aleksandra Klimczak, Massimo Bonini
Summary: Atmospheric pressure plasma treatments can modify the surface properties of magnesium phosphate-based cements (MPCs), resulting in changes in the relative amounts of different phases. These modified MPCs show good biocompatibility and promote cell proliferation, adhesion, and osteogenic differentiation.
ACS BIOMATERIALS SCIENCE & ENGINEERING
(2023)
Article
Chemistry, Analytical
Qian Wu, Li Tian, Xiangyu Shan, Huiling Li, Chao Li, Juan Lu
Summary: A novel ECL sensor was developed by modifying Fe3CuO4-Ru(bpy)3+ and GO-CdS@ZnS on the electrode for the detection of permethrin. The sensor exhibited high sensitivity and a wide detection range.
Article
Chemistry, Analytical
Tingting Gong, Lei Liao, Bingying Jiang, Ruo Yuan, Yun Xiang
Summary: In this study, a fluorescent biosensing system for high sensitivity detection of MT was established using a new Ag+-stabilized DNA triplex probe (Ag+-SDTP) combined with catalytic hairpin assembly (CHA) and CRISPR/Cas12a signal enhancements. The sensing method is able to selectively detect MT from other non-specific molecules and can achieve low level detection of MT in diluted human serums, demonstrating its potential for monitoring disease-specific MT biomarker at trace levels.
Article
Chemistry, Analytical
Estrella Sanz Rodriguez, Kyra Wood, Paul R. Haddad, Brett Paull
Summary: This study presents a simple, rapid, and reliable method for determining boron in aqueous solutions using suppressed ion chromatography coupled to electrospray ionisation-triple quadrupole mass spectrometry. The method achieved a low limit of detection and demonstrated excellent analytical performance.
Article
Chemistry, Analytical
Aline Cournut, Paul Moustiez, Yannick Coffinier, Christine Enjalbal, Claudia Bich
Summary: Alzheimer's disease is a major cause of senile dementia and is characterized by the aggregation of neurofibrillary tangles and amyloid plaques in the brain. The A beta 1-42 peptide is considered the primary cause of neurotoxicity due to its insolubility and subsequent aggregation. A beta 1-42 and A beta 1-40 have been identified as relevant biomarkers for AD diagnosis, and SurfaceAssisted Laser Desorption/Ionization Mass Spectrometry (SALDI-MS) was used to monitor the A beta 1-42/A beta 1-40 ratio without prior sample treatment.
Article
Chemistry, Analytical
Dotse Selali Chormey, Buse Tugba Zaman, Tulay Borahan Kustanto, Sezin Erarpat Bodur, Suleyman Bodur, Elif Ozturk Er, Sezgin Bakirdere
Summary: This review provides an overview of the harmful effects of endocrine disrupting chemicals (EDCs) on human health and introduces the methods for analyzing EDCs. Recent research has focused on using green chemicals, such as deep eutectic solvents (DESs), for microextraction to ensure environmental safety.
Article
Chemistry, Analytical
Yan Zhang, Renfeng Xu, Jingjing Wu, Zhenghong Zhang, Yuhuang Wang, Hongqin Yang, Sheng Zhang
Summary: This study visualized the pore-like structures in prostate cancer cell membranes after treatment with the anticancer drug paclitaxel, demonstrating its mechanism of action related to oxidative damage.
Article
Chemistry, Analytical
Chihong Ma, Qin Zhou, Jinjin Shi, Hua Gao, Di Huang, Huimin Xue, Han Wang, Zhenzhong Zhang, Sen Yang, Junli Zhang, Kaixiang Zhang
Summary: We developed a CRISPR-empowered electrochemical biosensor, named PER-E-CRISPR, for amplification-free and sensitive detection of miR-21. The biosensor combines the advantages of CRISPR/Cas13a and primer exchange reaction (PER) for target amplification. Under optimized conditions, the PER-E-CRISPR assay exhibits a linear range from 10-13 to 10-7 M and a limit of detection of 30.2 fM. The biosensor shows excellent performance in actual plasma, indicating promising prospects for miRNA detection in molecular diagnosis.
