4.7 Article

Modulation of optical and photocatalytic properties by morphology and microstrain in hierarchical ceria nanostructures

期刊

SOLAR ENERGY MATERIALS AND SOLAR CELLS
卷 195, 期 -, 页码 106-113

出版社

ELSEVIER
DOI: 10.1016/j.solmat.2019.02.033

关键词

Microwave assisted synthesis; Nanoceria; Microstrain; F-centers; Photocatalysis

资金

  1. FONDECYT Project, Government of Chile, Santiago [3160142]
  2. CONICYT PIA/APOYO CCTE [AFB170007]

向作者/读者索取更多资源

In this work, we presented our effort to understand the effect of the operating parameters of the microwave oven (power and irradiation time) on the structural and morphological changes in ceria (CeO2) nanostructures. A series of controlled experiments were carried out to understand the crucial factors determining the formation of ceria nanostructures with spheres and rods like morphology. By adjusting the experimental parameters different ceria nanostructures such as spheres, cubes and rods were obtained. The variation of the lattice parameter and morphology of the prepared samples was discussed by structural studies. The W-H analysis was implemented to calculate the average crystallite size and microstrain. The influence of morphology and microstrain on the band gap energy, luminescence and photocatalytic activity of the synthesized samples was discussed. The observed variation in the band gap was explained based on the variation of the crystallite size. Also, the observed variation in the ratio of the intensity of band gap related emission (I-Bg) and defects related emission (I-def) was discussed. In addition, the enhanced photocatalytic performance of the prepared ceria nanostructures with different morphology was discussed.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Environmental Sciences

Silver nanoparticles modified ZnO nanocatalysts for effective degradation of ceftiofur sodium under UV-vis light illumination

N. Pugazhenthiran, P. Sathishkumar, Omeer Albormani, S. Murugesan, M. Kandasamy, M. Selvaraj, S. Suresh, S. Karthick Kumar, D. Contreras, H. Valdes, R. Mangalaraja

Summary: The addition of silver-coated zinc oxide nanostructures in the photocatalytic degradation of ceftiofur sodium enhances the catalytic activity and ability to remove pharmaceutical wastewater.

CHEMOSPHERE (2023)

Article Forestry

Use of NIR spectroscopy and multivariate regression for prediction of pentosan content in wood pulp

Katherine Marquez, Felipe Jimenez-Aspee, Nicole Marquez, Pablo Salgado, David Contreras

Summary: This study developed an alternative method using near-infrared spectroscopy and partial least squares regression to predict the pentosan content in pulps. This new method is fast, inexpensive, and non-destructive, accurately predicting the pentosan content.

EUROPEAN JOURNAL OF WOOD AND WOOD PRODUCTS (2023)

Article Materials Science, Multidisciplinary

Cu-MXene: A potential biocide for the next-generation biomedical application

Neetu Talreja, Mohammad Ashfaq, Divya Chauhan, R. V. Mangalaraja

Summary: Bacterial resistance in humans has led to infectious diseases, necessitating the development of new antibacterial materials. The synthesized MXene and Cu-MXene materials showed high biocompatibility with erythrocyte cells and demonstrated excellent antibacterial activity against Gram-negative and Gram-positive bacterial strains. These materials can be safely used in biomedical applications.

MATERIALS CHEMISTRY AND PHYSICS (2023)

Article Materials Science, Multidisciplinary

Platinum nanoparticles confined within TiO2 nanotube matrix for enhanced catalytic reduction of azure b dye

Krishnamoorthy Shanmugaraj, Ramalinga Viswanathan Mangalaraja, Cristian H. Campos, Dinesh Pratap Singh, R. Udayabhaskar, Santiago Bedoya, Radhamanohar Aepuru

Summary: This work reports the synthesis of PtNPs-TiO2NTs catalyst, which exhibits high catalytic efficiency and operational stability in the reduction of AZB dye.

