期刊
SYNLETT
卷 30, 期 17, 页码 1929-1934出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1611874
关键词
carbene transfer reactions; cycloaddition; rearrangement; C-H functionalization; diazoalkanes; iron; photochemistry
资金
- RWTH Aachen University
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) [408033718]
Carbenes are versatile, highly reactive intermediates with great importance in chemistry. We recently reported on our findings on safe and scalable applications of hazardous diazoacetonitrile using cheap and commercially available iron catalysts in efficient carbene transfer reactions, ranging from cyclopropanation towards C-H functionalization reactions for the synthesis of biologically important building blocks. More lately, we uncovered the reactivity of diazoalkanes under photochemical conditions using visible light and were able to demonstrate a variety of different, metal-free carbene transfer reactions, which now open up new sustainable ways for the construction of small functional molecules.
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