Article
Chemistry, Analytical
Gang Liang, Jie Zhao, Yufei Gao, Tao Xie, Jianhui Zhen, Ligang Pan, Wenwen Gong
Summary: Molecular docking (MD) analysis is widely used for studying the interaction between aptamers and small molecules. This study established steady-state aptamers of tertiary structures (SATS) using specific aptamers of tetracycline antibiotics as docking models. Molecular docking results revealed multiple binding sites in the SATS of aptamers, with significant variations in binding free energy (BFE) and docking score (DS). The study also proposed a method for MD analysis based on SATS, providing insights into binding mode and predicting binding sites.
Article
Chemistry, Analytical
Yixuan Xu, Changchang Teng, Huiping Dang, Dalong Yin, Lifeng Yan
Summary: Stable organic radical molecules with high NIR fluorescence quantum efficiency have been synthesized and encapsulated into nanoparticles, which show great potential for both photodynamic therapy (PDT) and photothermal therapy (PTT) of tumors.
Article
Chemistry, Analytical
Yu Su, Dandan Yang, Yanjie Wang, Jie Ding, Lan Ding, Daqian Song
Summary: In this study, a highly selective molecularly imprinted polymer Cu-MIPs@CS was designed and synthesized for bisphenol A (BPA). Cu-MIPs@CS showed significantly enhanced imprinting factor and selective factor towards BPA compared to MIPs@CS. It also exhibited superior discrimination ability between BPA and its structural analogue. Additionally, Cu-MIPs@CS were successfully applied as a solid phase extraction adsorbent for the determination of BPA in drinking water samples.
Article
Chemistry, Analytical
Yi Qiao, Qiongdan Zhang, Yukun He, Tianguang Cheng, Jing Tu
Summary: Single cell heterogeneity plays an important role in many biological phenomena, and distinguishing cells with specific mutations is beneficial for clinical diagnosis and drug screening. This study introduces a gel plate platform that can distinguish cell types based on their phenotypes, with low equipment requirement. The gel platform has potential in point-of-care circumstances and single-cell stimulation responses that prioritize efficiency and simplicity.
Article
Chemistry, Analytical
Chengke Wang, Shuyang Sun, Ping Wang, Huawei Zhao, Wenling Li
Summary: The food safety of aquatic products is a global concern. Nanotechnology-based analyses have advantages in the detection of bacteria, metal ions, and small molecule contaminants. This review summarizes the recent advances in biosensing strategies for aquatic products and highlights the application of nanomaterials, lateral flow-based biosensors, surface-enhanced Raman scattering, microfluidic chips, and molecular imprinting technologies.
Article
Chemistry, Analytical
Liping Zhu, Zeng Tang, Xuemei Zhang, Li Zhu, Tian Meng, Linying Yu, Ting Xiao, Shasha Lu, Xiaoli Xiong, Xiurong Yang
Summary: A sensitive off-on electrochemiluminescence DNA sensor was developed using Exo III-assisted cascade amplification system. The sensor achieved high selectivity and ultra-high sensitivity in detecting target DNA by utilizing ECL and SPR effects. This study provides a new perspective for designing highly sensitive and programmable ECL biosensors.
Article
Chemistry, Analytical
Tong Li, Mengxu Sun, Suping Xia, Ting Huang, Rong-Tian Li, Chunrong Li, Zong Dai, Jin-Xiang Chen, Jun Chen, Nuan Jia
Summary: Here, we developed a binary system based on DNA tetrahedron and fluorogenic RNA aptamers for highly specific and label-free mRNA imaging in living cells. This system achieved high specificity label-free detection of nucleic acids with a detection limit of 1.34 nM. The method has potential applications in early disease diagnosis and new drug development.
Article
Chemistry, Analytical
Yao Zhao, Shu Zhang, Wang Yao, Yuxuan Zhu, Jing Qian, Juan Yang, Nianjun Yang
Summary: A new hierarchical nanostructured composite with high conductivity and catalytic activity is synthesized. The sensor exhibits significant catalytic effect and high sensitivity for monitoring the environmental endocrine disruptor bisphenol A (BPA).