MATERIALS LETTERS (2023)

Review Chemistry, Analytical

MXene-Based Nanocomposites for Piezoelectric and Triboelectric Energy Harvesting Applications

Durga Prasad Pabba, Mani Satthiyaraju, Ananthakumar Ramasdoss, Pandurengan Sakthivel, Natarajan Chidhambaram, Shanmugasundar Dhanabalan, Carolina Venegas Abarzua, Mauricio J. Morel, Rednam Udayabhaskar, Ramalinga Viswanathan Mangalaraja, Radhamanohar Aepuru, Sathish-Kumar Kamaraj, Praveen Kumar Murugesan, Arun Thirumurugan

Summary: This article presents the superior advantages of 2D MXenes for nanogenerators and reviews the recent progress in this field. The topics covered include the applications of MXenes in nanogenerators, renewable energy, classifications and working principles of nanogenerators, materials for energy harvesting, and combinations of MXene with other active materials. Furthermore, the synthesis and properties of MXene, MXene nanocomposites with polymeric materials, and internal improvement mechanisms of MXenes for nanogenerators using 3D printing technologies are discussed in detail. Finally, the key points of this review are summarized, and some thoughts on potential approaches for better performance of nanogenerators using MXene-based nanocomposite materials are presented.

MICROMACHINES (2023)

Article Electrochemistry

Photo-Alternating Current-Electro-Fenton Process for Pollutant Removal and Energy Usage from Industrial Wastewater: Response Surface Approach Optimization of Operational Parameters

Asaithambi Perumal, Mamuye Busier Yesuf, Rajendran Govindarajan, Subramaniapillai Niju, C. Arun, Selvakumar Periyasamy, T. Pandiyarajan, Esayas Alemayehu

Summary: There has been an increasing interest in the use of electrochemical and advanced oxidation technologies for industrial wastewater treatment over the past two decades. Amongst the examined techniques, the UV+AC+EF process showed the highest efficacy with 100% elimination of color and COD, and low energy consumption of 4 kWhr m(-3). Through optimization using mathematical and statistical methods, the UV+AC+EF technology achieved 89.50% COD elimination and reduced energy consumption to 2.775 kWhr m(-3).

CHEMELECTROCHEM (2023)

Article Chemistry, Physical

Synthesis and characterization of metal-free nanosheets of carbo-catalysts for bifunctional electrocatalyst towards HER and OER application

Natesan Kumaresan, Pichan Karuppasamy, M. Praveen Kumar, Shaik Gouse Peera, Mohamad S. AlSalhi, Sandhanasamy Devanesan, R. V. Mangalaraja, Perumalsamy Ramasamy, Tatianne Ferreira de Oliveira, G. Murugadoss

Summary: The production of green hydrogen through water electrolysis has gained attention due to the demand for green energy technologies. Currently, Pt and RuO2-based electrocatalysts are expensive, leading to the search for efficient and cheap alternatives. In this study, biomass-derived electrocatalysts with implanted heteroatoms were synthesized and characterized. The catalyst exhibited excellent morphology, surface area, and activity for hydrogen and oxygen evolution reactions in alkaline electrolytes.

MOLECULAR CATALYSIS (2023)

Article Chemistry, Physical

Nitrogen implanted carbon nanosheets derived from Acorus calamus as an efficient electrode for the supercapacitor application

Natesan Kumaresan, Mohamad S. Alsalhi, Pichan Karuppasamy, M. Praveen Kumar, Muthu Senthil Pandian, A. Arulraj, Shaik Gouse Peera, R. V. Mangalaraja, Sandhanasamy Devanesan, Perumalsamy Ramasamy, G. Murugadoss

Summary: The biggest challenges in modern society revolve around the production and storage of affordable, clean energy. Recent research has focused on discovering new electrode materials to enhance energy production and storage. In this study, nitrogen-implanted carbon particles were synthesized for the first time from Acorus Calamus for use in symmetric supercapacitors. The carbon particles activated with KOH at 750 degrees C (C-750) under a nitrogen atmosphere exhibited superior structural, textural, morphological, and electrochemical performance. BET analysis confirmed that the C-750 carbon nanoparticles significantly increased the surface area to about 3551.07 m(2)/g. Further analysis revealed a pore size of 3.70 nm and a pore volume of 0.51 cc/g. The high surface area and mesoporous nature of the C-750 sample effectively enhanced the specific capacitance to 354.44 Fg(-1) at 1 Ag-1 using a 6 M KOH electrolytic solution. Additionally, the energy density and power density of the C-750 sample were observed to be approximately 47.2 Whkg(-1) and 16,000 Wkg(-1), respectively.

MOLECULAR CATALYSIS (2023)

Article Biochemistry & Molecular Biology

Catalytic Selective Oxidation of β-O-4 Bond in Phenethoxybenzene as a Lignin Model Using (TBA)5[PMo10V2O40] Nanocatalyst: Optimization of Operational Conditions

Juan Diaz, Luis R. Pizzio, Gina Pecchi, Cristian H. Campos, Laura Azocar, Rodrigo Briones, Romina Romero, Eduardo Troncoso, Camila Mendez-Rivas, Victoria Melin, Juan C. Murillo-Sierra, David Contreras

Summary: The catalytic oxidation of a lignin model compound using a polyoxometalate nanocatalyst was optimized to achieve a high conversion rate. The optimized conditions allowed for the successful depolymerization of Kraft lignin, resulting in a decrease in molar mass distribution and polydispersity index, as well as the cleavage of the beta-O-4 bond. These findings offer a sustainable alternative for converting lignin into valuable products.

MOLECULES (2023)

Article Spectroscopy

Synthesis, Structure, Morphology, Element composition, Electrochemical, and Optical studies of Zn0.98-XMn0.02CeX Quantum dots

P. Sakthivel, R. V. Mangalaraja, G. Ramalingam, K. Sakthipandi, V. Gowtham

Summary: This paper reports the preparation of Mn-doped ZnS and Mn, Ce co-doped ZnS quantum dots using a facile co-precipitation technique. The synthesized particles were confirmed to have a cubic structure and a particle size of -2 nm through XRD and HR-TEM results. The optical characteristics of the samples were revealed through UV-visible absorbance and transmittance spectra.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2023)

Article Physics, Multidisciplinary

Exit dynamics from Morse potential under thermal fluctuations

P. Vipin, R. Sankaranarayanan

Summary: The dynamics of a Brownian particle in Morse potential under thermal fluctuations is investigated by numerically integrating the corresponding Langevin equation. The dependence of Kramer's rate on temperature and viscosity of the medium is studied by mean first passage time. An approximate analytical expression for the rate constant is found and it shows a temperature dependent pre-factor for the Arrhenius equation. Numerical simulations are consistent with the analytical approximations.

PRAMANA-JOURNAL OF PHYSICS (2023)

Article Biotechnology & Applied Microbiology

Isolation and molecular detection of endophytic actinomycetes Nocardiopsis dassonvillei DMS 1 (MH900216) from marine sea grasses with bacterial inactivation

Chackaravarthi Gnanasekaran, Ramachandran Govindan, Chenthis Kanisha Chelliah, Rajivgandhi Govindan, Priya Ranganathan, Maruthupandy Muthuchamy, Franck Quero, Arulraj Arunachalam, Mangalaraja Ramalinga Viswanathan, Naiyf S. Alharbi, Manoharan Natesan

Summary: In this study, a marine actinomycete called N. dassonvillei DMS 1 (MH900216) was discovered. The analysis of its products revealed that this actinomycete has antibacterial activity and can inhibit the growth of A. baumannii and K. pneumoniae. This research suggests that marine actinomycetes could be a promising alternative source for discovering new antibiotics to combat multi drug resistant bacteria.

BIOCATALYSIS AND AGRICULTURAL BIOTECHNOLOGY (2023)

Article Engineering, Environmental

Ultra-small Ni@NiFe2O4/TiO2 magnetic nanocomposites activated peroxymonosulphate for solar light-driven photocatalytic mineralization of Simazine

C. Ashina, N. Pugazhenthiran, P. Sathishkumar, M. Selvaraj, Mohammed A. Assiri, Chandrasekaran Rajasekaran, M. A. Gracia-Pinilla, R. V. Mangalaraja

Summary: In this study, Ni@NiFe2O4/TiO2 magnetic nanocomposites were prepared via a simple sonochemical route, and they showed excellent photocatalytic activity and activation of peroxymonosulphate under direct solar light irradiation.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Materials Science, Multidisciplinary

Understanding the synergetic effects of mechanical milling and hot pressing on bimodal microstructure and tribo-mechanical behavior in porous Ti structures

Ricardo Chavez-Vasconez, Cristina Arevalo, Yadir Torres, Mauricio Reyes-Valenzuela, Sergio Sauceda, Christopher Salvo, Ramalinga Viswanathan Mangalaraja, Isabel Montealegre, Eva M. Perez-Soriano, Sheila Lascano

Summary: This study investigates the interplay between processing parameters, microstructural attributes, and the tribo-mechanical performance of titanium grade 4 biomedical implants. The study finds that a sample composed of 75 wt% milled powder, 10-hour milling duration, and 60 vol% NaCl exhibits superior biomechanical equilibrium and promising application prospects.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2023)

Article Energy & Fuels

Highly efficient double-side-passivated perovskite solar cells for reduced degradation and low photovoltage loss

Shahriyar Safat Dipta, Md Habibur Rahaman, Walia Binte Tarique, Ashraful Hossain Howlader, Ayush Pratik, John A. Stride, Ashraf Uddin

Summary: Implementing a double-sided passivation approach can enhance the performance of n-i-p structured PSCs and improve the stability and photovoltaic properties of the cells.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Paste-based silver reduction for iTOPCon rear side metallization

Daniel Ourinson, Andreas Brand, Andreas Lorenz, Marwan Dhamrin, Sebastian Tepner, Michael Linse, Nathalie Goettlicher, Kosuke Tsuji, Jonas D. Huyeng, Florian Clement

Summary: This work presents two approaches to reduce the amount of silver on the rear side of M2-sized industrial iTOPCon solar cells. The Cu-based approach shows promise with similar power conversion efficiency compared to the conventional approach, while the Al-based approach exhibits some limitations but demonstrates the potential of such type of contact for iTOPCon solar cells.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Screen printable copper pastes for silicon solar cells

Abasifreke Ebong, Donald Intal, Sandra Huneycutt, Thad Druffel, Ruvini Dharmadasa, Kevin Elmer, Apolo Nambo

Summary: This study demonstrates the successful metallization of a PERC silicon solar cell using screen-printable copper (Cu) paste. The Cu paste contains antioxidant additives and diffusion inhibitors to prevent oxidation and diffusion of Cu. The Cu-printed cells achieved an efficiency of 19% and showed no Cu diffusion after characterization tests. The long-term stability and effectiveness of the Cu diffusion barrier were also confirmed.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Defining specifications for accurate Metal/TCO specific contact resistivity measurements by TLM in silicon heterojunction devices

Senami Zogbo, Wilfried Favre, Olivier Bonino, Marie-Estelle Gueunier-Farret

Summary: Measuring specific contact resistivity (pc) is crucial for interface engineering in high efficiency solar cells. The Transfer Length Method (TLM) is commonly used for evaluating layer sheet resistance (Rsheet) and pc, but it is not suitable for metal/Transparent Conductive Oxide (TCO) interface evaluation in silicon heterojunction (SHJ) cells. This study investigates the parameters that restrict current confinement within the TCO, including mid-gap trap density (Dit) at the a-Si:H/c-Si interface and the activation energy (Ea = Ec - EF) variation of a-Si:H contact layers.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Ribbons lengthening induced by thermal cycling in PV modules part I: Cell-ribbon mechanical interaction through the solder

Jean-Baptiste Charpentier, Philippe Voarino, Julien Gaume

Summary: The phenomenon of ribbon lengthening in PV modules exposed to thermal cycling is not well explained in the literature. In this study, a three layers model is proposed to explain this effect, and the predictions of the model are validated through finite element method simulations and experiments. The results show that the model predictions are consistent with the indirect measurements, but not with the direct measurements. Additionally, it is inferred that the encapsulant plays a role after the solder failure.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Ribbons lengthening induced by thermal cycling in PV modules, Part II: Glass-ribbon mechanical interaction through the encapsulant

Jean-Baptiste Charpentier, Philippe Voarino, Julien Gaume

Summary: This study investigates the problematic ribbon lengthening observed in PV modules exposed to high amplitude thermal cycling. A simplified system model is proposed and accurate predictions are obtained using the Finite Element Method. The results show that the thickness of the encapsulant has a substantial impact on the lengthening of the ribbons.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Gallium nanoparticles as antireflection structures on III-V solar cells

S. Catalan-Gomez, E. Martinez Castellano, M. Schwarz, M. Montes Bajo, L. Dorado Vargas, A. Gonzalo, A. Redondo-Cubero, A. Gallego Carro, A. Hierro, J. M. Ulloa

Summary: This study investigates the use of core-shell gallium nanoparticles as functional light scatterers on solar cells. By optimizing the nanoparticle size, the short-circuit current of the solar cells is significantly improved. The underlying physical mechanism is studied through optical measurements and simulations, and a method to reduce the plasmonic effect of the nanoparticles is demonstrated.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Highly reflective and passivated ohmic contacts in p-Ge by laser processing of aSiCx:H(i)/Al2O3/aSiC films for thermophotovoltaic applications

M. Gamel, G. Lopez, A. M. Medrano, A. Jimenez, A. Datas, M. Garin, I. Martin

Summary: In this study, a highly reflective ohmic contact to p-type c-Ge material is demonstrated, which can improve the efficiency of thermophotovoltaic devices. The experimental results show that this contact can simultaneously meet the requirements of good back surface passivation, low electrical resistivity, and high reflectivity. Moreover, simulations suggest that implementing these back contacts has the potential to achieve conversion efficiencies comparable to high-efficiency c-Ge TPV cells.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Improvement on solar selective absorption properties of anodic aluminum oxide photonic crystal films by electrodeposition of silver

Hongyang Wei, Qing Xu, Dongchu Chen, Min Chen, Menglei Chang, Xiufang Ye

Summary: This study prepared solar selective absorption films based on anodic aluminum oxide (AAO) photonic crystals using a unique electrodeposition method. The Co-Ag electrodeposited film exhibited superior solar selective absorption properties and thermal stability.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Optical absorption driven by efficient refraction and light concentration for photovoltaic applications

Ankit Kumar, Ankit Chauhan, Jordi Llobet, Helder Fonseca, Patricia C. Sousa, Carlos Calaza, Gil Shalev

Summary: This study found that decorating subwavelength arrays with SiO2 quasi-nanolenses (qNL arrays) can enhance the absorption of the solar spectrum. Optical absorption mechanisms in qNL arrays were investigated using near-field scanning optical microscopy (NSOM), revealing that the enhancement is a result of the combination of effective antireflection coating, increased optical interactions between adjacent dielectrics for elevated light trapping, and strong light concentration due to the presence of qNLs.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Progress on the reduction of silver consumption in metallization of silicon heterojunction solar cells

S. Pingel, T. Wenzel, N. Goettlicher, M. Linse, L. Folcarelli, J. Schube, S. Hoffmann, S. Tepner, Y. C. Lau, J. Huyeng, A. Lorenz, F. Clement

Summary: This study demonstrates the potential to reduce silver consumption in highly efficient SHJ cells through fine-line screen printing using low temperature paste with various screens. The results show that using finer mesh allows for narrower grid fingers and lower resistance, leading to improved cell efficiency. Simulation results indicate that module wire configuration is crucial for reducing silver consumption.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Efficient-thermal conductivity, storage and application of bionic tree-ring composite phase change materials based on freeze casting

Xibo He, Jun Qiu, Wei Wang, Yicheng Hou, Yong Shuai

Summary: This paper proposes a novel phase change material with high thermal conductivity and stability for fast photo-thermal conversion and storage. The experimental results demonstrate excellent durability and stability of the phase change material, with good performance in thermal conductivity and thermal storage efficiency.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Solar evaporation of liquid marbles with tunable nanowire array

Qingyuan Liu, Lin Wang, Zheng Liu, Guohua Liu

Summary: A new evaporating structure consisting of liquid marble with tunable nanowire array is proposed to enhance solar evaporation. The experiments show that the liquid marble with nanowire array exhibits outstanding evaporation performance, which has significant implications for seawater desalination or wastewater treatment.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Effects of different interface on the stability of hybrid heterojunction solar cells

Hao Liu, Qiming Liu, Jinpei Liu, Yonggang Zhao, Yingjie Yu, Yue An, Ganghui Wei, Yanzheng Li, Yujun Fu, Junshuai Li, Deyan He

Summary: Moisture in the air is identified as the main cause of performance degradation in organic-inorganic hybrid solar cells. Exposure to air leads to the growth of thin oxide layer on the interface and the formation of silver sulfide, increasing the series resistance and decreasing the fill factor, thus degrading the cell performance.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)

Article Energy & Fuels

Refractive indices and extinction coefficients of p-type doped Germanium wafers for photovoltaic and thermophotovoltaic devices

E. Blanco, P. Martin, M. Dominguez, P. Fernandez-Palacios, I. Lombardero, C. Sanchez-Perez, I. Garcia, C. Algora, M. Gabas

Summary: This study addresses the lack of optical parameters for p-type Ge wafers by determining the complex refractive indices of commercial Ge wafers with varying doping levels. The obtained data successfully reproduces the critical points associated with interband transitions and absorption features below the bandgap. The refractive indices were validated through experimental measurements and solar cell simulations.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2024)